scholarly journals A STEP FORWARD IN THE DETECTION OF BYPRODUCTS OF ANTHROPOGENIC ORGANIC MICROPOLLUTANTS IN CHLORINATED WATER

2021 ◽  
pp. e00148
Author(s):  
Cristina Postigo ◽  
Rubén Gil-Solsona ◽  
María Fernanda Herrera-Batista ◽  
Pablo Gago-Ferrero ◽  
Nikiforos Alygizakis ◽  
...  
Keyword(s):  
Organic Micropollutants

Resorcinarene Cavitand Polymers for the Remediation of Halomethanes and 1,4-Dioxane

2019 ◽  
Author(s):  
Luke Skala ◽  
Anna Yang ◽  
Max Justin Klemes ◽  
Leilei Xiao ◽  
William Dichtel
Keyword(s):  
Drinking Water ◽  
Activated Carbon ◽  
High Capacity ◽  
The United States ◽  
Water Sources ◽  
Disinfection Byproducts ◽  
Porous Polymer ◽  
Organic Micropollutants ◽  
Executive Summary ◽  
Regulatory Limits

<p>Executive summary: Porous resorcinarene-containing polymers are used to remove halomethane disinfection byproducts and 1,4-dioxane from water.<br></p><p><br></p><p>Disinfection byproducts such as trihalomethanes are some of the most common micropollutants found in drinking water. Trihalomethanes are formed upon chlorination of natural organic matter (NOM) found in many drinking water sources. Municipalities that produce drinking water from surface water sources struggle to remain below regulatory limits for CHCl<sub>3</sub> and other trihalomethanes (80 mg L<sup>–1</sup> in the United States). Inspired by molecular CHCl<sub>3</sub>⊂cavitand host-guest complexes, we designed a porous polymer comprised of resorcinarene receptors. These materials show higher affinity for halomethanes than a specialty activated carbon used for trihalomethane removal. The cavitand polymers show similar removal kinetics as activated carbon and have high capacity (49 mg g<sup>–1</sup> of CHCl<sub>3</sub>). Furthermore, these materials maintain their performance in real drinking water and can be thermally regenerated under mild conditions. Cavitand polymers also outperform activated carbon in their adsorption of 1,4-dioxane, which is difficult to remove and contaminates many public water sources. These materials show promise for removing toxic organic micropollutants and further demonstrate the value of using supramolecular chemistry to design novel absorbents for water purification.<br></p>

Multivariate micropollutants analysis in marine waters

1995 ◽  
Vol 32 (9-10) ◽  
pp. 341-348
Author(s):  
V. Librando ◽  
G. Magazzù ◽  
A. Puglisi
Keyword(s):  
Multivariate Data Analysis ◽  
Partial Least Squares Regression ◽  
Environmental Chemistry ◽  
Sampling Site ◽  
Principal Component ◽  
Least Squares Regression ◽  
Organic Micropollutants ◽  
Suspended Material ◽  
The Difference

The monitoring of water quality today provides a great quantity of data consisting of the values of the parameters measured as a function of time. In the marine environment, and especially in the suspended material, increasing importance is being given to the presence of organic micropollutants, particularly since some are known to be carcinogenic. As the number of measured parameters increases examining the data and their consequent interpretation becomes more difficult. To overcome such difficulties, numerous chemometric techniques have been introduced in environmental chemistry, such as Multivariate Data Analysis (MVDA), Principal Component Analysis (PCA) and Partial Least Squares Regression (PLSR). The use of the first technique in this work has been applied to the interpretation of the quality of Augusta bay, by measuring the concentration of numerous organic micropollutants, together with the classical water pollution parameters, in different sites and at different times. The MVDA has highlighted the difference between various sampling sites whose data were initially thought to be similar. Furthermore, it has allowed a choice of more significant parameters for future monitoring and more suitable sampling site locations.

Membranes In Organic Micropollutants Removal

2018 ◽  
Vol 22 (11) ◽  
pp. 1070-1102 ◽  
Author(s):  
Michal Bodzek ◽  
Krystyna Konieczny
Keyword(s):  
Organic Micropollutants

scholarly journals Solid-phase extraction cartridges with multi-walled carbon nanotubes and effect of the oxygen functionalities on the recovery efficiency of organic micropollutants

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Marta O. Barbosa ◽  
Rui S. Ribeiro ◽  
Ana R. L. Ribeiro ◽  
M. Fernando R. Pereira ◽  
Adrián M. T. Silva
Keyword(s):  
Carbon Nanotubes ◽  
Solid Phase Extraction ◽  
Solid Phase ◽  
Surface Groups ◽  
Phase Extraction ◽  
Organic Micropollutants ◽  
Oxidation Method ◽  
Hydrothermal Oxidation ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

AbstractPristine and functionalized multi-walled carbon nanotubes (MWCNTs) were investigated as adsorbent materials inside solid-phase extraction (SPE) cartridges for extraction and preconcentration of 8 EU-relevant organic micropollutants (with different pKa and polarity) before chromatographic analysis of surface water. The recoveries obtained were > 60% for 5/8 target pollutants (acetamiprid, atrazine, carbamazepine, diclofenac, and isoproturon) using a low amount of this reusable adsorbent (50 mg) and an eco-friendly solvent (ethanol) for both conditioning and elution steps. The introduction of oxygenated surface groups in the carbon nanotubes by using a controlled HNO3 hydrothermal oxidation method, considerably improved the recoveries obtained for PFOS (perfluorooctanesulfonic acid) and methiocarb, which was ascribed to the hydrogen bond adsorption mechanism, but decreased those observed for the pesticide acetamiprid and for two pharmaceuticals (carbamazepine and diclofenac), suggesting π–π dispersive interactions. Moreover, a good correlation was found between the recovery obtained for methiocarb and the amount of oxygenated surface groups on functionalized MWCNTs, which was mainly attributed to the increase of phenols and carbonyl and quinone groups. Thus, the HNO3 hydrothermal oxidation method can be used to finely tune the surface chemistry (and texture) of MWCNTs according to the specific micropollutants to be extracted and quantified in real water samples.

scholarly journals Heterotrophic enzymatic biotransformations of organic micropollutants in activated sludge

2021 ◽  
Vol 780 ◽  
pp. 146564
Author(s):  
David M. Kennes-Veiga ◽  
Bernadette Vogler ◽  
Kathrin Fenner ◽  
Marta Carballa ◽  
Juan M. Lema
Keyword(s):  
Activated Sludge ◽  
Organic Micropollutants

scholarly journals Promoting the degradation of organic micropollutants in tertiary moving bed biofilm reactors by controlling growth and redox conditions

2021 ◽  
Vol 414 ◽  
pp. 125535
Author(s):  
Ellen Edefell ◽  
Per Falås ◽  
Elena Torresi ◽  
Marinette Hagman ◽  
Michael Cimbritz ◽  
...  
Keyword(s):  
Redox Conditions ◽  
Organic Micropollutants ◽  
Moving Bed ◽  
Biofilm Reactors

Removal of organic micropollutants using advanced membrane-based water and wastewater treatment: A review

2020 ◽  
Vol 598 ◽  
pp. 117672 ◽  
Author(s):  
Noman Khalid Khanzada ◽  
Muhammad Usman Farid ◽  
Jehad A. Kharraz ◽  
Jungwon Choi ◽  
Chuyang Y. Tang ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Organic Micropollutants ◽  
Water And Wastewater Treatment ◽  
Water And Wastewater
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