Water vapour pressure above saturated salt solutions at low temperatures

1999 ◽  
Vol 155 (2) ◽  
pp. 297-309 ◽  
Author(s):  
V Morillon ◽  
F Debeaufort ◽  
J Jose ◽  
J.F Tharrault ◽  
M Capelle ◽  
...  
1970 ◽  
Vol 53 (3) ◽  
pp. 753-762
Author(s):  
JOHN MACHIN

1. The construction, maintenance and calibration of a sensitive instrument capable of making numerous vapour-pressure measurements within humidity gradients by the dew-point method is described. 2. Coefficients of diffusion of water vapour in air, calculated from observed vapour-pressure gradients and measured rates of evaporation agree with theoretical and other experimental values in still air. 3. Apparent coefficients in wind speeds between 10 and 100 cm/s were significantly lower than those in still air. 4. This finding, together with the performance of the dew-point probe, is discussed in relation to its possible use in the study of evaporation from animals and plants.


Nanoscale ◽  
2018 ◽  
Vol 10 (45) ◽  
pp. 21518-21532 ◽  
Author(s):  
Andi Cuko ◽  
Antoni Macià Escatllar ◽  
Monica Calatayud ◽  
Stefan T. Bromley

The stabilities and properties of globally optimised (TiO2)M(H2O)N and (SiO2)M(H2O)N clusters with M = 4–16 and a range of N/M ratios are studied with respect temperature and water vapour pressure. Our systematic study provides a comparative reference for understanding hydration of nano-silica and nano-titania.


Author(s):  
J. D. C. McConnell

SummaryA thermogravimetric vacuum microbalance has been used to study the reaction between β-soluble anhydrite and water vapour in the temperature range 20–100° C. Equilibrium water-vapour pressures for the hydration reaction in this temperature range were determined directly and have been compared with available data obtained by Kelly, Southard, and Anderson (1941) in the temperature range 80–120° C. The kinetics of the hydration and dehydration reactions have also been studied in a series of isothermal experiments with varying water-vapour pressure. These experiments indicate that in a vapour-pressure range close to the equilibrium value very low rates for both hydration and dehydration are observed. Outside this range of vapour pressures both hydration and dehydration rates increase suddenly and show an approximately linear increase with imposed water-vapour pressure.At low temperatures (25° C) the dehydration reaction has an associated activation energy of approximately 10 kcal mole−1. In the same temperature range additional, physical adsorption of water vapour by the specimen was noted.


2001 ◽  
Vol 7 (S2) ◽  
pp. 782-783
Author(s):  
C. J. Gilpin.

Of all the commercially available scanning electron microscopes which operate at “low vacuum” the ESEM is the most suitable for examining biological samples. in order to maintain samples with liquid water present the specimen chamber must be capable of operating at a pressure of at least 4.6 Torr (611 pascals) of water vapour pressure (the vapour pressure of water at 0°C). Use of lower pressures or a chamber gas other than water vapour will result in evaporation of water from the sample at a rate dependant on the partial pressure difference between the sample and its surrounding environment. Tables of relative humidity as a function of water vapour pressure and temperature are readily available to calculate desired settings for the microscope.One of the difficulties associated with examining fresh biological material is the need to have the microscope and sample available in the same location at the same time.If sample collection occurs at a site remote from the microscope inevitable necrotic changes will occur before examination can be carried out.


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