scholarly journals Corrosion resistance of cerium-doped zinc calcium phosphate chemical conversion coatings on AZ31 magnesium alloy

2016 ◽  
Vol 26 (2) ◽  
pp. 472-483 ◽  
Author(s):  
Rong-chang ZENG ◽  
Yan HU ◽  
Fen ZHANG ◽  
Yuan-ding HUANG ◽  
Zhen-lin WANG ◽  
...  
Author(s):  
P. Amaravathy ◽  
T.S. Sampath Kumar

A simple chemical conversion coating was adopted to deposit zinc calcium phosphate (ZCP) coating and strontium doped ZCP (SZCP) coating on AZ31 magnesium alloy to induce biocompatibility and reduce the degradation rate. The surface morphology, chemical composition and functional groups of the coating were characterized by Scanning Electron Microscopy with Energy Dispersive X-Ray Spectroscopy (SEM-EDS), X-Ray Diffraction (XRD) studies and Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy respectively. SZCP coating formed at 20 min deposition time produced crack free surface with a high degree of crystallinity with barrier property, which ultimately retards the dissolution of magnesium in Simulated Body Fluid (SBF). The corrosion resistance of AZ31 magnesium alloy was improved by SZCP coating as evident from hydrogen evolution test (HET). Cytotoxicity evaluation with L969 cells showed that Sr doped ZCP coatings showed less toxicity on resorbable magnesium alloys.


2009 ◽  
Vol 610-613 ◽  
pp. 927-930 ◽  
Author(s):  
Wei Zhang ◽  
Fu Sheng Pan ◽  
Ming Bo Yang ◽  
Jin Zhang ◽  
Tao Wen

Silane treatment is an effective method of chemical conversion as a replacement for chromium treatments. In this paper, KH-550 silane treatment was adopted to improve the corrosion resistance AZ31 magnesium alloy. Hydrolysis process of KH-550 in the silane solutions was detected by the conductivity detection method. It was found that KH-550 silane could be hydrolyzed easily and its hydrolysis time was about 10 minutes. Polarization curve and salt immersion were carried out to investigate the corrosion behavior of the coated magnesium alloy treated by five kinds of silane solutions with different silane concentrations. When the concentration of KH-550 in the silane solution was 8%, the coated specimens by heating at 100°C for half an hour after the surfaces dry had more excellent corrosion resistance than others. It was shown that the KH-550 silane treatment could form a -Si-O-M covalent bonded film/metal interface and -Si-O-Si siloxane chains to improve the corrosion resistance of coated magnesium alloy.


RSC Advances ◽  
2015 ◽  
Vol 5 (31) ◽  
pp. 24586-24590 ◽  
Author(s):  
Huan Zhao ◽  
Shu Cai ◽  
Zetao Ding ◽  
Ming Zhang ◽  
Yan Li ◽  
...  

A simple method has been proposed for the preparation of magnesium phosphate conversion coating on a magnesium alloy (AZ31) to achieve protection against fast degradation in an implant environment.


Vacuum ◽  
2021 ◽  
pp. 110146
Author(s):  
Wenling Xie ◽  
Yiman Zhao ◽  
Bin Liao ◽  
Pan Pang ◽  
Dongsing Wuu ◽  
...  

2012 ◽  
Vol 22 (11) ◽  
pp. 2713-2718 ◽  
Author(s):  
Xue-jun CUI ◽  
Chun-hai LIU ◽  
Rui-song YANG ◽  
Ming-tian LI ◽  
Xiu-zhou LIN ◽  
...  

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 784
Author(s):  
Longlong Zhang ◽  
Yuanzhi Wu ◽  
Tian Zeng ◽  
Yu Wei ◽  
Guorui Zhang ◽  
...  

The purpose of this study was to improve the cellular compatibility and corrosion resistance of AZ31 magnesium alloy and to prepare a biodegradable medical material. An aminated hydroxyethyl cellulose (AHEC) coating was successfully prepared on the surface of a micro-arc oxide +AZ31 magnesium alloy by sol–gel spinning. The pores of the micro-arc oxide coating were sealed. A polarization potential test analysis showed that compared to the single micro-arc oxidation coating, the coating after sealing with AHEC significantly improved the corrosion resistance of the AZ31 magnesium alloy and reduced its degradation rate in simulated body fluid (SBF). The CCK-8 method and cell morphology experiments showed that the AHEC + MAO coating prepared on the AZ31 magnesium alloy had good cytocompatibility and bioactivity.


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