Influence of submicro-sheet zinc phosphate modified by urea-formaldehyde on the corrosion protection of epoxy coating

2020 ◽  
Vol 18 ◽  
pp. 100403 ◽  
Author(s):  
Chao Shi ◽  
Yawei Shao ◽  
Yanqiu Wang ◽  
Guozhe Meng ◽  
Bin Liu
Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 113
Author(s):  
Jacob Ress ◽  
Ulises Martin ◽  
Juan Bosch ◽  
David M. Bastidas

The protection of mild steel by modified epoxy coating containing colophony microencapsulated corrosion inhibitors was investigated in this study. The corrosion behavior of these epoxy coatings containing colophony microcapsules was studied by electrochemical analysis using cyclic potentiodynamic polarization and electrochemical impedance spectroscopy. The microcapsule coating showed decreased corrosion current densities of 2.75 × 10−8 and 3.21 × 10−8 A/cm2 along with corrosion potential values of 0.349 and 0.392 VSCE for simulated concrete pore solution and deionized water with 3.5 wt.% NaCl, respectively, indicating improved corrosion protection in both alkaline and neutral pH. Electrochemical impedance spectroscopy analysis also showed charge transfer resistance values over one order of magnitude higher than the control sample, corroborating the electrochemical corrosion potential and current density testing results. Overall, the use of colophony microcapsules showed improved corrosion protection in simulated concrete pore solution and DI water solutions containing chloride ions.


Author(s):  
Александр Михайлович Ефремов ◽  
Петр Дмитриевич Волянский ◽  
Павел Олегович Ревин ◽  
Сергей Владимирович Ануфриев

При сооружении трубопроводов в России, странах Европы и Африки наиболее распространенным является применение труб с трехслойными полиэтиленовыми покрытиями. В то же время опыт строительства магистральных нефте- и газопроводов в США, Канаде, ряде других стран свидетельствует о возможности использования эпоксидных покрытий в качестве эффективной антикоррозионной защиты труб. В этой связи была начата научно-исследовательская работа по определению целесообразности применения двухслойных эпоксидных покрытий для антикоррозионной защиты магистральных трубопроводов подземной прокладки, эксплуатируемых организациями системы «Транснефть». Цель настоящего исследования - оценка технической и экономической целесообразности использования эпоксидных покрытий как альтернативы полиэтиленовой изоляции трубопроводов. Были проведены лабораторные исследования образцов трех систем эпоксидных покрытий, осуществлен сравнительный анализ технических свойств эпоксидной и полиэтиленовой изоляции. Установлено, что эпоксидные покрытия превосходят полиэтиленовые по ряду свойств, в частности обладают повышенной стойкостью к температурным воздействиям, УФ-излучению, катодному отслаиванию, а также повышенной механической прочностью, что позволяет обеспечить сохранность покрытия при строительстве трубопроводов методом наклонно-направленного бурения и прокладке в скальных грунтах. Основные мощности по производству сырья для эпоксидных порошковых покрытий локализованы в России, в то время как сырье для полиэтиленовых покрытий в основном производится за рубежом. Установлена экономическая целесообразность применения двухслойного эпоксидного покрытия как альтернативы трехслойному полиэтиленовому покрытию для трубопроводов больших диаметров - более 720 мм. Для внедрения труб с двухслойным эпоксидным покрытием на объектах ПАО «Транснефть» проводится его апробация, включающая строительство опытного участка трубопровода. When constructing pipelines in Russia, Europe, and Africa, it is the most common to use pipes with threelayer polyethylene coatings. At the same time, the oil and gas pipeline construction experience in the USA, Canada, and a number of other countries, as well as the construction of the Zapolyarye - Purpe elevated main pipeline by Transneft PJSC, indicates the possibility of using epoxy coatings as an effective pipe corrosion protection solution. In respect thereof, research study to determine the feasibility of using two-layer epoxy coatings for corrosion protection of underground pipelines operated by the Transneft system entities was instituted. The purpose of this study is to assess the technical and economic feasibility of using epoxy coatings as an alternative to polyethylene insulation of pipelines. Laboratory studies of samples of three epoxy coating systems, as well as a comparative analysis of the process properties of epoxy and polyethylene insulation were conducted. It has been established that epoxy coatings are superior to polyethylene coatings in a number of properties, in particular, they are characterized by increased resistance to temperature effects, UV radiation, cathodic disbondment, as well as increased mechanical strength, which makes it possible to ensure safety of the coating during the construction of pipelines by directional drilling and laying in rocky soils. The main production facilities for raw materials for epoxy powder coatings are localized in Russia, while raw materials for polyethylene coatings are mainly produced abroad. The economic feasibility of using a twolayer epoxy coating as an alternative to a three-layer polyethylene coating for pipelines of large diameters (over 720 mm (28 in)) was established. Testing for the introduction of pipes with a two-layer epoxy coating at the Transneft PJSC facilities is being performed, including construction of an experimental pipeline section.


2020 ◽  
Vol 147 ◽  
pp. 105864 ◽  
Author(s):  
Mahboobeh Attaei ◽  
Lénia M. Calado ◽  
Yegor Morozov ◽  
Maryna G. Taryba ◽  
R.A. Shakoor ◽  
...  

2019 ◽  
Vol 66 (2) ◽  
pp. 188-194
Author(s):  
Yingjun Zhang ◽  
Xue-Jun Cui ◽  
Yawei Shao ◽  
Yanqiu Wang ◽  
Guozhe Meng ◽  
...  

PurposeThis paper aims to prepare a residual rust epoxy coating by adding different quantities of phytic acid (PA) on the surface of the rusty steel and investigate the corrosion protection of PA and its action mechanisms.Design/methodology/approachA residual rust epoxy coating by adding different quantities of PA was prepared on the surface of the rusty steel. The influence of PA on the corrosion resistance of epoxy-coated rusty steel was investigated by means of electrochemical impedance spectroscopy and adhesion testing.FindingsResults indicated that PA can substantially improve the corrosion resistance of epoxy-coated rusty steel. This improvement is due to the reaction of PA with residual rust and generation of new compounds with protection properties and increased adhesive strength effects on the coating/metal interface. The coating showed better protection performance when 2 per cent PA was added.Originality/valueConsidering the structure of the active groups, PA has strong chelating capability with many metal ions and can form stable complex compounds on the surface of a metal substrate, thereby improving corrosion resistance. In recent years, PA has been reported to be useful in the conversion of coatings or as green corrosion inhibitor. To the best of the authors’ knowledge, few studies have reported the use of PA as a rust converter or residual rust coating. The present work aims to improve the corrosion resistance of residual rust epoxy coating by adding PA.


2019 ◽  
Vol 303 ◽  
pp. 239-245 ◽  
Author(s):  
Aurélien Roggero ◽  
Nicolas Caussé ◽  
Eric Dantras ◽  
Laura Villareal ◽  
Audrey Santos ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document