Application of a new choline-imidazole based deep eutectic solvents in hybrid magnetic molecularly imprinted polymer for efficient and selective removal of naproxen from aqueous samples

2021 ◽  
pp. 124228
Author(s):  
Nor Aniisah Husin ◽  
Musthahimah Muhamad ◽  
Noorfatimah Yahaya ◽  
Mazidatulakmam Miskam ◽  
Nik Nur Syazni Nik Mohamed Kamal ◽  
...  
Keyword(s):  
Molecularly Imprinted Polymer ◽  
Deep Eutectic Solvents ◽  
Selective Removal ◽  
Aqueous Samples ◽  
Imprinted Polymer ◽  
Molecularly Imprinted ◽  
Magnetic Molecularly Imprinted Polymer

In situ controllable synthesis of graphene oxide-based ternary magnetic molecularly imprinted polymer hybrid for efficient enrichment and detection of eight microcystins

2015 ◽  
Vol 3 (45) ◽  
pp. 23042-23052 ◽  
Author(s):  
Sheng-Dong Pan ◽  
Xiao-Hong Chen ◽  
Xiao-Ping Li ◽  
Mei-Qiang Cai ◽  
Hao-Yu Shen ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Molecularly Imprinted Polymer ◽  
Sensitive Detection ◽  
Imprinted Polymer ◽  
Controllable Synthesis ◽  
Molecularly Imprinted ◽  
Magnetic Molecularly Imprinted Polymer ◽  
Highly Efficient ◽  
Polymer Hybrid

A novel graphene oxide-based ternary magnetic molecularly imprinted polymer hybrid was synthesized for highly efficient enrichment and sensitive detection of microcystins.

scholarly journals Removal of bisphenol A from aqueous media using a highly selective adsorbent of hybridization cyclodextrin with magnetic molecularly imprinted polymer

2021 ◽  
Vol 8 (3) ◽  
Author(s):  
S. Mamman ◽  
F. B. M. Suah ◽  
M. Raaov ◽  
F. S. Mehamod ◽  
S. Asman ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Molecularly Imprinted Polymer ◽  
Binding Capacity ◽  
Bulk Polymerization ◽  
Resonance Spectroscopy ◽  
Template Molecule ◽  
Order Kinetic ◽  
Imprinted Polymer ◽  
Molecularly Imprinted ◽  
Magnetic Molecularly Imprinted Polymer

In this study, a unique magnetic molecularly imprinted polymer (MMIP) adsorbent towards bisphenol A (BPA) as a template molecule was developed by bulk polymerization using β-cyclodextrin (β-CD) as a co-monomer with methacrylic acid (MAA) to form MMIP MAA–βCD as a new adsorbent. β-CD was hybridized with MAA to obtain water-compactible imprinting sites for the effective removal of BPA from aqueous samples. Benzoyl peroxide and trimethylolpropane trimethacrylate were used as the initiator and cross-linker, respectively. The adsorbents were characterized by Fourier transform infrared spectroscopy, scanning electronic microscopy, transmission electron microscopy, vibrating sample magnetometer, Brunauer–Emmett–Teller and X-ray diffraction. 1 H nuclear magnetic resonance spectroscopy was used to characterize the MAA–βCD and BPA–MAA–βCD complex. Several parameters influencing the adsorption efficiency of BPA such as adsorbent dosage, pH of sample solution, contact time, initial concentrations and temperature as well as selectivity and reusability study have been evaluated. MMIP MAA–βCD showed significantly higher removal efficiency and selective binding capacity towards BPA compared to MMIP MAA owing to its unique morphology with the presence of β-CD. The kinetics data can be well described by the pseudo second-order kinetic and Freundlich isotherm and Halsey models best fitted the isotherm data. The thermodynamic studies indicated that the adsorption reaction was a spontaneous and exothermic process. Therefore, MMIP based on the hybrid monomer of MAA–βCD shows good potential of a new monomer in molecularly imprinted polymer preparation and can be used as an effective adsorbent for the removal of BPA from aqueous solutions.

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