scholarly journals Life cycle environmental impacts of chemical recycling via pyrolysis of mixed plastic waste in comparison with mechanical recycling and energy recovery

Author(s):  
Harish Jeswani ◽  
Christian Krüger ◽  
Manfred Russ ◽  
Maike Horlacher ◽  
Florian Antony ◽  
...  
2020 ◽  
Vol 12 (5) ◽  
pp. 2088 ◽  
Author(s):  
Irena Wojnowska-Baryła ◽  
Dorota Kulikowska ◽  
Katarzyna Bernat

This article focuses on the end-of-life management of bio-based products by recycling, which reduces landfilling. Bio-plastics are very important materials, due to their widespread use in various fields. The advantage of these products is that they primarily use renewable materials. At its end-of-life, a bio-based product is disposed of and becomes post-consumer waste. Correctly designing waste management systems for bio-based products is important for both the environment and utilization of these wastes as resources in a circular economy. Bioplastics are suitable for reuse, mechanical recycling, organic recycling, and energy recovery. The volume of bio-based waste produced today can be recycled alongside conventional wastes. Furthermore, using biodegradable and compostable bio-based products strengthens industrial composting (organic recycling) as a waste management option. If bio-based products can no longer be reused or recycled, it is possible to use them to produce bio-energy. For future effective management of bio-based waste, it should be determined how these products are currently being managed. Methods for valorizing bio-based products should be developed. Technologies could be introduced in conjunction with existing composting and anaerobic digestion infrastructure as parts of biorefineries. One option worth considering would be separating bio-based products from plastic waste, to maintain the effectiveness of chemical recycling of plastic waste. Composting bio-based products with biowaste is another option for organic recycling. For this option to be viable, the conditions which allow safe compost to be produced need to be determined and compost should lose its waste status in order to promote bio-based organic recycling.


2021 ◽  
Vol 888 ◽  
pp. 129-138
Author(s):  
Munzir Hadengganan ◽  
Djoko Sihono Gabriel

Plastic waste has become a big issue in the world for its large amount of plastic waste in the sea. Most of the plastic waste is plastic packaging which consists of flexible and rigid plastic packaging. This research discusses flexible plastic packaging. Until now, most researches on the loss of plastic materials discuss how to manage plastic waste disposal once it has been used by community: only a few discuss production cycle: while none of them discusses flexible plastic packaging area. This research aims to examine the number of mismanaged materials throughout flexible plastic packaging life cycle using a combination of Material Flow Analysis (MFA) and Life Cycle Analysis (LCA). Based on the literature review, interviews and observations conducted by the author to all stakeholders in the life cycle of flexible plastic packaging, mismanagement of plastic material occurred in each cycle, mostly caused by quality degradation of flexible plastic that could cause plastic waste was not acceptable in the mechanical recycle. The results of this study show that: (1) mismanaged material occurred in all cycles throughout the life cycles of flexible plastic packaging, (2) quality degradation is the main caused of mismanaged material in several cycles, and (3) the mismanaged materials in the life cycle of flexible plastic packaging were 98.29%.


Clean Energy ◽  
2020 ◽  
Vol 4 (3) ◽  
pp. 169-201
Author(s):  
Roh Pin Lee ◽  
Bernd Meyer ◽  
Qiuliang Huang ◽  
Raoul Voss

Abstract Waste is a valuable secondary carbon resource. In the linear economy, it is predominantly landfilled or incinerated. These disposal routes not only lead to diverse climate, environmental and societal problems; they also represent a loss of carbon resources. In a circular carbon economy, waste is used as a secondary carbon feedstock to replace fossil resources for production. This contributes to environmental protection and resource conservation. It furthermore increases a nation’s independence from imported fossil energy sources. China is at the start of its transition from a linear to circular carbon economy. It can thus draw on waste management experiences of other economies and assess the opportunities for transference to support its development of ‘zero waste cities’. This paper has three main focuses. First is an assessment of drivers for China’s zero waste cities initiative and the approaches that have been implemented to combat its growing waste crisis. Second is a sharing of Germany’s experience—a forerunner in the implementation of the waste hierarchy (reduce–reuse–recycle–recover–landfill) with extensive experience in circular carbon technologies—in sustainable waste management. Last is an identification of transference opportunities for China’s zero waste cities. Specific transference opportunities identified range from measures to promote waste prevention, waste separation and waste reduction, generating additional value via mechanical recycling, implementing chemical recycling as a recycling option before energy recovery to extending energy recovery opportunities.


2016 ◽  
Vol 24 (4) ◽  
pp. 372-384 ◽  
Author(s):  
Marina F. Cosate de Andrade ◽  
Patrícia M. S. Souza ◽  
Otávio Cavalett ◽  
Ana R. Morales

2021 ◽  
Vol 7 (15) ◽  
pp. eabf0187
Author(s):  
Nemi Vora ◽  
Peter R. Christensen ◽  
Jérémy Demarteau ◽  
Nawa Raj Baral ◽  
Jay D. Keasling ◽  
...  

Mechanical recycling of polymers downgrades them such that they are unusable after a few cycles. Alternatively, chemical recycling to monomer offers a means to recover the embodied chemical feedstocks for remanufacturing. However, only a limited number of commodity polymers may be chemically recycled, and the processes remain resource intensive. We use systems analysis to quantify the costs and life-cycle carbon footprints of virgin and chemically recycled polydiketoenamines (PDKs), next-generation polymers that depolymerize under ambient conditions in strong acid. The cost of producing virgin PDK resin using unoptimized processes is ~30-fold higher than recycling them, and the cost of recycled PDK resin ($1.5 kg−1) is on par with PET and HDPE, and below that of polyurethanes. Virgin resin production is carbon intensive (86 kg CO2e kg−1), while chemical recycling emits only 2 kg CO2e kg−1. This cost and emissions disparity provides a strong incentive to recover and recycle future polymer waste.


2021 ◽  
Vol 293 ◽  
pp. 126163
Author(s):  
Matthew G. Davidson ◽  
Rebecca A. Furlong ◽  
Marcelle C. McManus

Science ◽  
2021 ◽  
Vol 373 (6550) ◽  
pp. 66-69
Author(s):  
LaShanda T. J. Korley ◽  
Thomas H. Epps ◽  
Brett A. Helms ◽  
Anthony J. Ryan

Plastics have revolutionized modern life, but have created a global waste crisis driven by our reliance and demand for low-cost, disposable materials. New approaches are vital to address challenges related to plastics waste heterogeneity, along with the property reductions induced by mechanical recycling. Chemical recycling and upcycling of polymers may enable circularity through separation strategies, chemistries that promote closed-loop recycling inherent to macromolecular design, and transformative processes that shift the life-cycle landscape. Polymer upcycling schemes may enable lower-energy pathways and minimal environmental impacts compared with traditional mechanical and chemical recycling. The emergence of industrial adoption of recycling and upcycling approaches is encouraging, solidifying the critical role for these strategies in addressing the fate of plastics and driving advances in next-generation materials design.


Author(s):  
Evgeniіa Mykhailova ◽  
Dmytro Deineka ◽  
Hanna Pancheva

Methods of plastic waste management, the amount of which is constantly growing due to the high demand for polymer products with high performance properties, are considered. The urgency of the problem is explained by longevity of plastic, which, once in the environment, gradually degrades with the formation of substances dangerous to living organisms. The most common ways of plastic waste management are its storage on specially designated land plots or incineration with / without getting heat. Each of these methods has certain disadvantages, which necessitates the introduction of other measures. Recycling of plastic waste into secondary raw materials, energy or products with certain consumer properties can be the promising method of plastic waste management from ecological and economic points of view. The purpose of this work is to analyze the methods of plastic waste recycling, to establish their advantages and disadvantages, to determine the optimal ways for the disposal of polymeric materials with different properties. Two main groups of polymer recycling methods: physical and chemical, are considered. Physical method includes mechanical recycling, which is based on the physical grinding of plastic waste to obtain secondary raw materials without significant changes in the chemical structure of the material. This process is quite simple in terms of technical design, but requires careful sorting and cleaning of waste, and has limitations on the reuse of recycled material. Chemical recycling takes place through the processes of solvolysis (hydrolysis, glycolysis, alcoholysis) and conversion (pyrolysis, gasification). In this case, the plastic waste decomposes into the original molecules – monomers, from which it is possible to get a polymer product with the same properties. Chemical methods allow disposing of unsorted and contaminated polymeric materials many times without losing their quality. Thus, the introduction of the described methods will reduce the amount of plastic waste, turn them into valuable secondary raw materials and reduce using of natural resources used to obtain primary plastic materials.


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