Diffusion of aniline through a polyethylene terephthalate track-etched membrane

2009 ◽  
Vol 330 (1-2) ◽  
pp. 145-155 ◽  
Author(s):  
A.A. Belkova ◽  
A.I. Sergeeva ◽  
P.Y. Apel ◽  
M.K. Beklemishev
2019 ◽  
Vol 488 (1) ◽  
pp. 44-46
Author(s):  
S. L. Bazhenov ◽  
I. V. Razumovskaya ◽  
N. P. Kovalets ◽  
S. A. Bedin

Behavior of metallic nano-coating of the track membrane based on polyethylene terephthalate film under tension was investigated. In the vicinity of cracks in the coating, conical-shaped debondings of the coatings were observed. Debondings have the form of sharp cones, elongated along the tension axis and perpendicular to the cracks. Nanopores initiate multiple cracking of the coating, and the cracks initiate local debondings. Short microcracks mutually suppress their growth. As a result, long cracks crossing the entire coating do not appear. As a result, the coating retains its continuity and conducts electric current.


2019 ◽  
Vol 25 (1) ◽  
pp. 117-125 ◽  
Author(s):  
Wenxiong Lin ◽  
Huagang Liu ◽  
Haizhou Huang ◽  
Jianhong Huang ◽  
Kaiming Ruan ◽  
...  

PurposeThe purpose of this paper is to explore the possibility of an enhanced continuous liquid interface production (CLIP) with a porous track-etched membrane as the oxygen-permeable window, which is prepared by irradiating polyethylene terephthalate membranes with accelerated heavy ions. Design/methodology/approachExperimental approaches are carried out to characterize printing parameters of resins with different photo-initiator concentrations by a photo-polymerization matrix, to experimentally observe and theoretically fit the oxygen inhibition layer thickness during printing under conditions of pure oxygen and air, respectively, and to demonstrate the enhanced CLIP processes by using pure oxygen and air, respectively. FindingsOwing to the high permeability of track-etched membrane, CLIP process is demonstrated with printing speed up to 800 mm/h in the condition of pure oxygen, which matches well with the theoretically predicted maximum printing speed at difference light expose. Making a trade-off between printing speed and surface quality, maximum printing speed of 470 mm/h is also obtained even using air. As the oxygen inhibition layer created by air is thinner than that by pure oxygen, maximum speed cannot be simply increased by intensifying the light exposure as the case with pure oxygen. Originality/valueCLIP process is capable of building objects continuously instead of the traditional layer-by-layer manner, which enables tens of times improvement in printing speed. This work presents an enhanced CLIP process by first using a porous track-etched membrane to serve as the oxygen permeable window, in which a record printing speed up to 800 mm/h using pure oxygen is demonstrated. Owing to the high permeability of track-etched membrane, continuous process at a speed of 470 mm/h is also achieved even using air instead of pure oxygen, which is of significance for a compact robust high-speed 3D printer.


2019 ◽  
Vol 488 (1) ◽  
pp. 117-119
Author(s):  
S. L. Bazhenov ◽  
I. V. Razumovskaya ◽  
N. P. Kovalets ◽  
S. A. Bedin

2017 ◽  
Vol 57 (4) ◽  
pp. 347-352
Author(s):  
S. N. Podoynitsyn ◽  
O. N. Sorokina ◽  
A. L. Kovarski ◽  
T. V. Tsyganova ◽  
I. I. Levin ◽  
...  

2008 ◽  
Vol 22 (14) ◽  
pp. 1415-1421 ◽  
Author(s):  
SANJEEV KUMAR ◽  
S. K. CHAKARVARTI

In the present work, electrolytic transport phenomena is studied for different electrolytes ( LiCl , NaCl , KCl of different concentrations) at room temperature (25 ± 2° C ) through etched pores with different diameters having cylindrical shape in track-etched membranes of polyethylene terepthalate (PET) with pore density of the order of 106/cm2. Electric potential has been used as the driving force. It has been observed that electrolytic transport through pores is different for different electrolytes, depending strongly on size of cations and is independent of size of anions. In the case of cylindrical pores, there has not been found appreciable change in forward and backward resistances.


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