scholarly journals Hybrid chitosan/FeCl3 coagulation–membrane processes: Performance evaluation and membrane fouling study in removing natural organic matter

2015 ◽  
Vol 152 ◽  
pp. 23-31 ◽  
Author(s):  
W.L. Ang ◽  
A.W. Mohammad ◽  
Y.H. Teow ◽  
A. Benamor ◽  
N. Hilal
2004 ◽  
Vol 4 (5-6) ◽  
pp. 215-222 ◽  
Author(s):  
A.R. Costa ◽  
M.N. de Pinho

Membrane fouling by natural organic matter (NOM), namely by humic substances (HS), is a major problem in water treatment for drinking water production using membrane processes. Membrane fouling is dependent on membrane morphology like pore size and on water characteristics namely NOM nature. This work addresses the evaluation of the efficiency of ultrafiltration (UF) and Coagulation/Flocculation/UF performance in terms of permeation fluxes and HS removal, of the water from Tagus River (Valada). The operation of coagulation with chitosan was evaluated as a pretreatment for minimization of membrane fouling. UF experiments were carried out in flat cells of 13.2×10−4 m2 of membrane surface area and at transmembrane pressures from 1 to 4 bar. Five cellulose acetate membranes were laboratory made to cover a wide range of molecular weight cut-off (MWCO): 2,300, 11,000, 28,000, 60,000 and 75,000 Da. Severe fouling is observed for the membranes with the highest cut-off. In the permeation experiments of raw water, coagulation prior to membrane filtration led to a significant improvement of the permeation performance of the membranes with the highest MWCO due to the particles and colloidal matter removal.


Membranes ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 968
Author(s):  
Zhun Ma ◽  
Lu Zhang ◽  
Ying Liu ◽  
Xiaosheng Ji ◽  
Yuting Xu ◽  
...  

The fouling mechanism of the anion exchange membrane (AEM) induced by natural organic matter (NOM) in the absence and presence of calcium ions was systematically investigated via the extended Derjaguin–Landau–Verwey–Overbeek (xDLVO) approach. Sodium alginate (SA), humic acid (HA), and bovine serum albumin (BSA) were utilized as model NOM fractions. The results indicated that the presence of calcium ions tremendously aggravated the NOM fouling on the anion exchange membrane because of Ca-NOM complex formation. Furthermore, analysis of the interaction energy between the membrane surface and foulants via xDLVO revealed that short-range acid–base (AB) interaction energy played a significant role in the compositions of interaction energy during the electrodialysis (ED) process. The influence of NOM fractions in the presence of calcium ions on membrane fouling followed the order: SA > BSA > HA. This study demonstrated that the interaction energy was a dominating indicator for evaluating the tendency of anion exchange membranes fouling by natural organic matter.


2019 ◽  
Vol 5 (12) ◽  
pp. 2242-2250
Author(s):  
Xue Shen ◽  
Baoyu Gao ◽  
Kangying Guo ◽  
Qinyan Yue

Coagulation prior to the ultrafiltration (UF) process was implemented to improve natural organic matter (NOM) removal and membrane permeability.


2004 ◽  
Vol 50 (12) ◽  
pp. 279-285 ◽  
Author(s):  
J.H. Kweon ◽  
D.F. Lawler

The biggest impediment for applying membrane processes is fouling that comes from mass flux (such as particle and organic matter) to the membrane surface and its pores. Numerous research articles have indicated that either particles or natural organic matter (NOM) has been the most detrimental foulant. Therefore, the role of particles in membrane fouling was investigated with two synthetic waters (having either particles alone or particles with simple organic matter) and a natural water. Membrane fouling was evaluated with flux decline behavior and direct images from scanning electron microscopy. The results showed that the combined fouling by kaolin and dextran (a simple organic compound selected as a surrogate for NOM) showed no difference from the fouling with only the organic matter. The similarity might stem from the fact that dextran (i.e., polysaccharide) has no ability to be adsorbed on the clay material, so that the polysaccharide behaves the same with respect to the membrane with or without clay material being present. In contrast to kaolin, the natural particles showed a dramatic effect on membrane fouling.


1999 ◽  
Vol 40 (9) ◽  
pp. 113-120 ◽  
Author(s):  
A. Maartens ◽  
P. Swart ◽  
E. P. Jacobs

Organic matter in natural brown water as well as humic acids from a commercial sample were characterised by ultraviolet-visible light-spectroscopy and used in ultrafiltration studies. During ultrafiltration the pure-water flux and the operational flux were measured continuously to determine the degree of membrane fouling. The natural organic matter and commercial humic acid concentrations of the feed and permeate solutions were determined spectrophotometrically. These variables were used in conjunction with conventional flux measurements, to determine the colour-removal efficiency of ultrafiltration as well as the degree of foulant adsorption onto the membranes. Fouled membranes were cleaned with alkaline chemical agents normally used to extract natural organic matter from soil samples. The cleaning efficiency and the effect of cleaning solutions on the membrane selectivity were studied.


Membranes ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 238
Author(s):  
Fangshu Qu ◽  
Zhimeng Yang ◽  
Shanshan Gao ◽  
Huarong Yu ◽  
Junguo He ◽  
...  

To understand impacts of organic adhesion on membrane fouling, ultrafiltration (UF) membrane fouling by dissolved natural organic matter (NOM) was investigated in the presence of background cations (Na+ and Ca2+) at typical concentrations in surface water. Moreover, NOM adhesion on the UF membrane was investigated using atomic force microscopy (AFM) with colloidal probes and a quartz crystal microbalance with dissipation monitoring (QCM-D). The results indicated that the adhesion forces at the NOM-membrane interface increased in the presence of background cations, particularly Ca2+, and that the amount of adhered NOM increased due to reduced electrostatic repulsion. However, the membrane permeability was almost not affected by background cations in the pore blocking-dominated phase but was aggravated to some extent in the cake filtration-governed phase. More importantly, the irreversible NOM fouling was not correlated with the amount of adhered NOM. The assumption for membrane autopsies is doubtful that retained or adsorbed organic materials are necessarily a primary cause of membrane fouling, particularly the irreversible fouling.


2020 ◽  
Vol 988 ◽  
pp. 114-121 ◽  
Author(s):  
Mahmud ◽  
Muthia Elma ◽  
Erdina Lulu Atika Rampun ◽  
Aulia Rahma ◽  
Amalia Enggar Pratiwi ◽  
...  

Natural Organic Matter (NOM) content in peat water is a major problem of membrane fouling in ultrafiltration (UF). For that, two stages adsorption as pre-treatment was employed to minimize the membrane fouling of NOM content. This research was carried out to investigate the effect of two stages adsorption on ultrafiltration performance for NOM removal that remains in peat water. This method was using powdered activated carbon (PAC) dosage of 80, 160, 240, 320, 400, 480, 560, 640, 720, 800, 880 dan 960 mg.L-1. Then, Polysulfone (Psf) material was employed for Ultra filtration process. Membrane was applied in a dead-end mode with various operating pressure (1; 1.5; 2; 2.5; 3 bar). As a results, the optimum dose of PAC was 800 mg L-1 with dosage ratio of 3/4:1/4. Two stages adsorption-UF PSf provided the range from 86.9 to 92.8% of KMnO4 and 74.1-88.1% of UV254. For the experimental condition of 3 bar, the highest flux was achieved up to 39.919 L h-1.m-2.


Desalination ◽  
2002 ◽  
Vol 145 (1-3) ◽  
pp. 281-286 ◽  
Author(s):  
K. Majewska-Nowak ◽  
M. Kabsch-Korbutowicz ◽  
M. Dodź

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