Quantitative detection of bisphenol A and bisphenol A diglycidyl ether metabolites in human plasma by liquid chromatography–electrospray mass spectrometry

Author(s):  
Koichi Inoue ◽  
Akiko Yamaguchi ◽  
Megumi Wada ◽  
Yoshihiro Yoshimura ◽  
Tsunehisa Makino ◽  
...  
Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3682
Author(s):  
Monika Beszterda ◽  
Małgorzata Kasperkowiak ◽  
Magdalena Frańska ◽  
Sandra Jęziołowska ◽  
Rafał Frański

The acetonitrile extracts of can-coating materials have been analyzed by using high-pressure liquid chromatography/electrospray ionization-mass spectrometry (HPLC/ESI-MS). On the basis of detected ions [M + H]+, [M + NH4]+, [M + Na]+ and product ions, the ethoxylated butoxyethanol-bisphenol A diglycidyl ether adducts were identified in two of the analyzed extracts. Although the oxyethylene unit-containing compounds are widely used for the production of different kinds of materials, the ethoxylated species have not been earlier detected in epoxy resin can-coatings.


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