High resolution X-ray photoelectron spectroscopic analysis of transformation of surface chromium species on Phillips CrOx/SiO2 catalysts isothermally calcined at various temperatures
Abstract
Based on observations with the Chandra X-ray Observatory, we present the latest spectral evolution of the X-ray remnant of SN 1987A (SNR 1987A). We present a high-resolution spectroscopic analysis using our new deep (∼312 ks) Chandra HETG observation taken in 2018 March as well as archival Chandra grating spectroscopic data taken in 2004, 2007, and 2011 with similarly deep exposures (∼170–350 ks). We perform detailed spectral model fits to quantify changing plasma conditions over the last 14 yr. Recent changes in electron temperatures and volume-emission measures suggest that the shocks moving through the inner ring have started interacting with less dense circumstellar material, probably beyond the inner ring. We find significant changes in the X-ray line-flux ratios (among H- and He-like Si and Mg ions) in 2018, consistent with changes in the thermal conditions of the X-ray-emitting plasma that we infer based on the broadband spectral analysis. Post-shock electron temperatures suggested by line-flux ratios are in the range ∼0.8–2.5 keV as of 2018. We do not yet observe any evidence of substantial abundance enhancement, suggesting that the X-ray emission component from the reverse-shocked metal-rich ejecta is not yet significant in the observed X-ray spectrum.
Spectroscopic analysis is a powerful technique for the diagnosis of temperatures and compositions of astrophysical plasmas. The EUV (100–1000Å) and soft x-ray (10–100Å) bands contain hundreds of potentially useful diagnostic lines. Unfortunately, traditional types of grating spectrometer become inefficient or unwieldy when adapted to stellar spectroscopy onboard a spacecraft. At grazing incidence, the required length of a high-resolution plane-grating spectrometer can easily exceed the length of the telescope feeding it. For these reasons, we have systematically explored ways to introduce a reflection grating into the converging beam formed by a given objective optical system ahead of its first focus. A spectrometer of this type results in an optical train no longer than the telescope’s existing prime-focus beam.
Proteolytic digestion of the immunoglobulin IgG with papain cleaves the molecule into an antigen binding fragment, Fab, and a compliment binding fragment, Fc. Structures of intact immunoglobulin, Fab and Fc from various sources have been solved by X-ray crystallography. Rabbit Fc can be crystallized as thin platelets suitable for high resolution electron microscopy. The structure of rabbit Fc can be expected to be similar to the known structure of human Fc, making it an ideal specimen for comparing the X-ray and electron crystallographic techniques and for the application of the molecular replacement technique to electron crystallography. Thin protein crystals embedded in ice diffract to high resolution. A low resolution image of a frozen, hydrated crystal can be expected to have a better contrast than a glucose embedded crystal due to the larger density difference between protein and ice compared to protein and glucose. For these reasons we are using an ice embedding technique to prepare the rabbit Fc crystals for molecular structure analysis by electron microscopy.
Polytypism has been studied for a number of years and a wide variety of stacking sequences has been detected and analysed. SiC is the prototype material in this respect; see e.g. Electron microscopy under high resolution conditions when combined with x-ray measurements is a very powerful technique to elucidate the correct stacking sequence or to study polytype transformations and deviations from the ideal stacking sequence.
The phenomenon of clustering in Al-Ag alloys has been extensively studied since the early work of Guinierl, wherein the pre-precipitation state was characterized as an assembly of spherical, ordered, silver-rich G.P. zones. Subsequent x-ray and TEM investigations yielded results in general agreement with this model. However, serious discrepancies were later revealed by the detailed x-ray diffraction - based computer simulations of Gragg and Cohen, i.e., the silver-rich clusters were instead octahedral in shape and fully disordered, atleast below 170°C. The object of the present investigation is to examine directly the structural characteristics of G.P. zones in Al-Ag by high resolution transmission electron microscopy.
High resolution scanning electron microscopy (SEM) and energy dispersive x-ray analysis (EDXA) were performed to investigate microparticles in blended cements and their hydration products containing sodium-rich chemical wastes. The physical appearance of powder particles and the morphological development at different hydration stages were characterized by using high resolution SEM Hitachi S-900 and by SEM S-800 with a EDX spectrometer. Microparticles were dispersed on the sample holder and glued by 1% palomino solution. Hydrated bulk samples were dehydrated by acetone and mounted on the holder by silver paste. Both fracture surfaces and flat cutting sections of hydrating samples were prepared and examined. Some specimens were coated with an 3 nm thick Au-Pd or Cr layer to provide good conducting surfaces. For high resolution SEM S-900 observations the accelerating voltage of electrons was 1-2 KeV to protect the electron charging. Microchemical analyses were carried out by S800/EDS equipped with a LINK detector of take-off angle =40°.
Construction of a Wide-range High-resolution Beamline BL05 in NewSUBARU for Soft X-ray Spectroscopic Analysis on Industrial Materials