Disinfection byproducts and halogen-specific total organic halogen speciation in chlorinated source waters – The impact of iopamidol and bromide

2020 ◽  
Vol 89 ◽  
pp. 90-101 ◽  
Author(s):  
Nana Osei B. Ackerson ◽  
Hannah K. Liberatore ◽  
Michael J. Plewa ◽  
Susan D. Richardson ◽  
Thomas A. Ternes ◽  
...  
2019 ◽  
Vol 53 (10) ◽  
pp. 5987-5999 ◽  
Author(s):  
Amy A. Cuthbertson ◽  
Susana Y. Kimura ◽  
Hannah K. Liberatore ◽  
R. Scott Summers ◽  
Detlef R. U. Knappe ◽  
...  

Author(s):  
Nana Osei B. Ackerson ◽  
Hannah K. Liberatore ◽  
Susan D. Richardson ◽  
Michael J. Plewa ◽  
Thomas A. Ternes ◽  
...  

Abstract Iopamidol (an iodinated x-ray contrast media) and bromide are precursors in the formation of halogenated disinfection byproducts (DBPs). The interactions of these precursors are vital to elucidate the formation of halogenated DBPs during chloramination. This work investigated the formation of total organic halogen and select individual DBPs in two laboratory-chloraminated source waters (SWs) containing iopamidol and bromide. Experiments were carried out in batch reactors containing Barberton SW (BSW) and Cleveland SW (CSW), spiked with iopamidol (5 μM), bromide (15 μM), and 100 μM monochloramine. Total organic iodine concentrations were approximately equal regardless of SW since they are mostly unreacted iopamidol and iopamidol DBPs. Almost equal amount of total organic chlorine (3–4 nM) was produced in the SWs but higher quantities of total organic bromine were formed in BSW than CSW. Substantial quantities of regulated trihalomethanes (THMs) and haloacetic acids (HAAs) were formed in the SWs, along with appreciable concentrations of iodinated trihalomethanes (CHBrClI, CHCl2I, and CHBr2I). Low concentrations of iodo-HAAs were detected, especially at low pH. Overall, bromide concentrations appeared to suppress iodo-DBP formation during chloramination of iopamidol in the presence of natural organic matter. A good correlation (R2 = 0.801) between the yields of regulated DBPs and iodo-DBPs was observed.


2017 ◽  
Vol 18 (3) ◽  
pp. 968-975
Author(s):  
R. G. Silva ◽  
J. Szabo ◽  
V. Namboodiri ◽  
E. R. Krishnan ◽  
J. Rodriguez ◽  
...  

Abstract Development of greener water treatment technologies is important for the production of safe drinking water and water security applications, such as decontamination. Chlorine assisted disinfection is common and economical, but can generate disinfection byproducts (DBPs) that may be of health concern. DBPs are formed due to the reaction of chlorine with naturally occurring organic and inorganic substances in water. Currently, various innovative technologies are being developed as alternative approaches for preventing DBPs during water treatment. In this study, we evaluated the effectiveness of a novel combination of high efficiency flow filtration and UV disinfection treatment system for the removal of Bacillus globigii (B. globigii) spores in water. The filtration system consists of a charged membrane filter (CMF) that not only helps to remove suspended particles but also reduces the impact of other impurities including bio organisms. In order to get most performance details, the CMF was evaluated at clean, half-life, and end of life (EOL) conditions along with 100% UV transmittance (UVT). In addition, the effectiveness of the UV system was evaluated as a stand alone system at 100% and 70% EOL intensity. The study was conducted at the US EPA's Test and Evaluation (T&E) Facility in Cincinnati, OH, using B. globigii, a surrogate for B. anthracis spores. This non-chemical environmentally-friendly CMF/UV combination system and the stand alone UV unit showed greater than 6.0 log removal of B. globigii during the tests.


1984 ◽  
Vol 56 (12) ◽  
pp. 2271-2272 ◽  
Author(s):  
David L. Berger

2017 ◽  
pp. 109-122 ◽  
Author(s):  
D.L. Norwood ◽  
G.P. Thompson ◽  
J.J. St Aubin ◽  
D.S. Millington ◽  
R.F. Christman ◽  
...  

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