Laser Texturing for Superwetting Titanium Alloy and Investigation of Its Erosion Resistance

Erosion of materials is one of the major causes that lead to the malfunction of equipment and facilities, and surface texturing can be a solution for enhancement of erosion resistance. In this work, superwetting (superhydrophilic/superhydrophobic) titanium (Ti) alloy surface with periodic microstructure was prepared by a facile laser-based surface texturing approach which combines laser surface texturing and low-temperature annealing. The effect of laser-induced surface texture and wettability on the erosion resistance of the laser textured surface was studied. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to analyze the chemical surface microstructure and surface on the untreated and laser textured surfaces. The hardness and contact angle of the untreated surface, superhydrophilic surface and superhydrophobic surface were measured by microhardness tester and contact angle goniometer. Using an in-house built erosion experimental setup, the erosion resistance of the untreated surface, superhydrophilic surface and superhydrophobic surface was investigated. The experimental results demonstrate that micro-bumps are formed after laser surface texturing. In the meantime, the surface hardness for the laser textured surface with a step size of 150 μm is increased by 48% under the load of 1.961 N. Compared with the untreated surface, the erosion resistance is increased by 33.9%, 23.8% and 16.1%, respectively, for the superhydrophobic surface. The SEM results show that the untreated surface has large and deep impact pits, while the superhydrophobic surface only has small and shallow impact pits, indicating that the erosion process resulted in less damage to the substrate. The EDS results shows that superhydrophobicity plays a critical role in protecting the substrate from erosion. It is thus believed that the superhydrophobic surface has pronounced effects for improving the hardness and erosion resistance of Ti alloy.

Effect of the Type of Heterostructures on Photostimulated Alteration of the Surface Hydrophilicity: TiO2/BiVO4 vs. ZnO/BiVO4 Planar Heterostructured Coatings

Here, we report the results of comparative studies of the photostimulated hydrophilic behavior of heterostructured TiO2/BiVO4 and ZnO/BiVO4, and monocomponent TiO2 and ZnO nanocoating surfaces. The chemical composition and morphology of the synthesized nanocoatings were characterized by XPS, SEM, and AFM methods. The electronic energy structure of the heterostructure components (band gap, top of the valence band, bottom of the conduction band, and Fermi level position) was determined on the basis of experimental results obtained by XPS, UV-V absorption spectroscopy and Kelvin probe methods. According to their electronic energy structure, the ZnO/BiVO4 and TiO2/BiVO4 heterostructures correspond to type I and type II heterostructures, respectively. The difference in the type of heterostructures causes the difference in the charge transfer behavior at heterojunctions: the type II TiO2/BiVO4 heterostructure favors and the type I ZnO/BiVO4 heterostructure prevents the photogenerated hole transfer from BiVO4 to the outer layer of the corresponding metal oxide. The results of the comparative studies show that the interaction of the photogenerated holes with surface hydroxy-hydrated multilayers is responsible for the superhydrophilic surface conversion accompanying the increase of the surface free energy and work function. The formation of the type II heterostructure leads to the spectral sensitization of the photostimulated surface superhydrophilic conversion.

The Low-Temperature Ring during Droplet Impact on a Superhydrophilic Surface

Droplet impact on the solid surfaces is widespread in nature, daily life, and industrial applications. The spreading characteristics and temperature evolution in the inertial spreading regime are critical for the heat and mass transfer process on the solid-liquid interface. This work investigated the spreading characteristics and temperature distribution of the thin liquid film in the inertial rapid spreading regime of droplet impact on the heated superhydrophilic surfaces. Driven by the inertial and capillary force, the droplet rapidly spreads on the superhydrophilic surface, resulting in a high temperature center in the impact center surrounded by a the low-temperature ring. The formation of the unique the low-temperature ring on the heated superhydrophilic surface is due to the much smaller time scale of rapid spreading than that of heat transfer from the hot solid surface to the liquid film surface. CFD numerical simulation shows that the impacting droplet spreads and congests in the front of liquid film, leading to the formation of vortex velocity distribution in the liquid film. Increasing We number and wall temperature can accelerate the heat transfer rate of liquid film and shorten the existence time of the low-temperature ring. The findings of the the low-temperature ring on the superhydrophilic surface provide the guidelines to optimization of surface structures and functional coatings for enhancing heat transfer in various energy systems.

TiO2 Nanonetwork on Rough Ti Enhanced Osteogenesis In Vitro and In Vivo

The objective in this study was to enhance osteogenic responses (in vitro and in vivo) to roughened titanium (Ti) dental implants through the formation of superhydrophilic TiO2 nanonetwork surface structure. Sandblasting and acid etching (SLA) was used to roughen the Ti surface. An electrochemical anodization process was then used to form a superhydrophilic TiO2 nanonetwork on the SLA Ti surfaces. The pore size of the nanonetwork structure ranged from a few nanometers to more than 100 nm, which is on the same scale as many biological species. Human bone marrow mesenchymal stem cells were used as an in vitro test model. The TiO2 nanonetwork structure was shown to have a significantly positive effect on hydrophilicity, protein adsorption, cell adhesion, cell migration, cell mineralization, and the gene and protein expression of osteogenic markers. The osseointegration of an anodized SLA screw-type Ti dental implant was investigated in vivo via implantation in the femur of New Zealand white rabbits for durations of 4 or 12 wk. The presence of a superhydrophilic surface TiO2 nanonetwork was shown to significantly enhance the bone-to-implant contact of the roughened SLA screw-type Ti dental implants. Overall, the proposed superhydrophilic TiO2 nanonetwork structure on the roughened SLA Ti surface proved highly effective in enhancing osteogenic responses in vitro and in vivo.

Filmwise Condensation From Humid Air On a Vertical Superhydrophilic Surface: Explicit Roles of the Humidity Ratio Difference and the Degree of Subcooling

The process involving heat and mass transfer during filmwise condensation (FWC) in presence of non-condensable gases (NCG) has great significance in a large variety of engineering applications. The vapor mass flux leading to condensation and the resulting condensation heat transfer coefficient (CHTC) are dependent on the gradients of temperature and vapor mass fraction established near the condenser plate. The effects of the two most influencing thermodynamic parameters, i.e., the degree of subcooling and the difference of humidity ratio (between the free stream environment and on the condenser plate), have been characterized in this work both experimentally and through a mechanistic model. The vapor mass flux during condensation on a subcooled vertical superhydrophilic surface under a free convection regime is experimentally measured in a controlled environment (temperature and humidity) chamber. A mechanistic model, based on the similarity of energy and species transports, is formulated for the thermogravitational boundary layer over the condenser plate and tuned against the experimental results. Further, the model is used to obtain comprehensive data of the condensate mass flux and CHTC as functions of the salient thermal operating conditions over a wide parametric range. Results indicate that humidity ratio difference has a more pronounced influence on the condensation mass transfer rather than the degree of subcooling. The mechanistic model lends to the development of empirical correlations of condensate mass flux and CHTC as explicit functions of these two parameters for easy use in practical FWC configurations.

The Role of Slip and No Slip Behavior On Droplet Impingement

For the identification of role of slip and no slip conditions at the solid-liquid interface in case of hydrophobic, superhydrophilic and superhydrophobic surfaces, the experimentally determined velocity profiles are analysed. Before experimentation, each surface was characterized by using SEM, 2D and 3D Surface profilometer. The impact mapping results reveal that in case of hydrophobic surface, first no slip condition is achieved and then slip condition is noticed. Conversely, for superhydrophilic surface, initially slip and then no slip conditions are observed. Furthermore, in case of superhydrophobic surface, slip behaviour is observed throughout the process for the dimensionless time ranges 0.06-0.94 and this behaviour of the process promotes local enhancement of viscous and capillary forces. The experimentally obtained results are further tried to validate with the help of theoretical and visual observations.