Protean morphology of waterborne polyurethane dispersion: An overview of nanoparticles from sphere to irregular elongated shape

2020 ◽  
Vol 146 ◽  
pp. 105742 ◽  
Author(s):  
Xing Zhou ◽  
Yaya Hao ◽  
Xinyu He ◽  
Dan Zhou ◽  
Li Xie ◽  
...  
Polymers ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 15
Author(s):  
Antonella Patti ◽  
Domenico Acierno

Polyurethane is a polymer adaptable to different scientific and industrial requirements; nevertheless it is also extremely susceptible to UV radiation, which compromises the physical and mechanical functionality. In this framework, our study investigated the effect of waterborne polyurethane dispersion (WPUD) applied to a polyester (PET)-based fabric, through the impregnation method, on the puncturing and water resistance of the pristine material, before and after UV weathering. Results confirmed an increment of both features in the prepared fabrics, attributed to the PUR textile treatment; but a partially loss of the gained properties in the samples due to the UV weathering. In order to improve the efficiency of the impregnating dispersions, in protecting the durability of the treated materials, the addition of different UV light stabilizers, or/and of crosslinking agent into WPUD was also tested. From the experimental data, it can be concluded that formulations based on WPUD, containing both the crosslinker and UV organic absorber, have displayed an increment of their perforation and water resistance for the treated samples with respect to the starting textile, and contemporary have preserved the features against the UV light. Finally, microscopic and spectroscopic analyses have been performed as further characterization techniques of the samples surface.


2014 ◽  
Vol 955-959 ◽  
pp. 88-91 ◽  
Author(s):  
Zhe Yang ◽  
Yan Bin Zhu ◽  
Fang Peng ◽  
Chang Qing Fu

The undecylenate based diol (UAD) has been synthesized from undecylenate by esterification and thiol-ene click reaction sequently, and then it was used as a diol to prepare bio-based waterborne polyurethane (WPU) reacting with isophorone diisocyanate (IPDI) and castor oil-based carboxyl hydrophilic chain extender. The structure of undecylenate based diol was verified by hydrogen proton nuclear magnetic resonance (1H NMR). Fourier transform infrared spectroscopy (FT-IR) was used to characterize the structure of WPU film. Furthermore, particle size and viscosity were used to character apparent properties of the bio-based waterborne polyurethane dispersion. The result shows that: bio-based waterborne polyurethane dispersion is transparent and very stable under room temperature. This work provides a simple and efficient method for the preparation of fatty acids based polyols and bio-based waterborne polyurethanes.


2016 ◽  
Vol 45 (6) ◽  
pp. 270-276 ◽  
Author(s):  
Y. Zang ◽  
W. Gong ◽  
H. Xie ◽  
Z. Du ◽  
B. Liu ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (130) ◽  
pp. 107413-107420 ◽  
Author(s):  
Qiwen Yong ◽  
Fuwei Nian ◽  
Bing Liao ◽  
Liping Huang ◽  
Lu Wang ◽  
...  

Self-extinction and solvent-free waterborne polyurethane resin without the addition of extra matting agents.


2020 ◽  
Vol 137 (45) ◽  
pp. 49383
Author(s):  
Lei Jiang ◽  
Zhiyong Ren ◽  
Wentao Liu ◽  
Hao Liu ◽  
Chengshen Zhu

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 795
Author(s):  
Sariah Saalah ◽  
Luqman Chuah Abdullah ◽  
Min Min Aung ◽  
Mek Zah Salleh ◽  
Dayang Radiah Awang Biak ◽  
...  

Nowadays, there is a significant trend away from solvent-based polyurethane systems towards waterborne polyurethane dispersions due to government regulations requiring manufacturers to lower total volatile organic compounds, as well as consumer preference for more environmentally friendly products. In this work, a renewable vegetable oil-based polyol derived from jatropha oil was polymerized with isophorone diisocyanate and dimethylol propionic acid to produce anionic waterborne polyurethane dispersion. Free standing films with up to 62 wt.% bio-based content were successfully produced after evaporation of water from the jatropha oil-based waterborne polyurethane (JPU) dispersion, which indicated good film formation. The chemical and thermo-mechanical properties of the JPU films were characterized. By increasing the OH numbers of polyol from 161 mgKOH/g to 217 mgKOH/g, the crosslinking density of the JPU was significantly increased, which lead to a better storage modulus and improved hydrophobicity. Overall, JPU produced from polyol having OH number of 217 mgKOH/g appears to be a promising product for application as a binder for wood and decorative coatings.


RSC Advances ◽  
2014 ◽  
Vol 4 (67) ◽  
pp. 35476-35483 ◽  
Author(s):  
Ruqi Chen ◽  
Chaoqun Zhang ◽  
Michael R. Kessler

Anionic waterborne polyurethane dispersions were prepared from ring-opening epoxidized linseed oil with glycol and hydrochloric acid followed by saponification, step-growth polymerization, and ionomerization.


2007 ◽  
Vol 16 (8) ◽  
pp. 891-896 ◽  
Author(s):  
Su-Yong Yoo ◽  
Jung-Du Kim ◽  
Sang-Kyu Kam ◽  
Myung-Jun Moon ◽  
Min-Gyu Lee

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