Superalkali-alkalide ion pairs δ+(M-HMHC)-M’ δ - (M, M’ = Li, Na and K) serving as high-performance NLO molecular materials

2021 ◽  
pp. 118101
Author(s):  
Yin-Feng Wang ◽  
Jiangen Huang ◽  
Zhi-Jun Wang ◽  
Xue-Xia Liu ◽  
Jia Li ◽  
...  
2008 ◽  
Vol 65 (1) ◽  
pp. 99-101 ◽  
Author(s):  
Vasyl Sidey

Using the least-squares refinement procedure, high-performance Brown–Wu bond-valence parameters, r 0 and n, reported for the Sn2+/O2−, Sb3+/O2−, Te4+/O2− and I5+/O2− ion pairs have been converted into the commonly used bond-valence parameters, r 0 and b. The r 0 and b values obtained can be recommended as a replacement for the conventional bond-valence parameters based on the `universal constant' b = 0.37 Å.


MRS Bulletin ◽  
1997 ◽  
Vol 22 (6) ◽  
pp. 39-45 ◽  
Author(s):  
Tetsuo Tsutsui

Organic electroluminescence (EL) is moving from a simple curiosity in laboratories to the reality of commercial use. The day will soon arrive when high-quality green EL displays find practical usage. Charge-injection-type EL involves the combination of positive and negative charge carriers injected from electrodes in contact with an organic thin film. The occurrence of EL through bipolar charge injection into organic solids was clarified for single crystals of anthracene and related compounds in the 1960s. Few new developments in physics exist today for organic EL. However worldwide enthusiasm for charge-injection-type EL, which started in the mid-1980s, has been increasing rapidly. The motivation for this renewed interest is straightforward. High-efficiency surface emission across the whole visible spectral range can be obtained easily, and prospects now exist for full-color flat-panel-display technology.Since the demonstration of high-performance EL devices made of multilayers of vacuum-sublimed dye films by Tang and VanSlyke, much progress has occurred in the research and development of EL devices made from molecular materials. A variety of molecular materials such as vacuum-sublimed dye films, fully π-conjugated polymers, polymers with chromophores orr skeletal chains, or side chains, and polymer-dispersed dye films can be used for EL devices.Among a variety of EL devices, multilayer-structure versions made of vacuum-sublimed dye films exhibit the best performance. Application-oriented research in the development of high-quality flat-panel displays has been performed during the past 10 years, mainly in Japan's private-sector laboratories.


2009 ◽  
Vol 94 (6) ◽  
pp. 063304 ◽  
Author(s):  
Hiroshi Kageyama ◽  
Hitoshi Ohishi ◽  
Masatake Tanaka ◽  
Yutaka Ohmori ◽  
Yasuhiko Shirota

1982 ◽  
Vol 65 (3) ◽  
pp. 730-736
Author(s):  
Marc L Puttemans ◽  
Louis Dryon ◽  
Désiré L Massart

Abstract Food dyes, extracted into chloroform as ion-pairs with tri-n-octylamine, are chromatographed directly in various liquid chromatographic systems. Dyes can be identified by comparison of the chromatographic behavior of ion-pairs with behavior of reference dyes dissolved in water. In thin layer and paper chromatography, the ion-pairs dissociate when polar eluants are used; thin layer chromatography is preferred because of less tailing. In high performance liquid chromatography, a reverse phase ion-pair system is used with tetrabutylammonium as the counter ion; chloroform-extracted dyes show retention times similar to reference dyes dissolved in water.


1989 ◽  
Vol 35 (5) ◽  
pp. 794-799 ◽  
Author(s):  
J Iwata ◽  
T Suga

Abstract We describe a direct method for determining four sulfates and seven glucuronides of 17-oxosteroids (17OS) in urine without hydrolysis, by use of "high-performance" liquid chromatography (HPLC) with fluorometric detection. After pretreatment of urine samples with a Sep-Pak C18 cartridge, four 17OS sulfates and seven 17OS glucuronides in the pretreated urine samples were reacted with tetrapentylammonium ions to form ion pairs. Ion-paired 17OS sulfates were extracted with benzene. By adding sodium sulfate to the remaining sample, we could then extract ion-paired 17OS glucuronides with dichloromethane. Each extract was labeled with dansyl-hydrazine in an acetic acid-acetonitrile solution. The labeled steroids were separated by HPLC on a reversed-phase Capcell-Pak C8 (silicon-polymer-coated silica gel modified with octyl groups). We monitored each effluent with a fluorometric detector (330 nmexcitation, 535 nmemission).


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