scholarly journals Coupling Time-Resolved in-situ Experiments with Three-Dimensional Imaging - a New Approach to Defect Evolution Studies

2011 ◽  
Vol 17 (S2) ◽  
pp. 440-441
Author(s):  
I Robertson ◽  
G Liu ◽  
J Kacher ◽  
I Robertson
Keyword(s):  
Three Dimensional ◽  
Three Dimensional Imaging ◽  
Time Resolved ◽  
New Approach ◽  
In Situ Experiments ◽  
Defect Evolution ◽  
Coupling Time

Extended abstract of a paper presented at Microscopy and Microanalysis 2011 in Nashville, Tennessee, USA, August 7–August 11, 2011.

Pulsed Microwave Processing of High-TC Superconducting Films

1992 ◽  
Vol 269 ◽  
Author(s):  
R. B. James ◽  
R. A. Alvarez ◽  
A. K. Stamper ◽  
X. J. Bao ◽  
T. E. Schlesinger ◽  
...  
Keyword(s):  
Phase Transition ◽  
Barium Copper Oxide ◽  
Precursor Film ◽  
Silicon Substrates ◽  
Molten Layer ◽  
Time Resolved ◽  
Barium Copper ◽  
In Situ Experiments ◽  
Yttrium Barium

ABSTRACTWe have used 2.0-μsec microwave pulses at a frequency of 2.856 GHz to rapidly heat thin amorphous yttrium-barium-copper-oxide (YBCO) films deposited onto silicon substrates. The samples were irradiated inside a WR-284 waveguide by single-pass TE10 pulses in a traveling wave geometry. X-ray diffractometry studies show that an amorphous-to-crystalline phase transition occurs for incident pulse powers exceeding about 6 MW, in which case the amorphous YBCO layer is converted to Y2BaCuO5. Microscopy of the irradiated film reveals that the phase transition is brought about by melting of the YBCO precursor film and crystallization of the molten layer upon solidification. Time-resolved in situ experiments of the microwave reflectivity (R) and transmissivity (T) show that there is an abrupt change in R for microwave pulse powers exceeding the melt threshold, so that measurements of R and T can be used to monitor the onset of surface melting.

scholarly journals Ballast bed resistance characteristics based on discrete-element modeling

2018 ◽  
Vol 10 (6) ◽  
pp. 168781401878146 ◽  
Author(s):  
Zhiping Zeng ◽  
Shanyi Song ◽  
Weidong Wang ◽  
Haijian Yan ◽  
Guoshu Wang ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Discrete Element ◽  
Discrete Element Modeling ◽  
Slope Gradient ◽  
Three Dimensional Model ◽  
Lateral Resistance ◽  
In Situ Experiments ◽  
Distribution Limits ◽  
Longitudinal Resistance

In this study, in situ experiments were conducted to study the changing characteristics of the lateral and longitudinal resistance of a ballast bed, and a three-dimensional model for the ballast bed and sleeper was constructed based on the discrete-element method. The effects of the lateral and longitudinal resistance of the ballast bed, such as gravel ballast grading, sleeper depth, the angle of the shoulder slope, and ballast bed shoulder width, among others, were studied. The results suggest that (1) the lateral and longitudinal resistance of the ballast bed increases with the widening of ballast grading, and within the size distribution limits, the resistance of the ballast bed satisfies the specification; (2) the lateral and longitudinal resistance of ballast bed increases with an increase in the sleeper depth and the resistance of ballast bed satisfies the specifications for sleeper depth greater than 150 mm; (3) the lateral resistance of the ballast bed increases with a decrease in the angle of the shoulder slope, whereas the longitudinal resistance remains unchanged and the resistance of the ballast bed satisfies the specifications for slope gradient of 1:1.75 or less; and finally, (4) the lateral resistance of the ballast bed increases with the widening of the ballast bed shoulder, whereas the longitudinal resistance remains unchanged, and the resistance of ballast bed satisfies the specifications when the shoulder width is greater than 400 mm.

Three-Dimensional Imaging of In Situ Specimens with Low-Dose Electron Tomography to Analyze Protein Conformation

2004 ◽  
Vol 2 (5) ◽  
pp. 561-567 ◽  
Author(s):  
Martina Banyay ◽  
Fredrik Gilstring ◽  
Elenor Hauzenberger ◽  
Lars-Göran Öfverstedt ◽  
Anders B. Eriksson ◽  
...  
Keyword(s):  
Protein Conformation ◽  
Low Dose ◽  
Electron Tomography ◽  
Three Dimensional ◽  
Three Dimensional Imaging

Globule-Globule Interactions during Deformation in Semi-Solid Al-Cu Using Time-Resolved X-Ray Tomography

2012 ◽  
Vol 192-193 ◽  
pp. 179-184
Author(s):  
Kristina Maria Kareh ◽  
Peter D. Lee ◽  
Christopher M. Gourlay
Keyword(s):  
Solid Fraction ◽  
Three Dimensional ◽  
Solid Alloy ◽  
Three Dimensional Imaging ◽  
Time Resolved ◽  
X Ray ◽  
Analysis Techniques ◽  
Solid Deformation ◽  
Fundamental Understanding ◽  
Semi Solid

Optimising semi-solid processing and accurately modelling semi-solid deformation requires a fundamental understanding of the globule-scale mechanisms that cause the macroscopic rheological response. In this work, apparatus and analysis techniques are being developed for the time-resolved, three-dimensional imaging of semi-solid alloy deformation. This paper overviews synchrotron X-ray tomography results on globular Al-15wt%Cu deformed at 0.7 solid fraction using extrusion. The globule-globule interactions in response to load were quantified in terms of the response of individual globules with respect to globule translation, rotation, and deformation. The potential of time-resolved X-ray tomography in the study of semi-solid alloy deformation is then discussed.

scholarly journals In Situ Dispersive EXAFS in Electrocatalysis: The Investigation of the Local Structure of IrOxin Chronoamperometric Conditions as a Case Study

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Elisabetta Achilli ◽  
Alessandro Minguzzi ◽  
Ottavio Lugaresi ◽  
Cristina Locatelli ◽  
Sandra Rondinini ◽  
...  
Keyword(s):  
Fourier Transforms ◽  
Point Of View ◽  
General Point ◽  
Time Resolved ◽  
Electrochemical Processes ◽  
In Situ Experiments ◽  
X Ray Absorption ◽  
Short Range Structure

An in situ study with dispersive EXAFS (Extended X-Ray Absorption Spectroscopy) at the Ir-LIIIedge is performed to characterize Electrodeposited Iridium Oxide Films (EIROF) under chronoamperometric conditions. The technique monitors the local chemical environment and electronic structure of iridium during the oxidation of Ir(III) to Ir(IV) with a time resolution of milliseconds. The study is performed in both acidic and basic media. The Fourier transforms of the time-resolved EXAFS signals clearly show that the short-range structure of Ir is similar to that of rutile-type IrO2and is maintained during the reaction, thus accounting for the flexibility of the structure of the electrode material in accommodating different oxidation states. From a more general point of view, the work demonstrates the capabilities of in situ experiments based on state-of-the-art dispersive EXAFS in clarifying the mechanistic aspects of electrochemical processes.

Three-Dimensional Zinc Mapping inside Aluminum Foams Using Synchrotron X-Ray Microtomography

2007 ◽  
Vol 561-565 ◽  
pp. 1677-1680 ◽  
Author(s):  
Tomomi Ohgaki ◽  
Y. Takami ◽  
Hiroyuki Toda ◽  
Toshiro Kobayashi ◽  
Y. Suzuki ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Cell Wall ◽  
Concentration Distribution ◽  
Three Dimensional ◽  
Aluminum Foams ◽  
X Ray ◽  
Precipitated Phase ◽  
Zn Concentration ◽  
In Situ Experiments

Three-dimensional zinc mapping based on X-ray K-edge scanning has been performed. By microtomographies with energies above and below the K-absorption edges of the elements, the concentration distribution of the elements is evaluated during in-situ experiments, respectively. It is found that the Zn concentration distribution during the heat treatment was changed inside the cell wall of the aluminum foams and it has been homogenized. Also several precipitated phase transformation can be three-dimensionally visualized by the CT-method tuning X-ray energies.

scholarly journals Time-resolved in situ visualization of the structural response of zeolites during catalysis

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Jinback Kang ◽  
Jerome Carnis ◽  
Dongjin Kim ◽  
Myungwoo Chung ◽  
Jaeseung Kim ◽  
...  
Keyword(s):  
Active Sites ◽  
Density Functional ◽  
Three Dimensional ◽  
Structural Response ◽  
Active Regions ◽  
Structural Deformation ◽  
Time Resolved ◽  
X Ray ◽  
Future Design

AbstractZeolites are three-dimensional aluminosilicates having unique properties from the size and connectivity of their sub-nanometer pores, the Si/Al ratio of the anionic framework, and the charge-balancing cations. The inhomogeneous distribution of the cations affects their catalytic performances because it influences the intra-crystalline diffusion rates of the reactants and products. However, the structural deformation regarding inhomogeneous active regions during the catalysis is not yet observed by conventional analytical tools. Here we employ in situ X-ray free electron laser-based time-resolved coherent X-ray diffraction imaging to investigate the internal deformations originating from the inhomogeneous Cu ion distributions in Cu-exchanged ZSM-5 zeolite crystals during the deoxygenation of nitrogen oxides with propene. We show that the interactions between the reactants and the active sites lead to an unusual strain distribution, confirmed by density functional theory simulations. These observations provide insights into the role of structural inhomogeneity in zeolites during catalysis and will assist the future design of zeolites for their applications.

Study of The Hydrothermal Synthesis of Gallium Phosphates Using in Situ Time-Resolved X-Ray Diffraction

1998 ◽  
Vol 547 ◽  
Author(s):  
R.I. Walton ◽  
T. Loiseau ◽  
R.J. Francis ◽  
D. O'Hare ◽  
G. Férey
Keyword(s):  
Kinetic Data ◽  
Three Dimensional ◽  
Diffraction Method ◽  
Effect Of Temperature ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
Time Resolved ◽  
X Ray ◽  
Phosphorus Source

AbstractThe hydrothermal crystallisation (130-180 °C) of three-dimensional open-framework gallium and aluminium oxyfluoro-phosphates with the ULM-3 and ULM-4 structures have been studied in situ for the first time. The in situ energy-dispersive X-ray diffraction method has allowed the formation of the crystalline products to be observed under hydrothermal conditions The integrated areas of the strongest Bragg reflections has allowed quantitative kinetic data to be extracted. The effect of temperature, phosphorus source, templating agent have been investigated. The nature of phosphorus source in the reaction mixture has been found to affect dramatically the course of reaction for certain combinations of amine and temperature. Previously unobserved transient crystalline phases have been seen during the production of ULM-3 gallium phosphates when P2O5 or polyphosphoric acid are used. The formation of these intermediates affects the kinetics of product growth. In the case of the aluminium ULM-3 materials reaction always proceeds via a crystalline intermediate whatever phosphorus source is used. The ULM-4 framework materials are found to always crystallise directly with no evidence for any intermediates. Kinetic data for each system have been modelled using standard solid-state chemistry expressions, and these calculations indicate the reactions to be diffusion controlled.

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