Fabrication of highly hydrophobic sand@soot with core–shell structure and large-scale production possibility for oil/water separation

2021 ◽  
Vol 150 ◽  
pp. 109815
Author(s):  
Elham Mosayebi ◽  
Saeid Azizian ◽  
Byeong Jun Cha ◽  
Tae Gyun Woo ◽  
Young Dok Kim
Keyword(s):  
Large Scale ◽  
Core Shell ◽  
Scale Production ◽  
Water Separation ◽  
Production Possibility ◽  
Large Scale Production ◽  
Oil Water Separation ◽  
Oil Water ◽  
Core Shell Structure ◽  
Highly Hydrophobic

Superhydrophilic Nickel Nanoparticles with Core–Shell Structure To Decorate Copper Mesh for Efficient Oil/Water Separation

2016 ◽  
Vol 120 (23) ◽  
pp. 12685-12692 ◽  
Author(s):  
Zhi-Yong Luo ◽  
Kai-Xuan Chen ◽  
Ya-Qiao Wang ◽  
Jun-Hui Wang ◽  
Dong-Chuan Mo ◽  
...  
Keyword(s):  
Shell Structure ◽  
Nickel Nanoparticles ◽  
Core Shell ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water ◽  
Core Shell Structure ◽  
Copper Mesh

scholarly journals Carbon Nanotubes and Polydopamine Modified Poly(dimethylsiloxane) Sponges for Efficient Oil–Water Separation

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2431
Author(s):  
Wen Zhang ◽  
Juanjuan Wang ◽  
Xue Han ◽  
Lele Li ◽  
Enping Liu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Large Scale ◽  
Absorption Capacity ◽  
Potential Candidate ◽  
Hard Template ◽  
Water Separation ◽  
Industrial Oil ◽  
The Matrix ◽  
Oil Water Separation ◽  
Oil Water

In this paper, effective separation of oil from both immiscible oil–water mixtures and oil-in-water (O/W) emulsions are achieved by using poly(dimethylsiloxane)-based (PDMS-based) composite sponges. A modified hard template method using citric acid monohydrate as the hard template and dissolving it in ethanol is proposed to prepare PDMS sponge composited with carbon nanotubes (CNTs) both in the matrix and the surface. The introduction of CNTs endows the composite sponge with enhanced comprehensive properties including hydrophobicity, absorption capacity, and mechanical strength than the pure PDMS. We demonstrate the successful application of CNT-PDMS composite in efficient removal of oil from immiscible oil–water mixtures within not only a bath absorption, but also continuous separation for both static and turbulent flow conditions. This notable characteristic of the CNT-PDMS sponge enables it as a potential candidate for large-scale industrial oil–water separation. Furthermore, a polydopamine (PDA) modified CNT-PDMS is developed here, which firstly realizes the separation of O/W emulsion without continuous squeezing of the sponge. The combined superhydrophilic and superoleophilic property of PDA/CNT-PDMS is assumed to be critical in the spontaneously demulsification process.

scholarly journals Fabricated of Superhydrophobic Silanized Melamine Sponge with Photochromic Properties for Efficiency Oil/Water Separation

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Peng Hong ◽  
Zhu Liu ◽  
Yang Gao ◽  
Yubin Chen ◽  
Mingxun Zhuang ◽  
...  
Keyword(s):  
Large Scale ◽  
Separation Efficiency ◽  
Low Cost ◽  
Water Repellency ◽  
Dip Coating ◽  
Absorption Capacity ◽  
Photochromic Properties ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water

Superhydrophobic sponge as potential absorbing material for oil/water separation is attracting great attention recently. However, there are still some challenges to feasibly fabricate superhydrophobic sponge with large scale and low cost. Herein, a novel photochromic superhydrophobic melamine sponge (PDMS-SP sponge) is fabricated by facilely dip-coating and thermocuring of hydroxyl-terminated polydimethylsiloxanes mixed with photochromic spiropyran. FT-IR, EDS, and XPS results confirm the successful coating of PDMS-SP upon melamine sponge. The resultant sponge not only possesses excellent water repellency with a contact angle of 154.5° and oil-water separation efficiency with an oil absorption capacity of 48–116 folds of itself weight, but also shows photochromic phenomenon between colorless and purple when it is successively exposed to UV irradiation and visible light.

3D network super-hydrophobic hexafluorbisphenol A poly(aryl ether ketone) membrane prepared by one-step electrospraying

2020 ◽  
Vol 32 (10) ◽  
pp. 1094-1101
Author(s):  
Yongpeng Wang ◽  
Pengtao Yan ◽  
Xintong Huo ◽  
Mengzhu Liu ◽  
Haibo Zhang ◽  
...  
Keyword(s):  
Large Scale ◽  
Condensation Polymerization ◽  
Aryl Ether ◽  
Sliding Angle ◽  
Water Separation ◽  
3D Network ◽  
Oil Water Separation ◽  
Aryl Ether Ketone ◽  
Oil Water ◽  
Ether Ketone

Novel super-hydrophobic poly(aryl ether ketone) (PAEK) membranes have been firstly prepared by modifying ordinary PAEK into hexafluorbisphenol A-PAEK through traditional nucleophilic condensation polymerization and subsequently simple electrospraying technique. With the solution concentration increased, the micromorphology exhibited nanofibers, nanofiber with spindles, 3D network with microspheres embedded, microspheres and dense films, successively. The static water contact angle increased from 99° to 155°, while the sliding angle from 1.3° to 6.8° (±1°), in which the 3D network presented the strongest super-hydrophobicity. After 200 h of water flushing, the rough surface structure and super-hydrophobicity of the membranes were well retained. Moreover, the membrane exhibited wonderful self-cleaning property, oil/water separation property, and stability due to the hierarchical micro/nanostructures. This work provides a new route for the creation of super-hydrophobic high performance engineering plastic fabrics with the potential values in large-scale application of filtration, oil/water separation, and antifouling.

Amphiphilic hyperbranched polyethyleneimine for highly efficient oil–water separation

2020 ◽  
Vol 8 (5) ◽  
pp. 2412-2423 ◽  
Author(s):  
Shu Yan ◽  
Guijin He ◽  
Dengfeng Ye ◽  
Yongsheng Guo ◽  
Wenjun Fang
Keyword(s):  
Phase Separation ◽  
Soft Matter ◽  
Polymer Layer ◽  
Core Shell ◽  
Water Separation ◽  
Highly Efficient ◽  
Oil Water Separation ◽  
Oil Water

Core–shell structural amphiphilic soft matter, HPEI-g-Cn, can achieve phase separation thoroughly, in which an interfacial active-polymer layer is formed after demulsification.

SLOP TANK DESIGN FOR IMPROVED LOAD-ON-TOP

1975 ◽  
Vol 1975 (1) ◽  
pp. 195-200
Author(s):  
Robert J. Fiocco ◽  
Vincent W. Ridley
Keyword(s):  
Large Scale ◽  
Focal Point ◽  
Operational Flexibility ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oily Water ◽  
Oil Water ◽  
Tank Design ◽  
Oil Tankers ◽  
Capacity Structure

ABSTRACT Slop tanks are the focal point of the Load-On-Top system used on crude oil tankers to prevent pollution of the sea. Design of these tanks and their operating procedures strongly affect the degree of oil-water separation achieved. This paper presents the results of an investigation undertaken to define designs and procedures for improving separation and minimizing oil discharge to sea. The program was funded in part by the U.S. Maritime Administration. Based on tanker experience and laboratory tests with tank models, guidelines on capacity, structure, inlets, outlets, system design, and wastewater handling, procedures were developed. The guidelines aim at assuring successful Load-On-Top operations by (1) providing tanker operational flexibility for handling oily water, (2) minimizing the degree of oil-water mixing, (3) avoiding re-dispersion of separated oil during feeding and discharging operations, and (4) eliminating the possibility of accidental oil contamination. This investigation provides a basis for future large-scale or shipboard studies to improve the performance of slop tanks on existing tankers as well as on future tankers.

scholarly journals A Robust Superhydrophobic Polyurethane Sponge Loaded with Multi-Walled Carbon Nanotubes for Efficient and Selective Oil-Water Separation

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3344
Author(s):  
De Liu ◽  
Shiying Wang ◽  
Tao Wu ◽  
Yujiang Li
Keyword(s):  
Ionic Strength ◽  
Absorptive Capacity ◽  
Large Scale ◽  
Low Cost ◽  
Absorption Capacity ◽  
Effect Of Temperature ◽  
Water Contact ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water

The influence of different coupling agents and coupling times on the wettability of a polyurethane (PU) sponge surface were optimized. Octadecyltrichlorosilane (OTS) was selected as the optimal coupling agent to prepare the superhydrophobic sponge. The superhydrophobic sponge was prepared in one step, which has the advantages of simple operation and enhanced durability. The superhydrophobic sponge was characterized by scanning electron microscopy, Teclis Tracker tensiometry, and Fourier transform infrared (FT-IR) spectrophotometry. The water contact angle increased from 64.1° to 151.3°, exhibiting ideal superhydrophobicity. Oils and organic solvents with different viscosities and densities can be rapidly and selectively absorbed by superhydrophobic sponges, with an absorption capacity of 14.99 to 86.53 times the weight of the sponge itself, without absorbing any water. Since temperature affects the viscosity and ionic strength of oil, and influences the surface wettability of the sponges, the effect of temperature and ionic strength on the oil absorption capacity of the superhydrophobic sponges was measured, and its mechanism was elucidated. The results showed that the absorptive capacity retained more than 90% of the initial absorptive capacity after repeated use for 10 times. Low-cost, durable superhydrophobic sponges show great potential for large-scale oil-water separation.

scholarly journals Efficient Oil/Water Separation Membrane Derived from Super-Flexible and Superhydrophilic Core–Shell Organic/Inorganic Nanofibrous Architectures

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 974 ◽  
Author(s):  
Zhi Liu ◽  
Detao Qin ◽  
Jianghui Zhao ◽  
Quan Feng ◽  
Zhengtao Li ◽  
...  
Keyword(s):  
Separation Efficiency ◽  
Scale Up ◽  
Core Shell ◽  
Water Separation ◽  
Membrane Performance ◽  
Novel Approach ◽  
Separation Membrane ◽  
Oil Water Separation ◽  
Oil Water ◽  
Nanofibrous Membranes

To address the worldwide oil and water separation issue, a novel approach was inspired by natural phenomena to synthesize superhydrophilic and underwater superoleophobic organic/inorganic nanofibrous membranes via a scale up fabrication approach. The synthesized membranes possess a delicate organic core of PVDF-HFP and an inorganic shell of a CuO nanosheet structure, which endows super-flexible properties owing to the merits of PVDF-HFP backbones, and superhydrophilic functions contributed by the extremely rough surface of a CuO nanosheet anchored on flexible PVDF-HFP. Such an organic core and inorganic shell architecture not only functionalizes membrane performance in terms of antifouling, high flux, and low energy consumption, but also extends the lifespan by enhancing its mechanical strength and alkaline resistance to broaden its applicability. The resultant membrane exhibits good oil/water separation efficiency higher than 99.7%, as well as excellent anti-fouling properties for various oil/water mixtures. Considering the intrinsic structural innovation and its integrated advantages, this core–shell nanofibrous membrane is believed to be promising for oil/water separation, and this facile approach is also easy for scaled up manufacturing of functional organic/inorganic nanofibrous membranes with insightful benefits for industrial wastewater treatment, sensors, energy production, and many other related areas.

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