scholarly journals Recyclability of water-soluble ruthenium–phosphine complex catalysts in multiphase selective hydrogenation of cinnamaldehyde using toluene and pressurized carbon dioxide

2006 ◽  
Vol 249 (1-2) ◽  
pp. 223-229 ◽  
Author(s):  
Shin-ichiro Fujita ◽  
Shuji Akihara ◽  
Masahiko Arai
ChemInform ◽  
2005 ◽  
Vol 36 (12) ◽  
Author(s):  
Fengyu Zhao ◽  
Shin-ichio Fujita ◽  
Jianmin Sun ◽  
Yutaka Ikushima ◽  
Masahiko Arai

Author(s):  
Ana Aguiar-Ricardo ◽  
Vasco D. B. Bonifácio ◽  
Teresa Casimiro ◽  
Vanessa G. Correia

The integrated use of supercritical carbon dioxide (scCO 2 ) and micro- and nanotechnologies has enabled new sustainable strategies for the manufacturing of new medications. ‘Green’ scCO 2 -based methodologies are well suited to improve either the synthesis or materials processing leading to the assembly of three-dimensional multifunctional constructs. By using scCO 2 either as C1 feedstock or as solvent, simple, economic, efficient and clean routes can be designed to synthesize materials with unique properties such as polyurea dendrimers and oxazoline-based polymers/oligomers. These new biocompatible, biodegradable and water-soluble polymeric materials can be engineered into multifunctional constructs with antimicrobial activity, targeting moieties, labelling units and/or efficiently loaded with therapeutics. This mini-review highlights the particular features exhibited by these materials resulting directly from the followed supercritical routes.


2014 ◽  
Vol 94 ◽  
pp. 138-146 ◽  
Author(s):  
Shang-Jung Yang ◽  
Jia-Jiuan Wu ◽  
Yuan-Chuen Wang ◽  
Chih-Feng Huang ◽  
Tzong-Ming Wu ◽  
...  

Holzforschung ◽  
1999 ◽  
Vol 53 (2) ◽  
pp. 161-166 ◽  
Author(s):  
Martin Hofrichter ◽  
Katrin Scheibner ◽  
Friedemann Bublitz ◽  
Ivonne Schneegaß ◽  
Dirk Ziegenhagen ◽  
...  

SummaryManganese peroxidase preparations (MnP) from the white-rot fungusNematoloma frowardiiwere able to release14CO2directly from14C-labeled milled wheat straw (MWS; total lignin fraction) and milled straw lignin (MSL; dioxane soluble part of MWS). Apart from the formation of14CO2(4–10 %) the treatment of insoluble MWS and MSL with MnP resulted in the formation of water-soluble14C-lignin fragments (lignin solubilization, 14–25%). Analyses with gel permeation chromatography (GPC) demonstrated the formation of lignin fragments with predominant molecular masses around 1 kDa. The extent of MWS mineralization and solubilization was enhanced in the presence of reduced glutathione (GSH) acting as thiol mediator, whereas MSL mineralization was not stimulated by GSH. The principle of direct extracellular mineralization of lignin catalyzed by the MnP system may make a significant contribution to the formation of carbon dioxide in lignincellulose containing habitats.


Author(s):  
Manabu Iwai ◽  
Ryouta Yamashita ◽  
Satoshi Anzai ◽  
Shinichi Ninomiya

Abstract The authors have proposed a micro bubble coolant in which micro bubbles (20∼50μm in diameter) are included in water soluble coolant. In the previous study, it was confirmed that the tool life was improved by applying the micro bubble coolant to various machining operations such as drilling, turning and grinding. Also, purification effects of the micro bubble coolant were found. In this study, micro bubble coolant in which inert gases (N2 and CO2) were mixed was proposed to be applied to grinding processes for further improvement in grinding performances. When nitrogen gas (2L/min) was mixed with the micro bubble in the water soluble coolant (70L), amount of the dissolved oxygen in coolant decreased to 0.5mg/L. And concentration of the carbon dioxide gas in the coolant increased to 100mg/L when carbon dioxide gas (2L/min) was mixed in. From the result of grinding test on high speed steel, it was found that grinding performances improved when the micro bubble coolant with any of air, N2 and CO2 gases was used. The grinding force decreased by a factor of about 15% and the tool life increased by 20∼30%. When nitrogen gas was mixed in, the surface roughness improved by about 15%. In grinding stainless steels, performances such as grinding force, tool life and surface roughness improved by 10% when nitrogen gas was mixed in. In addition, a tendency of flank wear reduction and improvement in the surface roughness were observed when air micro bubble was mixed into the coolant in the turning of high carbon steel and Inconel 718 as well. When N2 micro bubble was generated in the coolant, a flank wear was reduced by 20% and surface roughness was improved by 30 to 40%. These effects were higher than the coolant with air micro bubble.


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