Research on the novel technology of fluidized roasting reduction of low-grade
pyrolusite coupling with pretreatment of stone coal has been conducted.
According to the response surface design and the analysis of results,
orthogonal experiments have been conducted on the major factors and effects
of the factors on the manganese reduction efficiency have been studied. The
quadratic model between the manganese reduction efficiency and the factors
has been established. Meanwhile, the contour or 3D response surface of the
manganese reduction efficiency among various factors has been presented. The
maximum manganese reduction efficiency could be optimized to nearly 100%,
when the mass ratio of stone coal to pyrolusite was 2.5:1, the roasting
temperature of stone coal was 1080?C, the roasting temperature of pyrolusite
was 775?C, and the roasting time was 2h. The results of the manganese
reduction efficiency of the actual experiments were close to those of the
fitting model by the verification experiments, indicating that the optimum
solution has a relatively high reliability. Other low-grade pyrolusite such
as Guangxi pyrolusite (China), Hunan pyrolusite (China), and Guizhou
pyrolusite (China) were tested and all these materials responded well giving
nearly 100% manganese reduction efficiency.