Atomic force microscopic study of nanoscale interaction between N719 dye and CdSe quantum dot in hybrid solar cells and their enhanced open circuit potential

Solar Energy ◽  
2015 ◽  
Vol 116 ◽  
pp. 25-36 ◽  
Author(s):  
Laveena P. D’Souza ◽  
Vipin Amoli ◽  
H.R. Chandan ◽  
Anil Kumar Sinha ◽  
Ranjith Krishna Pai ◽  
...  
2017 ◽  
Vol 5 (6) ◽  
pp. 2473-2477 ◽  
Author(s):  
Chandima Bulumulla ◽  
Jia Du ◽  
Katherine E. Washington ◽  
Ruvanthi N. Kularatne ◽  
Hien Q. Nguyen ◽  
...  

The incorporation of functional groups into the side chains of polythiophenes can improve the phase separation of polymer : nanoparticle hybrid solar cells (HSCs).


Nano Hybrids ◽  
2015 ◽  
Vol 9 ◽  
pp. 7-14 ◽  
Author(s):  
Alfian Ferdiansyah Madsuha ◽  
Chuyen Van Pham ◽  
Michael Krueger

In this work, the development of room-temperature solution-processed hybrid solar cells based on carbon nanotubes (CNT) - CdSe quantum dot (QD) hybrid material incorporated into a layer of conjugated polymer poly [2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta [2,1-b;3,4-b′] dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)], PCPDTBT, has been demonstrated. Incorporation of multi walled CNTs helps to improve the long-term efficiency of the solar cells in respect of power conversion efficiency (PCE) and short-circuit current density (Jsc) compared to QD only based devices. For the formation of the hybrid material hexadecylamine (HDA)/ trioctylphosphine oxide (TOPO) capped CdSe QDs were attached to CNTs by engineering the interface between CNTs and CdSe QDs by introducing thiol functional groups to CNTs. Initial PCE values of about 1.9 % under AM1.5G illumination have been achieved for this hybrid CNT-CdSe photovoltaic device. Furthermore, the long term stability of the photovoltaic performance of the devices was investigated and found superior to CdSe QD only based devices. About 90 % of the original PCE remained after storage in a glove box for almost one year without any further encapsulation. It is assumed that the improvement is mainly due to the thiol-functionalization of the CNT interface leading to a strong binding of CdSe QDs and a resulting preservation of the nanomorphology of the hybrid film over time.


2014 ◽  
Vol 119 ◽  
pp. 169-173 ◽  
Author(s):  
Eung-Kyu Park ◽  
Jae-Hyoung Kim ◽  
In Ae Ji ◽  
Hye Mi Choi ◽  
Ji-Hwan Kim ◽  
...  

2015 ◽  
Vol 66 (15) ◽  
pp. 1-8
Author(s):  
R. Scott ◽  
A. Kirkeminde ◽  
M. Gong ◽  
J. Totleben ◽  
S. Ren ◽  
...  

2013 ◽  
Vol 873 ◽  
pp. 556-561
Author(s):  
Jian Jun Tian

CdS/CdSe quantum dots co-sensitized solar cells (QDSCs) were prepared by combining the successive ion layer absorption and reaction (SILAR) method and chemical bath deposition (CBD) method for the fabrication of CdS and CdSe quantum dots, respectively. In this work, we designed anisotropic nanostructure ZnO photoelectrodes, such as nanorods/nanosheets and nanorods array, for CdS/CdSe quantum dots co-sensitized solar cells. Our study revealed that the performance of QDSCs could be improved by modifying surface of ZnO to increase the loading of quantum dots and reduce the charge recombination.


2016 ◽  
Vol 84 ◽  
pp. 212-217 ◽  
Author(s):  
Xiaowei Li ◽  
Ruixue Chen ◽  
Huidong Sui ◽  
Xiaoxian Yuan ◽  
Meng Li ◽  
...  

2015 ◽  
Vol 2015 ◽  
pp. 1-4
Author(s):  
Xiaojun Zhu ◽  
Xiaoping Zou ◽  
Hongquan Zhou

We use the successive ionic layer adsorption and reaction (SILAR) method for the preparation of quantum dot sensitized solar cells, to improve the performance of solar cells by doping quantum dots. We tested the UV-Vis absorption spectrum of undoped CdS QDSCs and Cu doped CdS QDSCs with different doping ratios. The doping ratios of copper were 1 : 100, 1 : 500, and 1 : 1000, respectively. The experimental results show that, under the same SILAR cycle number, Cu doped CdS quantum dot sensitized solar cells have higher open circuit voltage, short circuit current density photoelectric conversion efficiency than undoped CdS quantum dots sensitized solar cells. Refinement of Cu doping ratio are 1 : 10, 1 : 100, 1 : 200, 1 : 500, and 1 : 1000. When the proportion of Cu and CdS is 1 : 10, all the parameters of the QDSCs reach the minimum value, and, with the decrease of the proportion, the short circuit current density, open circuit voltage, and the photoelectric conversion efficiency are all increased. When proportion is 1 : 500, all parameters reach the maximum values. While with further reduction of the doping ratio of Cu, the parameters of QDSCs have a decline tendency. The results showed that, in a certain range, the lower the doping ratio of Cu, the better the performance of quantum dot sensitized solar cell.


Energies ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1931
Author(s):  
Hee-Je Kim ◽  
Jin-Ho Bae ◽  
Hyunwoong Seo ◽  
Masaharu Shiratani ◽  
Chandu Venkata Veera Muralee Gopi

Suppressing the charge recombination at the interface of photoanode/electrolyte is the crucial way to improve the quantum dot sensitized solar cells (QDSSCs) performance. In this scenario, ZnS/SiO2 blocking layer was deposited on TiO2/CuInS2 QDs to inhibit the charge recombination at photoanode/electrolyte interface. As a result, the TiO2/CuInS2/ZnS/SiO2 based QDSSCs delivers a power conversion efficiency (η) value of 4.63%, which is much higher than the TiO2/CuInS2 (2.15%) and TiO2/CuInS2/ZnS (3.23%) based QDSSCs. Impedance spectroscopy and open circuit voltage decay analyses indicate that ZnS/SiO2 passivation layer on TiO2/CuInS2 suppress the charge recombination at the interface of photoanode/electrolyte and enhance the electron lifetime.


Sign in / Sign up

Export Citation Format

Share Document