Novel Cu-bearing high-strength pipeline steels with excellent resistance to hydrogen-induced cracking

2016 ◽  
Vol 92 ◽  
pp. 300-305 ◽  
Author(s):  
Xianbo Shi ◽  
Wei Yan ◽  
Wei Wang ◽  
Yiyin Shan ◽  
Ke Yang
2008 ◽  
Author(s):  
Jr, C J McMahon ◽  
Xinyu Liu ◽  
Jun Kameda ◽  
Michael J Morgan

2021 ◽  
Vol 28 (2) ◽  
pp. 249-256 ◽  
Author(s):  
En-dian Fan ◽  
Shi-qi Zhang ◽  
Dong-han Xie ◽  
Qi-yue Zhao ◽  
Xiao-gang Li ◽  
...  

2009 ◽  
Vol 502 (1-2) ◽  
pp. 38-44 ◽  
Author(s):  
Wei Wang ◽  
Yiyin Shan ◽  
Ke Yang

Author(s):  
M. Elboujdaini ◽  
R. W. Revie ◽  
M. Attard

A comparison was made between four strength levels of pipeline steels (X-70, X80, X-100 and the X-120) from the point of view of their susceptibility to hydrogen embrittlement under cathodic protection. The main aim was to determine whether the development of higher strength materials led to greater susceptibility to hydrogen embrittlement. This was achieved by straining at 2×10−6 s−1 after cathodic charging in a simulated dilute groundwater solution (NS4) containing 5% CO2/95% N2 (pH approximately 6.7). The results showed quantitatively the loss of ductility after charging, and the loss of ductility increases with strength level of the steel. All four steels exhibited a loss of ductility at overprotected charging potential and an increasing amount of brittleness on the fracture surface. Ductility in solution was measured under four different levels of cathodic protection, ranging from no cathodic protection to 500 mV of overprotection with respect to the usually accepted criterion of −850 mV vs. Cu/CuSO4 reference electrode. Experiments were carried out by straining during cathodic polarization in a simulated dilute ground water solution (NS-4 solution). Strain rates used were 2×10−6 s−1. After failure, the fracture surfaces were characterized by examination using scanning electron microscopy (SEM). Under cathodic protection, all four steels showed loss of ductility and features of brittle fracture. The loss of ductility under cathodic polarization was larger the greater the strength of the steel and the more active (i.e., more negative) the applied potential. The Ductility Reduction Index (DRI) was defined to quantify the reduction in ductility.


2014 ◽  
pp. 583-595
Author(s):  
Yongqing Zhang ◽  
Chengjia Shang ◽  
Aimin Guo ◽  
Lei Zheng ◽  
Tao Niu ◽  
...  

Author(s):  
Frank Barbaro ◽  
Zhixiong Zhu ◽  
Lenka Kuzmikova ◽  
Huijun Li ◽  
Han Jian

Author(s):  
Douglas G. Stalheim ◽  
Bernhard Hoh

Worldwide oil and natural gas reserves can be classified as either sweet or sour service. The sour service classified oil and natural gas reserves contain some level of H2S making the product flowing through a steel pipeline corrosive. Due to this, the majority of the oil and natural gas reserves that have been drilled are of the sweet service nature. However as demand continues and supplies change, many of the remaining oil and natural gas reserves contain the H2S component and are of a sour service nature. These oil and natural gas reserves containing the H2S component through a corrosion mechanism will allow for diatomic hydrogen — in the presence of moisture — to disseminate to monatomic hydrogen and diffuse into the pipeline steel microstructure. Depending on the microstructure and level of cleanliness the monatomic hydrogen can become trapped at areas of high residual stress, recollect to diatomic hydrogen and creating partial pressures that exceed the tensile strength of the steel resulting in cracking. Therefore transmission pipelines are being built to transport sour service oil or natural gas requires steels with hydrogen induced cracking (HIC) resistance. Alloy designs, steel making processing, continuous casting, plate or strip rolling, pipe forming, and last not least corrosion testing are all key components in producing pipeline steels that are resistant to HIC applications and meeting the NACE TM0284 specifications. However, producing steels that have good HIC performance do not necessarily meet other mechanical property requirements such as strength and YT ratios. Balance has to be achieved to meet not only the HIC requirements but the other required mechanical properties. Mastering this complex HIC process poses a serious challenge to pipe producers and their primary material suppliers. The capability of producing HIC steel grades according to critical specifications and/or standards clearly distinguishes excellent steel producers from good steel makers. This paper will discuss the basics of the hydrogen induced cracking phenomenon, the requirements of the NACE TM0284 specification and give guidelines for steel production of API pipeline steels that not only can meet the specification requirements the NACE testing but also fulfill the other mechanical property requirements.


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