High barrier graphene oxide nanosheet/poly(vinyl alcohol) nanocomposite films

2012 ◽  
Vol 409-410 ◽  
pp. 156-163 ◽  
Author(s):  
Hua-Dong Huang ◽  
Peng-Gang Ren ◽  
Jun Chen ◽  
Wei-Qin Zhang ◽  
Xu Ji ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Vinyl Alcohol ◽  
Nanocomposite Films ◽  
Poly Vinyl Alcohol ◽  
Graphene Oxide Nanosheet

Nanocomposite Films of Poly(vinyl alcohol)-Grafted Graphene Oxide/Poly(vinyl alcohol) for Gas Barrier Film Applications

2015 ◽  
Vol 15 (10) ◽  
pp. 8348-8352 ◽  
Author(s):  
Min Eui Lee ◽  
Hyoung-Joon Jin
Keyword(s):  
Graphene Oxide ◽  
Vinyl Alcohol ◽  
Transmission Rate ◽  
Barrier Properties ◽  
Nanocomposite Films ◽  
Strong Interactions ◽  
Poly Vinyl Alcohol ◽  
Gas Barrier ◽  
Oxygen Transmission Rate ◽  
Gas Barrier Properties

Poly(vinyl alcohol) (PVA) composites containing graphene oxide (GO) functionalized with PVA were synthesized via the esterification of the carboxylic groups of GO. The presence of PVA-grafted GO (PVA-g-GO) in the PVA matrix induced strong interactions between the chains of the PVA matrix and allowed the PVA-g-GO to be uniformly dispersed throughout the matrix. The grafting of PVA to GO increased the gas barrier properties of the GO/PVA composites because of the increased compatibility between GO and PVA. The PVA-g-GO/PVA composites were used to coat the surface of poly(ethylene terephthalate) films. These coated films exhibited excellent gas barrier properties; the film containing 0.3 wt% of PVA-g-GO had an oxygen transmission rate (OTR) of 0.025 cc/(m2 · day) and an optical transmittance of 83.8%. As a result, PVA-g-GO/PVA composites that exhibited enhanced gas barrier properties were prepared with a solution mixing method.

High Mechanical Performance of Layered Graphene Oxide/Poly(vinyl alcohol) Nanocomposite Films

Small ◽  
2013 ◽  
Vol 9 (14) ◽  
pp. 2466-2472 ◽  
Author(s):  
Luqi Liu ◽  
Yun Gao ◽  
Qing Liu ◽  
Jun Kuang ◽  
Ding Zhou ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Vinyl Alcohol ◽  
Mechanical Performance ◽  
Nanocomposite Films ◽  
Poly Vinyl Alcohol

scholarly journals Dielectric Relaxation Behavior of Silver Nanoparticles and Graphene Oxide Embedded Poly(vinyl alcohol) Nanocomposite Film: An Effect of Ionic Liquid and Temperature

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 374 ◽  
Author(s):  
Ganeswar Sahu ◽  
Mamata Das ◽  
Mithilesh Yadav ◽  
Bibhu Prasad Sahoo ◽  
Jasaswini Tripathy
Keyword(s):  
Electron Microscopy ◽  
Ionic Liquid ◽  
Graphene Oxide ◽  
Dielectric Permittivity ◽  
Dielectric Relaxation ◽  
Ag Nanoparticles ◽  
Vinyl Alcohol ◽  
Nanocomposite Films ◽  
Poly Vinyl Alcohol ◽  
Dielectric Relaxation Behavior

This paper presents the dielectric characteristics of nanocomposite films of poly(vinyl alcohol) (PVA) embedded with silver (Ag) nanoparticles and graphene oxide(GO). The nanocomposite films were fabricated by using the solvent casting approach. The morphological analysis was carried out through scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The dielectric relaxation behavior of nanocomposite films was analyzed in the frequency range of 101 to 106 Hz, by varying GO loading. The temperature effect was investigated over the temperature range of 40 to 150 °C. The effect of ionic liquid (IL) was also explored by comparing the dielectric behavior of films fabricated without using ionic liquid. The conductive filler loading variation showed a significant effect on dielectric permittivity(ε′), complex impedance (Z*) and electric conductivity (σac). The obtained results revealed that the dielectric permittivity (ε′) increased by incorporating Ag nanoparticles and increasing GO loading in PVA matrix. An incremental trend in dielectric permittivity was observed on increasing the temperature, which is attributed to tunneling and hopping mechanism. With an increase in nanofiller loading, the real part of impedance (Z′) and imaginary part of impedance (Z″) were found to decrease. Further, the semicircular nature of Nyquist plot indicated the decrease in bulk resistivity on increasing GO loading, temperature and incorporating ionic liquid. On the basis of above findings, the obtained GO-Ag-PVA nanocomposite films can find promising applications in charge storage devices.

scholarly journals Properties and structural characterization of chitosan/poly(vinyl alcohol)/graphene oxide nano composites

e-Polymers ◽  
2012 ◽  
Vol 12 (1) ◽  
Author(s):  
Jun Ma ◽  
Changhua Liu ◽  
Rui Li ◽  
Jia Wang
Keyword(s):  
Graphene Oxide ◽  
Vinyl Alcohol ◽  
Tensile Testing ◽  
Nanocomposite Films ◽  
Poly Vinyl Alcohol ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Force Microscopy ◽  
Atomic Force ◽  
Uniform Dispersion

AbstractChitosan (CS)/poly(vinyl alcohol) (PVA)/graphene oxide (GO) nanocomposites in the form of films are prepared in a casting and solvent evaporation method. Fourier-transform infrared spectroscopy (FTIR), X-ray diffractions (XRD), atomic force microscopy (AFM), thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC), tensile testing and moisture uptake were used to study the structure and properties of these chitosan/poly(vinyl alcohol) /graphene oxide (PCS/GO-n) nanocomposites. The result from tensile testing indicated that the nanocomposite containing 2 wt% GO exhibits high tensile strength (71.21 MPa) with a large elongation at break (51.8%). The high mechanical properties of the nanocomposite films are mainly due to uniform dispersion of GO sheets in the polymer matrix and strong interfacial interactions among components.

Poly (vinyl alcohol)/graphene oxide nanocomposite films and hydrogels prepared by gamma ray

2018 ◽  
Vol 48 (2) ◽  
pp. 42-47 ◽  
Author(s):  
Masoud Frounchi ◽  
Susan Dadbin ◽  
Mehrdad Tabatabaei
Keyword(s):  
Graphene Oxide ◽  
Vinyl Alcohol ◽  
Gamma Ray ◽  
Nanocomposite Films ◽  
Poly Vinyl Alcohol

scholarly journals Graphene Based Poly(Vinyl Alcohol) Nanocomposites Prepared by In Situ Green Reduction of Graphene Oxide by Ascorbic Acid: Influence of Graphene Content and Glycerol Plasticizer on Properties

Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 1013 ◽  
Author(s):  
Mónica Cobos ◽  
M. Fernández ◽  
M. Fernández
Keyword(s):  
Ascorbic Acid ◽  
Graphene Oxide ◽  
Water Absorption ◽  
Vinyl Alcohol ◽  
Nanocomposite Films ◽  
Ex Situ ◽  
Poly Vinyl Alcohol ◽  
Vapor Permeability ◽  
Water Barrier

The enhanced properties of polymer nanocomposites as compared with pure polymers are only achieved in the presence of well-dispersed nanofillers and strong interfacial adhesion. In this study, we report the preparation of nanocomposite films based on poly(vinyl alcohol) (PVA) filled with well dispersed graphene sheets (GS) by in situ reduction of graphene oxide (GO) dispersed in PVA solution using ascorbic acid (L-AA) as environmentally friendly reductant. The combined effect of GS content and glycerol as plasticizer on the structure, thermal, mechanical, water absorption, and water barrier properties of PVA/GS nanocomposite films is studied for the first time. Higher glass transition temperature, lower crystallinity, melting, and crystallization temperature, higher mechanical properties, and remarkable improvement in the thermal stability compared to neat PVA are obtained as a result of strong interfacial interactions between GS and PVA by hydrogen bonding. PVA/GS composite film prepared by ex situ process is more brittle than its in situ prepared counterpart. The presence of GS improves the water barrier and water resistance properties of nanocomposite films by decreasing water vapor permeability and water absorption of PVA. This work demonstrates that the tailoring of PVA/GS nanocomposite properties is enabled by controlling GS and glycerol content. The new developed materials, particularly those containing plasticizer, could be potential carriers for transdermal drug delivery.

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