Optimization of the photoelectric properties and photo-stability of CH3NH3PbBrXI3-X films for efficient planar perovskite solar cells

2018 ◽  
Vol 113 ◽  
pp. 118-128 ◽  
Author(s):  
Zhaoyi Jiang ◽  
Weijia Zhang ◽  
Denghao Ma ◽  
Haixu Liu ◽  
Wei Yu ◽  
...  
Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2364
Author(s):  
Zhiyuan He ◽  
Chi Zhang ◽  
Rangwei Meng ◽  
Xuanhui Luo ◽  
Mengwei Chen ◽  
...  

In this paper, Ag@SiO2 core-shell nanoparticles (NPs) with different shell thicknesses were prepared experimentally and introduced into the photosensitive layer of mesoscopic hole-conductor-free perovskite solar cells (PSCs) based on carbon counter electrodes. By combining simulation and experiments, the influences of different shell thickness Ag@SiO2 core-shell nanoparticles on the photoelectric properties of the PSCs were studied. The results show that, when the shell thickness of 0.1 wt% Ag@SiO2 core-shell nanoparticles is 5 nm, power conversion efficiency is improved from 13.13% to 15.25%, achieving a 16% enhancement. Through the measurement of the relevant parameters of the obtained perovskite film, we found that this gain not only comes from the increase in current density that scholars generally think, but also comes from the improvement of the film quality. Like current gain, this gain is related to the different shell thickness of Ag@SiO2 core-shell nanoparticles. Our research provides a new direction for studying the influence mechanism of Ag@SiO2 core-shell nanoparticles in perovskite solar cells.


Solar Energy ◽  
2019 ◽  
Vol 186 ◽  
pp. 126-135 ◽  
Author(s):  
Yanfeng Wang ◽  
Jianmin Song ◽  
Weiye Song ◽  
Ying Tian ◽  
Bing Han ◽  
...  

2020 ◽  
Vol 8 (46) ◽  
pp. 24608-24619 ◽  
Author(s):  
Somayeh Moghadamzadeh ◽  
Ihteaz M. Hossain ◽  
The Duong ◽  
Saba Gharibzadeh ◽  
Tobias Abzieher ◽  
...  

Incorporating 2.5% Cs in FA0.8MA0.2Sn0.5Pb0.5I3 improves the photo-stability of the low-bandgap perovskite solar cells. The champion device with power conversion efficiency of 18.9% maintain 92% of its initial efficiency after 120 min MPP tracking.


Author(s):  
Atsushi Kogo ◽  
Kohei Yamamoto ◽  
Takurou N MURAKAMI

Abstract Although the all-inorganic perovskite CsPbI3 exhibits superior thermal- and photo-stability compared with organic-inorganic perovskites, formation of the photoactive α-phase requires sintering at approximately 320 oC. Herein, we report the partial substitution of Ge2+ ions for Pb2+ as a means of tuning the stability of the material and enabling α-phase formation at 90 oC.


2021 ◽  
Vol 1 (12 (109)) ◽  
pp. 36-43
Author(s):  
Rustan Hatib ◽  
Sudjito Soeparman ◽  
Denny Widhiyanuriyawan ◽  
Nurkholis Hamidi

Organic metal halide perovskite has recently shown great potential for applications, as it has the advantages of low cost, excellent photoelectric properties, and high power conversion efficiency. The Hole Transport Material (HTM) is one of the most critical components in Perovskite Solar Cells (PSC). It has the function of optimizing the interface, adjusting the energy compatibility, and obtaining higher PCE. The inorganic p-type semiconductor is an alternative HTM due to its chemical stability, higher mobility, increased transparency in the visible region, and general valence band energy level (VB). Here we report the use of the Graphene Oxide (GO) layer as a Hole Transport Layer (HTL) to improve the perovskite solar cells' performance. The crystal structure and thickness of GO significantly affect the increase in solar cell efficiency. This perovskite film must show a high degree of crystallinity. The configuration of the perovskite material is FTO/NiO/GO/CH3NH3PbI3/ZnO/Ag. GO as a Hole Transport Layer can increase positively charged electrons' mobility to improve current and voltage. As a blocking layer that can prevent recombination. The GO can make the perovskite interface layer with smoother holes, and molecular uniformity occurs to reduce recombination. The method used in this study is by using spin coating. In the spin-coating process, the GO layer is coated on top of NiO with variations in the rotation of 700 rpm, 800 rpm, 900 rpm, 1,000 rpm, and 1,500 rpm. The procedure formed different thicknesses from 332.5 nm, 314.7 nm, 256.4 nm, 227.4 to 204.5 nm. The results obtained at a thickness of 227.4 nm reached the optimum efficiency, namely 15,3 %. Thus, the GO material as a Hole Transport Layer can support solar cell performance improvement by not being too thick and thin


Author(s):  
M. I. El-Henawey ◽  
Istiaque M. Hossain ◽  
Liang Zhang ◽  
Behrang Bagheri ◽  
Ranjith Kottokkaran ◽  
...  

Author(s):  
Istiaque Hossain ◽  
Liang Zhang ◽  
Ranjith Kottokkaran ◽  
Mohamed El-Henawey ◽  
Pranav Joshi ◽  
...  

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