Metastable wurtzite phase Cu2ZnSnS4 nanocrystal synthesis and application in solar cell

2022 ◽  
pp. 122900
Author(s):  
Manjeet Singh ◽  
Ashish Kumar Singh
2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Fengyan Zhang ◽  
Chivin Sun ◽  
Cyril Bajracharya ◽  
Rene G. Rodriguez ◽  
Joshua J. Pak

CuIn0.75Ga0.25S2(CIGS) thin film solar cells have been successfully fabricated using CIGS Wurtzite phase nanoparticles for the first time. The structure of the cell is Glass/Mo/CIGS/CdS/ZnO/ZnO:Al/Ag. The light absorption layer is made from CIGS Wurtzite phase nanoparticles that are formed from single-source precursors through a microwave irradiation. The Wurtzite phase nanoparticles were converted to Chalcopyrite phase film through a single-step annealing process in the presence of argon and sulfur at 450°C. The solar cell made from Wurtzite phase nanoparticles showed 1.6% efficiency and 0.42 fill factor.


2020 ◽  
Vol 851 ◽  
pp. 16-24
Author(s):  
Markus Diantoro ◽  
Syahri Yanor ◽  
Thathit Suprayogi ◽  
Nandang Mufti ◽  
Aripriharta ◽  
...  

Photosupercapacitor is an integrated device for harvesting and storing solar energy into electrical energy. Photosupercapacitor is constructed by solar cell and supercapacitor. In the solar cell with DSSC type, one of the influential variables is photoanode performance. The photoanode with ZnO layer plays a role in light absorption, charge mobility, and electrical properties, which are influenced by crystal structure and nanoscale morphology. One of nanoscale morphology of ZnO that widely used is nanorods. This work is focussed to investigate the effect of annealing temperature on seed layer ZnO to growth nanorods shape in photoanode of photosupercapacitor and its performance. The seed layer ZnO nanoparticle was deposited onto FTO substrate by a screen printing method. The ZnO nanorod was grown by dippin FTO/ZnO in solution (Zinc nitrate, HMT, and DI water) under 100 °C. The photosupercapacitor was constructed by DSSC and ZnO symmetric supercapacitor which integrated by using aluminum foil substrate. The annealing temperature on ZnO nanoparticles affected on increasing crystal size of ZnO seed. All of the samples show ZnO wurtzite phase with the highest peak located on the hkl plane (101), but ZnO nanorod growth to hkl plane (100). The DSSC part efficiency produced around 0.874%. The resulting efficiency of photosupercapacitor is around 0.549%. The annealing temperature causes the value of specific capacitance to decrease, because of decreasing DSSC performance.


2015 ◽  
Vol 18 (4) ◽  
pp. 213-218 ◽  
Author(s):  
M. Y.A. Rahman ◽  
A. A. Umar ◽  
L. Roza ◽  
S. A.M. Samsuri ◽  
M. M. Salleh ◽  
...  

Synthesis parameter plays important role in modifying physical property of metal oxide films which serve as photoanode in dye-sensitized solar cell (DSSC). This paper reports the synthesis of boron doped ZnO nanostructures via seed mediated growth hydrothermal technique and their application as photanode in DSSC. The growth process was carried out at various solution concentrations, 0.1, 0.2, 0.3 and 0.4 M. The solution contains 1 % wt. dimethyl borate as boron source, hexamethylenetetramine (HMT) surfactant and zinc nitrate (Zn(NO3)2). The samples are crystalline with wurtzite phase. The morphological shape of the samples changes with the growth solution concentration. The optical absorption increases as the concentration increases. However, the band gap does not significantly change with the concentration. The DSSC utilizing the ZnO sample prepared at 0.1 M solution performs the best photovoltaic parameters with the JSC of 0.969 mA cm-2, FF of 0.48 and η of 0.222%, respectively since it shows the highest absorption and lowest photoluminescence in visible region.


2001 ◽  
Vol 5 (8) ◽  
pp. 609-616 ◽  
Author(s):  
Viviane Aranyos ◽  
Johan Hjelm ◽  
Anders Hagfeldt ◽  
Helena Grennberg
Keyword(s):  

1981 ◽  
Vol 42 (C4) ◽  
pp. C4-475-C4-478
Author(s):  
C. R. Wronski ◽  
Y. Goldstein ◽  
S. Kelemen ◽  
B. Abeles ◽  
H. Witzke

2020 ◽  
pp. 114-119

Experimental and theoretical study Porphyrin-grafted ZnO nanowire arrays were investigated for organic/inorganic hybrid solar cell applications. Two types of porphyrin – Tetra (4-carboxyphenyle) TCPP and meso-Tetraphenylporphine (Zinc-TPP)were used to modify the nanowire surfaces. The vertically aligned nanowires with porphyrin modifications were embedded in graphene-enriched poly (3-hexylthiophene) [G-P3HT] for p-n junction nanowire solar cells. Surface grafting of ZnO nanowires was found to improve the solar cell efficiency. There are different effect for the two types of porphyrin as results of Zn existing. Annealing effects on the solar cell performance were investigated by heating the devices up to 225 °C in air. It was found that the cell performance was significantly degraded after annealing. The degradation was attributed to the polymer structural change at high temperature as evidenced by electrochemical impedance spectroscopy measurements.


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