A modeling of the irreversible melting kinetics of polymer crystals responding to temperature modulation with retardation of melting rate coefficient

Polymer ◽  
2001 ◽  
Vol 42 (10) ◽  
pp. 4727-4730 ◽  
Author(s):  
A Toda
2018 ◽  
Vol 18 (6) ◽  
pp. 3637-3643 ◽  
Author(s):  
Akihiko Toda ◽  
Ken Taguchi ◽  
Koji Nozaki ◽  
Tatsuya Fukushima ◽  
Hironori Kaji

1999 ◽  
Vol 330 (1-2) ◽  
pp. 75-83 ◽  
Author(s):  
Akihiko Toda ◽  
Takeshi Arita ◽  
Chiyoko Tomita ◽  
Masamichi Hikosaka

Soft Matter ◽  
2016 ◽  
Vol 12 (6) ◽  
pp. 1765-1777 ◽  
Author(s):  
Lara A. Patel ◽  
James T. Kindt

Frozen lipid vesicles simulated using a coarse-grained potential and subject to temperature jumps respond by melting on timescales similar to those observed experimentally; changes in curvature stress appear to play a dominant role in controlling the melting rate.


2016 ◽  
Vol 17 (2) ◽  
pp. 256-261
Author(s):  
S.G. Orlovskaya ◽  
F.F. Karimova ◽  
M.S. Shkoropado

A new approach is developed to study melting kinetics of n-Octadecane. Modelling of heat transfer during the melting of solid particle is described. The calculation results are in good agreement with experimental data on melting duration. The effect of applied electric field on melting kinetics is studied. Almost twofold increase of melting time is found in an electric field of strength E = 82 kv/m. In addition a rotation of a solid core inside a melt is observed, which is a manifestation of Quinke effect. A droplet shape evolution during phase transition is described. It is shown that initially elongated particle is almost spherical near the melting point and elongates again with the temperature rise. This shape evolution is explained by non-monotonous change of surface tension and is connected with rotational phase. Thus a possibility is shown to control a melting rate of normal alkanes using electric field.


Crystals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 901
Author(s):  
Kinnor Chattopadhyay ◽  
Rodolfo Morales-Davila ◽  
Alfonso Nájera-Bastida ◽  
Jafeth Rodríguez-Ávila ◽  
Carlos Rodrigo Muñiz-Valdés

Molten steel is alloyed during tapping from the melting furnace to the argon-bottom stirred ladle. The metallic additions thrown to the ladle during the ladle filling time are at room temperature. The melting rates or kinetics of sinking-metals, like nickel, are simulated through a multiphase Euler–Lagrangian mathematical model during this operation. The melting rate of a metallic particle depends on its trajectory within regions of the melt with high or low turbulence levels, delaying or speeding up their melting process. At low steel levels in the ladle, the melting rates are higher on the opposite side of the plume zone induced by the bottom gas stirring. This effect is due to its deviation after the impact of the impinging jet on the ladle bottom. The higher melting kinetics are located on both sides at high steel levels due to the more extensive recirculation flows formed in taller baths. Making the additions above the eye of the argon plume spout increases the melting rate of nickel particles. The increase of the superheat makes the heat flux more significant from the melt to the particle, increasing its melting rate. At higher superheats, the melting kinetics become less dependent on the fluid dynamics of the melt.


2008 ◽  
Vol 41 (1) ◽  
pp. 120-127 ◽  
Author(s):  
Akihiko Toda ◽  
Isao Kojima ◽  
Masamichi Hikosaka

1996 ◽  
Vol 464 ◽  
Author(s):  
Mark S. Feldman ◽  
Anna L. Lin ◽  
Raoul Kopelman

AbstractWe investigate the anomalous kinetics in one dimension of a diffusion limited catalytic trapping reaction, A + T → T, by measuring the oxidation of glucose. The reaction is carried out in a thin capillary tube, and the depletion of oxygen in the vicinity of the reaction front is monitored by the fluorescence of a Ru(II) dye. Theoretical results and simulations have predicted an asymptotic t1/2 dependence for the rate coefficient. We observe a depedence on t0.56, with what appears to be an asymptotic behavior approaching t1/2.


2008 ◽  
Vol 47 (7) ◽  
pp. 6016-6022 ◽  
Author(s):  
Yung-Sung Hsu ◽  
Ying-Da Liu ◽  
Yung-Chiun Her ◽  
Shun-Te Cheng ◽  
Song-Yeu Tsai

2003 ◽  
Vol 36 (11) ◽  
pp. 4042-4050 ◽  
Author(s):  
Patrick S. Dai ◽  
Peggy Cebe ◽  
Malcolm Capel ◽  
Rufina G. Alamo ◽  
Leo Mandelkern

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