Rapid solidification represents a very attractive approach to develop new Al alloys in an economically convenient way. The lower segregation content, refined grains, higher ultimate tensile and yield strengths combined to a good ductile properties confer to these materials an interesting position also in the so critical automotive and/or aeronautical applications. The current paper presents results of an analysis concerning Zn-Al alloys with a new metastable microcrystalline structure, where Copper has been used as alloying element. With addition of elements as Ti and B modification of the microstructure has been reached. In order to study the influence of the cooling rate on the microstructure and structural transformations castings has been realized with melt spinning technique, in both steel and sand moulds. For morphological investigations optical and scanning electron microscopy has been employed. By dilatometric analysis and X-Ray diffraction technique the thermodynamic factors, the kinetic effects, phase transformations and the volume changes related to the transformations produced at the eutectoid temperature have been monitored. For the aforementioned field of applications the most favourable composition has been chosen: based on the up to date outcomes, by modifying the original alloy with some elements a quite homogeneous structure combined with good mechanical behaviour has been obtained.
