Evaluation of an HCl process for leaching of low-grade highly siliceous bauxite ore

Author(s):  
S.A. Hussain ◽  
R. Jamal
Keyword(s):  
2020 ◽  
Vol 195 ◽  
pp. 105368 ◽  
Author(s):  
Syed Sikandar Shah ◽  
Mauricio Cesar Palmieri ◽  
Sandra Regina Pombeiro Sponchiado ◽  
Denise Bevilaqua

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7740
Author(s):  
Adamantia Lazou ◽  
Leiv Kolbeinsen ◽  
Jafar Safarian

This work evaluates the characteristics of calcium aluminate slag and pig iron samples obtained from the smelting of calcined and reduced diasporic bauxite ore. The study is conducted in the Pedersen process framework, which is a method to produce alumina from low-grade resources. Parameters such as the effect of crucible type, lime addition, and atmospheric conditions are studied considering the characteristics of the product pig irons and calcium aluminate slags for further uses. The behavior of the bauxite and distribution of the species between slag and metal was assessed based on the applied analytical techniques and thermodynamic calculations. Iron was reduced and separated from the slags in the presence of carbon (graphite crucible) for both the reduced and calcined bauxite. Si and Ti were mainly concentrated in the slags. Iron was separated from the slag in the absence of carbon (alumina crucible) for the H2-reduced bauxite. The results show that slags with increased lime additions are composed mainly of 5CaO.Al2O3 and CaO.Al2O3, that are considered highly leachable compounds. An optimum CaO/Al2O3 mass ratio of 1.12 was suggested. The presence of O2 and/or OH- in the furnace atmosphere will result in the formation of 12CaO.7Al2O3.


2015 ◽  
Vol 32 (4) ◽  
pp. 209-214
Author(s):  
X. Y. Yu ◽  
X. A. Wei ◽  
A. Zeng ◽  
B. Feng

Author(s):  
Thomas R. McKee ◽  
Peter R. Buseck

Sediments commonly contain organic material which appears as refractory carbonaceous material in metamorphosed sedimentary rocks. Grew and others have shown that relative carbon content, crystallite size, X-ray crystallinity and development of well-ordered graphite crystal structure of the carbonaceous material increases with increasing metamorphic grade. The graphitization process is irreversible and appears to be continous from the amorphous to the completely graphitized stage. The most dramatic chemical and crystallographic changes take place within the chlorite metamorphic zone.The detailed X-ray investigation of crystallite size and crystalline ordering is complex and can best be investigated by other means such as high resolution transmission electron microscopy (HRTEM). The natural graphitization series is similar to that for heat-treated commercial carbon blacks, which have been successfully studied by HRTEM (Ban and others).


Author(s):  
V.K. Berry

There are two strains of bacteria viz. Thiobacillus thiooxidansand Thiobacillus ferrooxidanswidely mentioned to play an important role in the leaching process of low-grade ores. Another strain used in this study is a thermophile and is designated Caldariella .These microorganisms are acidophilic chemosynthetic aerobic autotrophs and are capable of oxidizing many metal sulfides and elemental sulfur to sulfates and Fe2+ to Fe3+. The necessity of physical contact or attachment by bacteria to mineral surfaces during oxidation reaction has not been fairly established so far. Temple and Koehler reported that during oxidation of marcasite T. thiooxidanswere found concentrated on mineral surface. Schaeffer, et al. demonstrated that physical contact or attachment is essential for oxidation of sulfur.


Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.


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