Visible-light Enabled C4-Thiocyanation of Pyrazoles by Graphite-Phase Carbon Nitride(g-C3N4)

2021 ◽  
pp. 153253
Author(s):  
Junyi Pan ◽  
Cheng Liu ◽  
Jianqiang Wang ◽  
Yunqiao Dai ◽  
Shengyu Wang ◽  
...  
2021 ◽  
Author(s):  
yin zhao ◽  
hong qin ◽  
Qianlan luo ◽  
ziwei wang ◽  
han wang ◽  
...  

Abstract Using semiconductor photocatalysts for antibiotic contaminants degradation under visible light has become a hot topic in recent years. Herein, a novel cadmium doped graphite phase carbon nitride (Cd/g-C3N4) photocatalyst was successfully constructed via 60 °C oil bath method to degrade tetracycline. Experimental and characterization results revealed that cadmium was well doped at g-C3N4 surface and exhibited high intercontact with g-C3N4. Meanwhile, Cd/g-C3N4 presented excellent electrical conductivity and inhibited the recombination of electron-hole pairs. The introduction of cadmium significantly improved the photocatalytic activity and the degradation efficiency of 10 Cd/g-C3N4 reached to 89.09%, which was exceeded 2.0 times than pure g-C3N4 (43.99%). Additionally, the quenching experiments and electron spin-resonance tests exhibited holes (h+), hydroxyl radicals (•OH) and superoxide radicals (•O2−) were dominated active species in TC degradation. Furthermore, the effects of various conditions on the reaction process, such as different pH, initial TC concentrations and catalyst dosage, were also researched. This work gives a reasonable point to synthesize high-efficiency and economic photocatalysts.


2021 ◽  
Vol 898 (1) ◽  
pp. 012025
Author(s):  
Wei’e Wang ◽  
Bohong Wu ◽  
Zhiyang Gao ◽  
Yuguang Lv

Abstract Photocatalysts are mainly divided into two categories: one is that they have good response to sunlight and visible light, such as BiVO4 and Fe2O3; One is that it has its own defects and can not make full use of the energy converted by visible light. In recent years, a class of oxides have attracted much attention because of their good performance of visible light photocatalytic degradation of pollutants. People also have a strong interest in the research of compound oxides in pollutant degradation. In order to further clarify the photocatalytic mechanism of GCB composite samples, different capture agents were added to determine the main active species in the photocatalytic process. Only through the method of modification, the synergistic effect can enhance its photocatalytic activity. 1% g-C3N4/BiVO4(GCB) sample, drhb = 90.4%, the photocatalytic activity did not change significantly after adding IPA. After adding EDTA and VC, the photocatalytic activity decreased, drhb = 32.6% and drhb = 51%. Therefore, the experiments show that h+ and ·O2- are active species of GCB catalytic system, O2 is more important for RHB degradation.


RSC Advances ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 6383-6394 ◽  
Author(s):  
Haishuai Li ◽  
Linlin Cai ◽  
Xin Wang ◽  
Huixian Shi

A noval ternary nanocomposite AgCl/Ag3PO4/g-C3N4 was successfully synthesized for photocatalytic degradation of methylene blue, methylparaben and inactivation of E. coli under visible light irradiation, showing excellent photocatalytic degradation performance and stability.


ChemSusChem ◽  
2014 ◽  
Vol 7 (3) ◽  
pp. 738-742 ◽  
Author(s):  
Xiangju Ye ◽  
Yanjuan Cui ◽  
Xinchen Wang

2021 ◽  
pp. 2004001
Author(s):  
Youyu Duan ◽  
Yang Wang ◽  
Liyong Gan ◽  
Jiazhi Meng ◽  
Yajie Feng ◽  
...  

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