Effect of solvent on large-area polymer–fullerene solar cells fabricated by a slot-die coating method

2014 ◽  
Vol 126 ◽  
pp. 107-112 ◽  
Author(s):  
Soonil Hong ◽  
Minjin Yi ◽  
Hongkyu Kang ◽  
Jaemin Kong ◽  
Woontae Lee ◽  
...  
2018 ◽  
Vol 5 (5) ◽  
pp. 172158 ◽  
Author(s):  
Daniel Burkitt ◽  
Justin Searle ◽  
Trystan Watson

The fabrication of perovskite solar cells in an N-I-P structure with compact titanium dioxide blocking, mesoporous titanium dioxide scaffold, single-step perovskite and hole-transport layers deposited using the slot-die coating technique is reported. Devices on fluorine-doped tin oxide-coated glass substrates with evaporated gold top contacts and four slot-die-coated layers are demonstrated, and best cells reach stabilized power conversion efficiencies of 7%. This work demonstrates the suitability of slot-die coating for the production of layers within this perovskite solar cell stack and the potential to transfer to large area and roll-to-roll manufacturing processes.


Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2106 ◽  
Author(s):  
Daniel Burkitt ◽  
Justin Searle ◽  
David Worsley ◽  
Trystan Watson

This work demonstrates a sequential deposition of lead iodide followed by methylammonium iodide using the industrially compatible slot-die coating method that produces homogeneous pin-hole free films without the use of the highly toxic dimethylformamide. This is achieved through the careful selection and formulation of the solvent system and coating conditions for both the lead iodide layer and the methylammonium iodide coating. The solvent system choice is found to be critical to achieving good coating quality, conversion to the final perovskite and for the film morphology formed. A range of alcohols are assessed as solvent for methylammonium iodide formulations for use in slot-die coating. A dimethylsulfoxide solvent system for the lead iodide layer is shown which is significantly less toxic than the dimethylformamide solvent system commonly used for lead iodide deposition, which could find utility in high throughput manufacture of perovskite solar cells.


2018 ◽  
Vol 11 (11) ◽  
pp. 3248-3255 ◽  
Author(s):  
Seyeong Song ◽  
Kang Taek Lee ◽  
Chang Woo Koh ◽  
Hyebeom Shin ◽  
Mei Gao ◽  
...  

High performance flexible polymer solar cells are realized by using the 3D printer-based slot die coating method.


Solar RRL ◽  
2021 ◽  
Author(s):  
Sophie Bernard ◽  
Sébastien Jutteau ◽  
Salim Mejaouri ◽  
Stefania Cacovich ◽  
Iwan Zimmerman ◽  
...  

2015 ◽  
Vol 3 (22) ◽  
pp. 5859-5868 ◽  
Author(s):  
Seyul Kim ◽  
So Yeon Kim ◽  
Moon Hyun Chung ◽  
Jeonghun Kim ◽  
Jung Hyun Kim

An AgNW/PEDOT:PSS coated, transparent, conducting, roll film (460 mm in width × 20 m in length) with good electrical and optical properties was produced using the roll-to-roll slot-die coating method.


Polymers ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 4003
Author(s):  
Seongyong Kim ◽  
Minho Jo ◽  
Jongsu Lee ◽  
Changwoo Lee

Solar cells are important alternatives to fossil fuels for energy generation in today’s world, where the demand for alternative, renewable sources of energy is increasing. However, solar cells, which are installed outdoors, are susceptible to pollution by environmental factors. A solution to overcome this limitation involves coating solar cell surfaces with functional coatings. In this study, we propose a transmittance control method for a tensioned web in a roll-to-roll, transparent, water-repellent film coating. First, we analyzed the effects of process conditions on the transmittance and contact angle of the transparent water-repellent film during roll-to-roll slot-die coating. It was confirmed that the tension was the most dominant factor, followed by the coating gap. Through the tension control, the transmittance was changed by 3.27%, and the contact angle of the DI water was changed by 17.7°. In addition, it was confirmed that the transmittance was changed by 0.8% and the contact angle of DI water by 3.9° via the coating gap control. Based on these results, a transmittance prediction model was developed according to the tension and coating gap, and was then verified experimentally. Finally, a water-repellent film with a high transmittance of 89.77% was obtained using this model.


2021 ◽  
pp. 2105114
Author(s):  
Heng Zhao ◽  
Baojun Lin ◽  
Jingwei Xue ◽  
Hafiz Bilal Naveed ◽  
Chao Zhao ◽  
...  

MRS Advances ◽  
2019 ◽  
Vol 4 (24) ◽  
pp. 1399-1407 ◽  
Author(s):  
Daniel Burkitt ◽  
Peter Greenwood ◽  
Katherine Hooper ◽  
David Richards ◽  
Vasil Stoichkov ◽  
...  

Abstract:Roll-to-roll slot-die coating with a meniscus guide is used to deposit several layers in a P-I-N perovskite solar cell stack, including the perovskite layer. The use of various length meniscus guides as part of the slot-die head allows controlled coating of these layers at a common coating speed. The length of meniscus guide used is optimised and related to the rheology of the coated ink and appropriate choice of meniscus guide length provides a way to avoid flooding of the coated area and improve coating definition. Initial coating trial results suggest the low-flow limit of slot-die coating is still applicable when using a meniscus guide, which is an important and previously unreported observation, application of this theory to meniscus guide coating provides a useful tool for rapidly determining the appropriate coating conditions that can be used as part of a manufacturing process. This is further explored through the deposition of perovskite solar cells by roll-to-roll slot-die coating. The perovskite layer is deposited using a sequential slot-die deposition process using a low toxicity dimethyl sulfoxide ink for the lead iodide layer, it is found that increasing the drying oven temperature and air flow rate can be used to improve the uniformity of the layer but this can also result in deformation of the plastic substrate. Functioning perovskite solar cells are demonstrated using this technique, but a large variation is found between device performances which is attributed to the poor uniformity of the perovskite layer and damage caused to the substrate by excessive heating.


2021 ◽  
Author(s):  
Jun Wang ◽  
Michael R. Squillante ◽  
Siraj Sidhik ◽  
Aditya Mohite ◽  
Matthew S. J. Marshall

Solar Energy ◽  
2019 ◽  
Vol 177 ◽  
pp. 255-261 ◽  
Author(s):  
Yu-Ching Huang ◽  
Chia-Feng Li ◽  
Zhi-Hao Huang ◽  
Po-Hung Liu ◽  
Cheng-Si Tsao

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