Influences of nano bio-filler on the fire-resistive and mechanical properties of water-based intumescent coatings

2018 ◽  
Vol 124 ◽  
pp. 33-40 ◽  
Author(s):  
Ming Chian Yew ◽  
Ming Kun Yew ◽  
Lip Huat Saw ◽  
Tan Ching Ng ◽  
Rajkumar Durairaj ◽  
...  
2019 ◽  
Vol 72 (2) ◽  
pp. 112 ◽  
Author(s):  
Matthew Russo ◽  
Holly Warren ◽  
Geoffrey M. Spinks ◽  
Douglas R. MacFarlane ◽  
Jennifer M. Pringle

Thermoelectrochemical cells are a promising new technology for harvesting low-grade waste heat. The operation of these cells relies on a redox couple within an electrolyte, which is most commonly water-based, and improvement of these materials is a key aspect of the advancement of this technology. Here, we report the gelation of aqueous electrolytes containing the K3Fe(CN)6/K4Fe(CN)6 redox couple using a range of different polymers, including polyvinyl alcohol (PVA), sodium carboxymethyl cellulose (Cmc), polyacrylamide (PAAm), and two commercial polyurethane-based polymers: HydroMed D640 and HydroSlip C. These polymers produce quasi-solid-state electrolytes with sufficient mechanical properties to prevent leakage, and allow improved device flexibility and safety. Furthermore, the incorporation of various ionic liquids within the optimized hydrogel network is investigated as a route to enhance the electrochemical and mechanical properties and thermal energy harvesting performance of the hydrogels.


2002 ◽  
Vol 740 ◽  
Author(s):  
Mats Carlsson ◽  
Mats Johnsson ◽  
Annika Pohl

ABSTRACTCeramic composites containing 2 and 5vol. % of nanosized commercially available TiN and SiC particles in alumina were prepared via a water based slurry processing route followed by spark plasma sintering (SPS) at 75 MPa in the temperature range 1200–1600°C. Some of the samples could be fully densified by use of SPS already after five minutes at 1200°C and 75 MPa. The aim was to control the alumina grain growth and thus obtain different nano-structure types. The microstructures have been correlated to some mechanical properties; e.g. hardness and fracture toughness.


Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 757 ◽  
Author(s):  
Abderrahman Aqlibous ◽  
Svetlana Tretsiakova-McNally ◽  
Talal Fateh

Flammability and combustion of softwood treated with intumescent coatings were studied in the present work. The formulations applied onto wood surfaces contained different ratios of industrial fillers, titanium dioxide TiO2 and aluminium trihydroxide Al(OH)3, and/or bio-fillers, eggshell and rice husk ash. Combustion behaviours of unprotected and protected wood samples have been examined with the aid of cone calorimetry performed under the varied levels of thermal flux ranging from 30 to 50 kW/m². The char residues obtained after the completion of cone calorimetry test at 40 kW/m² were analysed by the Raman spectroscopy. The fire protective properties of the studied coatings were strongly influenced by the nature of the fillers as well as by the intensity of thermal irradiance. The incorporation of bio-based fillers into the water-based intumescent formulations significantly improved fire resistance of wood substrates. For example, at 30 kW/m², the Effective Heat of Combustion was reduced by more than 40%, whilst the average Peak to Heat Release Rate had dropped from 193.2 to 150.3 kW/m² for the wood sample protected with the formulation incorporating two industrial and two bio-fillers. Moreover, an application of the studied coatings resulted in a notable reduction of the back surface temperature of the wood specimens.


2006 ◽  
Vol 309-311 ◽  
pp. 1219-1222 ◽  
Author(s):  
Seiji Ban ◽  
Masahiro Nawa ◽  
Y. Suehiro ◽  
H. Nakanishi

Yttria stabilized tetragonal zirconia polycrystals (Y-TZP) have been applied to dental crown and bridges. Whereas, to further improve its mechanical strength, the zirconia/alumina nano-composite stabilized with cerium oxide (Ce-TZP/Al2O3 nano-composite) was developed. In the present study, biaxial flexure strength, fracture toughness and hardness were determined before and after soaking in water-based conditions and the possibility of application to all ceramic dental restorations was discussed. In comparison to Y-TZP, Ce-TZP/Al2O3 nano-composite has quite high flexure strength and fracture toughness along with satisfied durability for LTAD in various water-based conditions encountered in dentistry. Therefore, it is concluded that the nano-composite can be safely applied to dental restoratives such as all-ceramic bridges.


2011 ◽  
Vol 331 ◽  
pp. 65-68
Author(s):  
Ge Wang ◽  
Fu Ming Chen ◽  
Hai Tao Cheng ◽  
Zi Xuan Yu ◽  
Ze Hui Jiang ◽  
...  

The objective of this work was to use a novel 3-D test analysis system for evaluating the mechanical properties of the natural fiber fabric composites under biaxial loads. Composites with three resin matrices (water-based epoxy resin, isocyanate resin, phenolic resin) were investigated, and strain filed were characterized by using the digital speckle correlation. The water-based epoxy resin plate and isocyanate resin plate demonstrated a characteristic of orthotropy and elastoplasticity, while the phenolic resin board revealed linear elastic and brittle-fracture simultaneously at X,Y-axial. Dissimilarities of biaxial load value were related to the orthotropy of composite structure, and load changes in fracture direction had a negative effect on the other directions at breaking moment. The degrees of dropping presented a positive correlation with the load values at rift direction. Under the linear elastic stage, the value of load and average strain at Y-direction were larger than that under X-direction within the same testing area. The strain-filed at X/Y-direction provided by isocyanate and phenolic resin plates illustrated a more smooth change than that of the water-based epoxy resin plate.


2020 ◽  
pp. 073490412096106
Author(s):  
Lars-Hendrik Daus ◽  
Bernhard Schartel ◽  
Volker Wachtendorf ◽  
Rolf Mangelsdorf ◽  
Manfred Korzen

A systematic approach was used to investigate the weathering-induced degradation of a common water–based intumescent coating. In this study, the coatings are intended for humid indoor applications on steel substrates. The coating contains ammonium polyphosphate, pentaerythritol, melamine, and polyvinyl acetate. By replacing each ingredient with a less water-soluble substance, the most vulnerable substances, polyvinyl acetate and pentaerythritol, were identified. Furthermore, the weathering resistance of the system was improved by exchanging the ingredients. The coatings were stressed by artificial weathering tests and evaluated by fire tests. Thermogravimetry and Fourier-transform infrared spectroscopy were used to study the thermal decomposition. This study lays the foundation for the development of a new generation of water-based intumescent coatings.


2020 ◽  
Vol 26 (2) ◽  
pp. 227-242
Author(s):  
Lilin Wu ◽  
Wei Qian ◽  
Jin Liu ◽  
Zezhuo Song ◽  
Debi Prasanna Kanungo ◽  
...  

ABSTRACT Natural sisal fiber is an environment-friendly and efficient material for soil reinforcement. Many studies have reported that the shear strength of soil has been improved by the addition of fiber. However, the mechanical properties of sand can be more effectively improved by the incorporation of water-based polymer and sisal fiber. An extensive laboratory testing program was conducted to determine the effect of water-based polyurethane and sisal fiber reinforcement on sand. Laboratory tests included sieve analysis, X-ray diffraction, conventional triaxial compression, and scanning electron microscopy (SEM) tests. The effects of polymer content (PC), fiber content (FC), fiber length (FL), and sample dry density (ρ) are thoroughly investigated. The results indicate that the increases of PC, FC, and ρ all improve the mechanical properties of sand. For FL, this improvement in shear strength was maintained to FLs of up to 18 mm. Beyond 18 mm, the shear strength decreased with further increase in FL. The mixing of polymer and fiber changes the failure mode from shear faulting to ductile flow. This indicates that the ductility of sand is improved. From the SEM images we found that sisal fibers, binding with colloidal materials formed by polymer, fill the sand voids and join the sand particles. This demonstrates that mixing of fiber and polymer can enhance the bonding of sand particles.


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