Direct catalytic conversion cellulose pyrolysis vapors into long chain alkanes (LCAs) over Au/TS-1

In this paper, we aim to focus on the utilization of carbon dioxide (CO2) as a feedstock for synthetic applications in chemical and fuel industries, through catalytic carboxylation and reduction reactions. Thermal catalytic conversion as well as non-thermal plasma assisted and photocatalytic conversion CO2 into fuels such as methane, methanol, and long-chain hydrocarbons using different catalyst especially nano catalyst are also thoroughly compared and reviewed in this paper. Among currently available technical routes, the thermal catalytic conversion of CO2 via the Fischer-Tropsch (FT) synthesis using nanoscale catalyst offers the most feasible, practical and mature alternative for industrial-scale applications on the short term basis, converting gigantic quantity of CO2 captured from power plants into hydrocarbons.

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Catalytic conversion of C12–C14 primary alcohols mixture into long-chain ketones

Catalysis Communications ◽

10.1016/j.catcom.2010.05.024 ◽

2010 ◽

Vol 11 (14) ◽

pp. 1143-1147 ◽

Cited By ~ 3

Author(s):

Roman Klimkiewicz ◽

Ireneusz Morawski ◽

Janusz Trawczyński

Keyword(s):

Catalytic Conversion ◽

Primary Alcohols ◽

Long Chain

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Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis/aromatization

Science ◽

10.1126/science.abc5441 ◽

2020 ◽

Vol 370 (6515) ◽

pp. 437-441 ◽

Cited By ~ 3

Author(s):

Fan Zhang ◽

Manhao Zeng ◽

Ryan D. Yappert ◽

Jiakai Sun ◽

Yu-Hsuan Lee ◽

...

Keyword(s):

Molecular Weight ◽

Waste Disposal ◽

Reaction Temperature ◽

Molecular Hydrogen ◽

Catalytic Conversion ◽

Weight Percent ◽

Low Molecular Weight ◽

Moderate Reaction ◽

High Yields ◽

Long Chain

The current scale of plastics production and the accompanying waste disposal problems represent a largely untapped opportunity for chemical upcycling. Tandem catalytic conversion by platinum supported on γ-alumina converts various polyethylene grades in high yields (up to 80 weight percent) to low-molecular-weight liquid/wax products, in the absence of added solvent or molecular hydrogen, with little production of light gases. The major components are valuable long-chain alkylaromatics and alkylnaphthenes (average ~C30, dispersity Ð = 1.1). Coupling exothermic hydrogenolysis with endothermic aromatization renders the overall transformation thermodynamically accessible despite the moderate reaction temperature of 280°C. This approach demonstrates how waste polyolefins can be a viable feedstock for the generation of molecular hydrocarbon products.

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Polymer Morphology Revealed by Staining Techniques

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100098204 ◽

1981 ◽

Vol 39 ◽

pp. 340-341

Author(s):

A. C. Reimschuessel ◽

V. Kramer

Keyword(s):

Polymer Melt ◽

Nylon 6 ◽

Morphological Features ◽

Negative Staining ◽

Polymer Morphology ◽

Crystallizable Polymer ◽

Staining Techniques ◽

Long Chain

Staining techniques can be used for either the identification of different polymers or for the differentiation of specific morphological domains within a given polymer. To reveal morphological features in nylon 6, we choose a technique based upon diffusion of the staining agent into accessible regions of the polymer.When a crystallizable polymer - such as nylon 6 - is cooled from the melt, lamellae form by chainfolding of the crystallizing long chain macromolecules. The regions between adjacent lamellae represent the less ordered amorphous domains into which stain can diffuse. In this process the lamellae will be “outlined” by the dense stain, giving rise to contrast comparable to that obtained by “negative” staining techniques.If the cooling of the polymer melt proceeds relatively slowly - as in molding operations - the lamellae are usually arranged in a radial manner. This morphology is referred to as spherulitic.

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A theory of contamination in electron microscopes by surface diffusion

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100107721 ◽

1978 ◽

Vol 36 (1) ◽

pp. 116-117

Author(s):

J.T. Fourie

Keyword(s):

Electron Beam ◽

Surface Diffusion ◽

High Vacuum ◽

Ultra High Vacuum ◽

Physical Parameters ◽

Carbon Compounds ◽

Hydrocarbon Molecules ◽

Electron Microscopes ◽

Primary Electrons ◽

Long Chain

Contamination in electron microscopes can be a serious problem in STEM or in situations where a number of high resolution micrographs are required of the same area in TEM. In modern instruments the environment around the specimen can be made free of the hydrocarbon molecules, which are responsible for contamination, by means of either ultra-high vacuum or cryo-pumping techniques. However, these techniques are not effective against hydrocarbon molecules adsorbed on the specimen surface before or during its introduction into the microscope. The present paper is concerned with a theory of how certain physical parameters can influence the surface diffusion of these adsorbed molecules into the electron beam where they are deposited in the form of long chain carbon compounds by interaction with the primary electrons.

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The effects of low-ratio n-6/n-3 PUFA on biomarkers of inflammation: a systematic review and meta-analysis

Food & Function ◽

10.1039/d0fo01976c ◽

2021 ◽

Author(s):

Yali Wei ◽

Yan Meng ◽

Na Li ◽

Qian Wang ◽

Liyong Chen

Keyword(s):

Systematic Review ◽

Fatty Acid ◽

Polyunsaturated Fatty Acid ◽

Meta Analysis ◽

Chain Polyunsaturated Fatty Acid ◽

Inflammation Markers ◽

Pufa Supplementation ◽

Long Chain

The purpose of the systematic review and meta-analysis was to determine if low-ratio n-6/n-3 long-chain polyunsaturated fatty acid (PUFA) supplementation affects serum inflammation markers based on current studies.

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Biophysics (and sociology) of ceramides.

Biochemical Society Symposium ◽

10.1042/bss0720177 ◽

2005 ◽

Vol 72 ◽

pp. 177-188 ◽

Cited By ~ 28

Author(s):

Félix M. Goñi ◽

F-Xabier Contreras ◽

L-Ruth Montes ◽

Jesús Sot ◽

Alicia Alonso

Keyword(s):

Cell Biology ◽

Positive Curvature ◽

Acyl Chain ◽

Cell Signalling ◽

Hexagonal Structure ◽

Lipid Monolayer ◽

Flip Flop ◽

Long Chain ◽

Bilayer Permeability

In the past decade, the long-neglected ceramides (N-acylsphingosines) have become one of the most attractive lipid molecules in molecular cell biology, because of their involvement in essential structures (stratum corneum) and processes (cell signalling). Most natural ceramides have a long (16-24 C atoms) N-acyl chain, but short N-acyl chain ceramides (two to six C atoms) also exist in Nature, apart from being extensively used in experimentation, because they can be dispersed easily in water. Long-chain ceramides are among the most hydrophobic molecules in Nature, they are totally insoluble in water and they hardly mix with phospholipids in membranes, giving rise to ceramide-enriched domains. In situ enzymic generation, or external addition, of long-chain ceramides in membranes has at least three important effects: (i) the lipid monolayer tendency to adopt a negative curvature, e.g. through a transition to an inverted hexagonal structure, is increased, (ii) bilayer permeability to aqueous solutes is notoriously enhanced, and (iii) transbilayer (flip-flop) lipid motion is promoted. Short-chain ceramides mix much better with phospholipids, promote a positive curvature in lipid monolayers, and their capacities to increase bilayer permeability or transbilayer motion are very low or non-existent.

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