Enhanced efficiency and current density of solar cells via energy-down-shift having energy-tuning-effect of highly UV-light-harvesting Mn2+-doped quantum dots

Nano Energy ◽  
2017 ◽  
Vol 33 ◽  
pp. 257-265 ◽  
Author(s):  
Mohammed Jalalah ◽  
Yun-Hyuk Ko ◽  
Farid A. Harraz ◽  
M.S. Al-Assiri ◽  
Jea-Gun Park
Nanomaterials ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 291 ◽  
Author(s):  
Askar A. Maxim ◽  
Shynggys N. Sadyk ◽  
Damir Aidarkhanov ◽  
Charles Surya ◽  
Annie Ng ◽  
...  

Perovskite solar cells (PSCs) with a standard sandwich structure suffer from optical transmission losses due to the substrate and its active layers. Developing strategies for compensating for the losses in light harvesting is of significant importance to achieving a further enhancement in device efficiencies. In this work, the down-conversion effect of carbon quantum dots (CQDs) was employed to convert the UV fraction of the incident light into visible light. For this, thin films of poly(methyl methacrylate) with embedded carbon quantum dots (CQD@PMMA) were deposited on the illumination side of PSCs. Analysis of the device performances before and after application of CQD@PMMA photoactive functional film on PSCs revealed that the devices with the coating showed an improved photocurrent and fill factor, resulting in higher device efficiency.


2021 ◽  
Vol 8 (3) ◽  
Author(s):  
Kulrisa Kuntamung ◽  
Patrawadee Yaiwong ◽  
Chutiparn Lertvachirapaiboon ◽  
Ryousuke Ishikawa ◽  
Kazunari Shinbo ◽  
...  

We studied the effect of gold quantum dots (AuQDs)/grating-coupled surface plasmon resonance (GC-SPR) in inverted organic solar cells (OSCs). AuQDs are located within a GC-SPR evanescent field in inverted OSCs, indicating an interaction between GC-SPR and AuQDs' quantum effects, subsequently giving rise to improvement in the performance of inverted OSCs. The fabricated solar cell device comprises an ITO/TiO 2 /P3HT : PCBM/PEDOT : PSS : AuQD/silver grating structure. The AuQDs were loaded into a hole transport layer (PEDOT : PSS) of the inverted OSCs to increase absorption in the near-ultraviolet (UV) light region and to emit visible light into the neighbouring photoactive layer, thereby achieving light-harvesting improvement of the device. The grating structures were fabricated on P3HT:PCBM layers using a nanoimprinting technique to induce GC-SPR within the inverted OSCs. The AuQDs incorporated within the strongly enhanced GC-SPR evanescent electric field on metallic nanostructures in the inverted OSCs improved the short-circuit current and the efficiency of photovoltaic devices. In comparison with the reference OSC and OSCs with only green AuQDs or only metallic grating, the developed device indicates enhancement of up to 16% power conversion efficiency. This indicates that our light management approach allows for greater light utilization of the OSCs because of the synergistic effect of G-AuQDs and GC-SPR.


2017 ◽  
Vol 5 (3) ◽  
pp. 654-662 ◽  
Author(s):  
Rezvan Soltani ◽  
Ali Asghar Katbab ◽  
Kerstin Schaumberger ◽  
Nicola Gasparini ◽  
Christoph J. Brabec ◽  
...  

PCE is improved owing to the enhanced JSC, resulting from larger light harvesting and higher charge generation.


2019 ◽  
Vol 52 (50) ◽  
pp. 505108
Author(s):  
Shun Chan ◽  
Dongyoung Kim ◽  
Mingchu Tang ◽  
Xiao Li ◽  
Huiyun Liu

2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
S. Abdallah ◽  
N. Al-Hosiny ◽  
Ali Badawi

The optical properties and photovoltaic characterization of CdS quantum dots sensitized solar cells (QDSSCs) were studied. CdS QDs were prepared by the chemical solution deposition (CD) technique. Photoacoustic spectroscopy (PA) was employed to study the optical properties of the prepared samples. The sizes of the CdS QDs were estimated from transmission electron microscope (TEM) micrographs gives radii ranged from 1.57 to 1.92 nm. The current density-voltage (J-V) characteristic curves of the assembled QDSSCs were measured. Fluorine doped Tin Oxide (FTO) substrates were coated with 20 nm-diameter TiO2nanoparticles (NPs). Presynthesized colloidal CdS quantum dots of different particles size were deposited on the TiO2-coated substrates using direct adsorption (DA) method. The FTO counter electrodes were coated with platinum, while the electroelectrolyte containingI-/I-3redox species was sandwiched between the two electrodes. The short current density (Jsc) and efficiency (η) increases as the particle size increases. The values ofJscincreases linearly with increasing the intensities of the sun light which indicates the greater sensitivity of the assembled cells.


Author(s):  
Ha Thanh Tung

In this study, we have prepared and investigated the optical properties of the TiO2/CdS:Mn2+/CdSe photoanode as the function of Mn2+ doping concentration and thickness. The results show that the peaks of the UV-Vis spectra shifted toward longer wavelength while Mn2+ doping concentrations or thickness of the films were changed. The main cause of the red-shifting in UV-Vis spectra may come from the increasing of photoanode light-harvesting capacity. In addition, the results also demonstrated by the boosting performance of quantum dots sensitized solar cells from 2.07% for TiO2/CdS/CdSe photoanode to 2.5% for TiO2/CdS:Mn2+/CdSe photoanode.


Author(s):  
Leimeng Xu ◽  
Shichen Yuan ◽  
Le Ma ◽  
Baisong Zhang ◽  
Fang Tao ◽  
...  

Solution-processed colloidal lead halide perovskite quantum dots (QDs) are considered as one of the promising candidates for the next-generation photovoltaics (PVs) due to the excellent optoelectronic properties and low-cost synthetic...


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