Superhydrophobic Behavior of Coatings Based on Fluoroalkyl Methacrylate Copolymers on a Textured Aluminum Surface

2021 ◽  
pp. 101255
Author(s):  
V.V. Klimov ◽  
E.V. Bryuzgin ◽  
A.V. Navrotskiy ◽  
I.A. Novakov
1998 ◽  
Author(s):  
Leo G. Henry ◽  
J.H. Mazur

Abstract The task of differentiating precisely between EOS and ESD failures continues to be a challenging one for Failure Analysis Engineers. Electrical OverStress (EOS) failures on the die surface (burnt/fused metallization) of an IC can be characterized mainly by the discoloration at the site of the failures. This is in direct contrast to the lack of discoloration characteristic of ESD failures, which occur almost exclusively below the die surface (oxide and junction failures). To aid in this distinction, this paper attempts to present the underlying physics behind the discoloration produced in the EOS failures. For the EOS failures, the metal fuses due to the longer pulse widths (sec to msec), while for the ESD failures, the silicon melts because of the shorter pulse widths (< < 500 nsec) and higher energy. After EOS, the aluminum surface becomes dark and rough and the oxide in the surrounding area becomes deformed and distorted, resulting in the discoloration observed in the light microscope. This EOS discoloration could be due to one or more of the following: 1) morphological and structural changes at the metal/glass interface and the glass itself; 2) changes in the thickness and scattering behavior of the glass and metal in the failed areas.


1981 ◽  
Vol 46 (8) ◽  
pp. 1941-1946 ◽  
Author(s):  
Karel Setínek

A series of differently crosslinked macroporous 2,3-epoxypropyl methacrylate-ethylenedimethacrylate copolymers with chemically bonded propylsulphonic acid groups were used as catalysts for the kinetic study of reesterification of ethyl acetate by n-propanol in the liquid phase at 52 °C and in the gas phase at 90 °C. Analysis of kinetic data by the method of nonlinear regression for a series of equations of the Langmuir-Hinshelwood type showed that kinetic equations which describe best the course of the reaction are the same as for the earlier studied sulphonated macroporous styrene-divinylbenzene copolymers. Compared types of catalysts differ, however, in the dependence of their activity on the degree of crosslinking of the copolymer used.


Author(s):  
Paulo R. O. Brito ◽  
Cristhian R. L. Loayza ◽  
Mário E. S. Sousa ◽  
Eduardo M. Braga ◽  
Rômulo S. Angélica ◽  
...  

2017 ◽  
Vol 139 (10) ◽  
Author(s):  
Jinsub Kim ◽  
Seongchul Jun ◽  
Jungho Lee ◽  
Juan Godinez ◽  
Seung M. You

The effect of surface roughness on the pool boiling heat transfer of water was investigated on superhydrophilic aluminum surfaces. The formation of nanoscale protrusions on the aluminum surface was confirmed after immersing it in boiling water, which modified surface wettability to form a superhydrophilic surface. The effect of surface roughness was examined at different average roughness (Ra) values ranging from 0.11 to 2.93 μm. The boiling heat transfer coefficients increased with an increase in roughness owing to the increased number of cavities. However, the superhydrophilic aluminum surfaces exhibited degradation of the heat transfer coefficients when compared with copper surfaces owing to the flooding of promising cavities. The superhydrophilic aluminum surfaces exhibited a higher critical heat flux (CHF) than the copper surfaces. The CHF was 1650 kW/m2 for Ra = 0.11 μm, and it increased to 2150 kW/m2 for Ra = 0.35 μm. Surface roughness is considered to affect CHF as it improves the capillary wicking on the superhydrophilic surface. However, further increase in surface roughness above 0.35 μm did not augment the CHF, even at Ra = 2.93 μm. This upper limit of the CHF appears to result from the hydrodynamic limit on the superhydrophilic surface, because the roughest surface with Ra = 2.93 μm still showed a faster liquid spreading speed.


2014 ◽  
Vol 887-888 ◽  
pp. 766-769 ◽  
Author(s):  
Huey Ling Chang ◽  
Chih Ming Chen ◽  
Chin Huang Sun ◽  
Jin Shyong Lin

This study produced a regularly arranged membrane, called anodic aluminum oxide (referred AAO), by mean of anodic oxidation treatment. The structure of AAO can be molecular self-assembly and its pore size is consistent. Also, the manufacturing process cost is low. These properties make the AAO be a nanotemplate material. This study further created a high quality of nanostructured film by electrochemical mould with the design of electrolyzer. In addition, a uniform nanothin film was grown on the aluminum surface in the stable control of current and temperature according to the conditions of different anode treatment. This film can form a nanopore array which the diameter can be controlled the size ranging from 15 nm to 400 nm. As results, the study can produce nanoporous template for various aperture by mean of anodic oxidation.


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