Washoff of Dicamba and 3,6-Dichlorosalicylic Acid from Turfgrass Foliage

1993 ◽  
Vol 7 (2) ◽  
pp. 437-442 ◽  
Author(s):  
Mark J. Carroll ◽  
Robert L. Hill ◽  
Emy Pfeil ◽  
Albert E. Herner

The functional relationships between rainfall intensities and amounts, and the washoff of dicamba and 3,6-DCSA from turfgrass foliage were determined. Dicamba was applied to Kentucky bluegrass field plots and the turfgrass was subjected to 2 to 58 mm of simulated rainfall 18 to 48 h later. Rainfall was applied at an average intensity of 20.6 or 39.9 mm h−1. The 39.9 mm h−1intensity reduced dicamba washoff by 10% for a given amount of rainfall. Washoff of 3,6-DCSA was independent of rainfall intensity. When averaged over intensities, washoff of dicamba was best described by the equation y = 1 − 0.341x0.187, and 3,6-DCSA washoff by the equation y = exp(-0.210x), where x represents millimeters of rainfall and y, the proportion of compound remaining on the foliage after rainfall.

Soil Research ◽  
2004 ◽  
Vol 42 (1) ◽  
pp. 17 ◽  
Author(s):  
K. Müller ◽  
M. Trolove ◽  
T. K. James ◽  
A. Rahman

Runoff potential of 5 herbicides (acetochlor, atrazine, hexazinone, pendimethalin, and terbuthylazine) was evaluated in a small-scale study under simulated rainfall on a cultivated Hamilton clay loam soil. At 24 h after herbicide application, rainfall events of different intensities were simulated to 0.5-m2 field plots with 20% (70, 88, and 111 mm/h) and 30% (60, 70, and 80 mm/h) slope, respectively. The objective of this study was to compare the behaviour of pesticides covering a range of properties under identical hydrodynamic conditions. Sediment amounts and herbicide concentrations were determined in the runoff samples. As the transported sediment amounts were not sufficient for chemical analyses, herbicide residues attached to sediment were estimated using Kd values determined locally for the soil. Whereas pendimethalin concentrations followed no noticeable pattern, the concentrations for the other herbicides were highest in the first runoff samples, and decreased exponentially with further rain. Results show that herbicides were primarily transported in their dissolved form with the exception of pendimethalin. Slope affected cumulative runoff, sediment, and herbicide losses significantly (P < 0.05). The impact of increased rainfall intensity on runoff initiation followed a similar trend, but herbicide losses from plots exposed to different intensities were not always significant. Losses dissolved in runoff from plots with 20% slope were ≤1% of the applied herbicide, whereas on plots with 30% slope the maximum recorded loss was 65%. Here, losses for all herbicides ranged between 1 and 7% at 60 mm/h and 8 and 65% at 80 mm/h. Exports of herbicides with moderate solubility were negatively correlated with their Kd values and their water solubility.


Soil Research ◽  
1983 ◽  
Vol 21 (2) ◽  
pp. 109 ◽  
Author(s):  
MJ Singer ◽  
PH Walker

The 20-100 mm portion of a yellow podzolic soil (Albaqualf) from the Ginninderra Experiment Station (A.C.T.) was used in a rainfall simulator and flume facility to elucidate the interactions between raindrop impact, overland water flow and straw cover as they affect soil erosion. A replicated factorial design compared soil loss in splash and runoff from 50 and 100 mm h-1 rainfall, the equivalent of 100 mm h-1 overland flow, and 50 and 100 mm h-1 rainfall plus the equivalent of 100 mm h-' overland flow, all at 0, 40 and 80% straw cover on a 9% slope. As rainfall intensity increased, soil loss in splash and runoff increased. Within cover levels, the effect of added overland flow was to decrease splash but to increase total soil loss. This is due to an interaction between raindrops and runoff which produces a powerful detaching and transporting mechanism within the flow known as rain-flow transportation. Airsplash is reduced, in part, because of the changes in splash characteristics which accompany changes in depths of runoff water. Rain-flow transportation accounted for at least 64% of soil transport in the experiment and airsplash accounted for no more than 25% of soil transport The effects of rainfall, overland flow and cover treatments, rather than being additive, were found to correlate with a natural log transform of the soil loss data.


CATENA ◽  
2019 ◽  
Vol 177 ◽  
pp. 92-100 ◽  
Author(s):  
Yuxin Liu ◽  
Yan Xin ◽  
Yun Xie ◽  
Wenting Wang

Weed Science ◽  
1975 ◽  
Vol 23 (4) ◽  
pp. 285-288 ◽  
Author(s):  
F. L. Baldwin ◽  
P. W. Santelmann ◽  
J. M. Davidson

Specially constructed runoff plots were used to study the effect of simulated rainfall intensity, antecedent soil moisture, and subsequent rainfall on prometryn [2,4-bis(isopropylamino)-6-methylthio-s-triazine] movement across and through a field soil with a 1% slope. The first cm (45.4 L) of runoff was collected and subdivided. The initial 3.8 L of runoff water generally contained a higher concentration of prometryn than did a composite from the next 41.6 L. The sediment contained a higher prometryn concentration than did the runoff water. However, due to the greater volume of water lost compared to sediment, over 90% of the prometryn lost was in the water fraction. When prometryn was applied to a dry soil and rainfall simulated, runoff losses of prometryn were 0.5% or less of the total amount initially applied. The first runoff producing simulated rainfall caused the largest prometryn losses, but prometryn could not be detected in the runoff 1 month subsequent to application. Prometryn was never detected at soil depths greater than 5 cm. Prometryn runoff was greater from plots in which the soil was wet at the time of application.


Oikos ◽  
2010 ◽  
Vol 120 (4) ◽  
pp. 570-581 ◽  
Author(s):  
Benjamin G. Jackson ◽  
Pablo Martin ◽  
Marie-Charlotte Nilsson ◽  
David A. Wardle

2015 ◽  
Vol 72 (3) ◽  
pp. 484-490 ◽  
Author(s):  
Li Qinqin ◽  
Chen Qiao ◽  
Deng Jiancai ◽  
Hu Weiping

An understanding of the characteristics of pollutants on impervious surfaces is essential to estimate pollution loads and to design methods to minimize the impacts of pollutants on the environment. In this study, simulated rainfall equipment was constructed to investigate the pollutant discharge process and the influence factors of urban surface runoff (USR). The results indicated that concentrations of total suspended solids (TSS), total nitrogen (TN), total phosphorus (TP) and chemical oxygen demand (COD) appeared to be higher in the early period and then decreased gradually with rainfall duration until finally stabilized. The capacity and particle size of surface dust, rainfall intensity and urban surface slopes affected runoff pollution loads to a variable extent. The loads of TP, TN and COD showed a positive relationship with the surface dust capacity, whereas the maximum TSS load appeared when the surface dust was 0.0317 g·cm−2. Smaller particle sizes (&lt;0.125 mm) of surface dust generated high TN, TP and COD loads. Increases in rainfall intensity and surface slope enhanced the pollution carrying capacity of runoff, leading to higher pollution loads. Knowledge of the influence factors could assist in the management of USR pollution loads.


2011 ◽  
Vol 347-353 ◽  
pp. 2094-2097 ◽  
Author(s):  
Pei Qing Xiao ◽  
Wen Yi Yao ◽  
Chang Gao Wang

Runoff, sediment yield and infiltration process of shrub plots were studied under rainfall intensities of 45, 87 and 127 mm/h with 20° slope gradient using simulated rainfall experiment. The results showed that cumulative runoff and cumulative sediment yield of shrub plot had an obvious positive correlation with rainfall time. Under rainfall intensity of 45 mm/h, runoff and sediment yield of shrub plot kept a constant level. Under rainfall intensity of 87 mm/h, runoff kept a fluctuant increase, whereas sediment yield basically kept steady. Under rainfall intensity of 127 mm/h, runoff and sediment yield of shrub plot increased evidently due to the formation of erosion pits. Infiltration rate of shrub plot had a negative relation with runoff as well as sediment yield.


Weed Science ◽  
1969 ◽  
Vol 17 (1) ◽  
pp. 13-15 ◽  
Author(s):  
G. S. Smith ◽  
L. M. Callahan

Common Kentucky bluegrass (Poa pratensis L.) sod-plugs were grown in the greenhouse in soil freshly treated with 11 herbicides and in soil collected from the 0 to 2 and 2 to 4-inch depths of field plots treated 10 months earlier with the same herbicides. Fresh herbicide treatments reduced significantly the root regrowth of the bluegrass plants. The 12-lb/A rate of the fresh application of 1-(2-methylcyclohexyl)-3-phenylurea (siduron) caused the least chemical inhibition of root regrowth. The most phytotoxic fresh applications were 2-chloro-4-ethylamino-6-isopropylamino-s-triazine (atrazine) and 2-chloro-4,6-bis(ethylamino)-s-triazine (simazine), both killing the bluegrass plants at the 4 lb /A rate. Root regrowth of bluegrass grown in the herbicide residue samples was significantly reduced for all treatments. Herbicides which tended to persist in the 0 to 2-inch soil level and were most phytotoxic to root regrowth were simazine, polychlorodicyclopentadiene isomers (hereinafter referred to as bandane), N-(2-mercaptoethyl)-benzenesulfonamide S-(O,O-diisopropyl phosphorodithioate) (bensulide), and 2,6-di-tert-butyl-p-tolyl-methylcarbamate (terbutol). Those herbicides which tended to leach into the 2 to 4-inch soil level and cause the greatest reduction of root regrowth were N-butyl-N-ethyl-alpha, alpha, alpha-trifluoro-2,6-dinitro-p-toluidine (benefin), α,α,α-trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine (trifluralin), atrazine, and O-(2,4-dichlorophenyl) O-methyl isopropylphosphoramidothioate (DMPA). Herbicides which tended to leach uniformly throughout the 0 to 2 and 2 to 4-inch soil layers were siduron, an equal mixture of 1,1-dimethyl-4,6-diisopropyl-5-indanyl ethyl ketone and 1,1-dimethyl-4,6-diisopropyl-7-indanyl ethyl ketone (hereinafter referred to as sin-done), and dimethyl 2,3,5,6-tetra-chloroterephthalate (DCPA).


1986 ◽  
Vol 66 (3) ◽  
pp. 761-771 ◽  
Author(s):  
M. S. SHAROM ◽  
L. V. EDGINGTON

Soil thin layer chromatography studies showed that metalaxyl (methyl-N-(2,6-dimethylphenyl)-N-(2-methoxyacetyl)alaninate) was similar to 2,4-D and more mobile than pyrazone > permethrin. Soil column studies indicated that approximately 0, 9, 73 and 83% of the applied fungicide leached through a 25-cm soil column after being subjected to 5, 10, 15 and 20 cm of simulated rainfall, respectively. A study on the effects of sequential periods of rain and dry spells on movement of metalaxyl showed that the fungicide was leached with each 5 cm simulated rainfall but moved upward during the dry cycle. There was no leachate from soil columns that received four increments of 5 cm of simulated rainfall alternated with a 48-h drying cycle. However, approximately 32% of the applied metalaxyl was leached through soil columns that received similar rainfall treatment alternated with a 24-h drying cycle. Field plot studies indicated that most of the soil-incorporated metalaxyl remained in the upper 0–30 cm, with approximately 10% being leached into the 30- to 45-cm zone. The half-life of metalaxyl in soil from field plots and six growers’ farms ranged from 3 to 5 wk. Metalaxyl acid, a possible metabolite, was not detected in any of the soil samples. Metalaxyl and its acid were not detected in either the water or sediment of Big Creek which drains the tobacco region.Key words: Metalaxyl, mobility, persistence, environmental contamination


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