Research on Laser Cladding Co-Based Alloy on the Surface of Vermicular Graphite Cast Iron

To further improve the hardness of the laser cladding layer on the surface of the vermicular graphite cast iron, the structural parameters of the laser cladding Co-base were designed and optimized, and the properties of the clad layer were evaluated using optical microscopy (OM), scanning electron microscopy (SEM), energy spectroscopy (EDS), X-ray diffractometer (XRD), electrochemical workstation, and friction wear equipment. The results show that the average hardness of the molten layer of Ni and Co-based composite cladding layer is 504 HV0.5, which is 0.64 times that of the Co-based cladding layer due to the combined factors of Ni-Cr-Fe equivalent to the dilution of the Ni-based cladding layer to the Co-based cladding layer. Due to the potential difference of the Ni, Cr, and Co elements on the surface of the cladding layer, the self-corrosion potential of the Ni and Co-based composite cladding layer is 1.08 times that of the Co-based cladding layer, and the self-corrosion current density is 0.51 times. Laser cladding Co-based cladding layer has high corrosion resistance. Under the influence of plastic deformation and oxidative wear of the cladding layer of the Ni and Co-based composite cladding layer, the wear amount of the cladding layer of the Ni and Co-based composite cladding layer is less.

Modification of steel surface layer by electroslag surfacing using compounds with high melting point

The authors have studied the effect of alloying on the structure, microhardness and abrasive wear resistance of electroslag surfacing layers on low-alloy structural steel 09G2S. For modification, mixtures of Si3 N4 + FeSi2 + Si powders obtained in the Department of Structural Macrokinetics of the Tomsk Scientific Centre SB RAS by the method of SHS synthesis, as well as powder compositions based on TiC, were used. A molten electrode was made of low-alloy steel St3, on which modifying compositions Si3 N4 + FeSi2 + Si were poured out, in the first case, and modifying compositions Si3 N4 + FeSi2 + Si, located below, in the second case. Metallography and X-ray microanalysis methods were used to determine the structure and to analyze the composition of the deposited layers, heat-affected zone (HAZ) and the base metal, on the basis of which assumptions were made about the nature of the formation of coating properties – hardness and wear resistance. It is shown that the main influence on the wear resistance is exerted by structure of the surfacing metal. There is a positive effect of modifying coatings by alloying materials with the alloys Si3 N4 + FeSi2 + Si + St3 and TiC + St3. In the molten layer, many new crystallization centers are released in the form of dispersed TiC particles. Dispersed TiC particles with a high melting point (3180 °C) are the first to fall out of the melt and not only serve as multiple crystallization centers, but also prevent the growth of austenitic grains, which ensures the formation of dispersed structure. The coatings contain TiC carbide particles, as well as inclusions of other phases. At the same time, an increase in hardness of the deposited layer containing titanium carbide inclusions is observed in direction of the boundary with the base. Wear resistance of the layer increases when a TiC-based coating is formed. The obtained data can be used to create deposited layers on the metal surface with high resistance against abrasive wear.

Forced laser nanostructuring of the surface of alumina-oxide ceramics

The possibility of creating quasiperiodic nanostructures on the surface of articles made of ceramic materials based on -Al2O3 under the action of a laser beam moved by a two-coordinate linear stepping motor (LSM) is shown. It is shown that the cause of the arising non-uniformity of heat release and convective instability of the molten layer are electromagnetic surface waves at the "conductor-insulator" interface, while the "conductor" is the melt layer. The discreteness of the laser beam movement due to LSD makes it possible to create a regular wave-like relief on the melt surface, which plays the role of an input diffraction structure for gen-erating a surface wave of TM polarization.

Physico-Chemical Changes in the KCl-MgCl2/La-FAU Composite Catalyst Induced by Oxidative Dehydrogenation of Ethane

In this research, a binary eutectic composition of KCl and MgCl2 supported over lanthanum exchanged FAU (faujasite) zeolite has been investigated for the oxidative dehydrogenation (ODH) of ethane. The catalyst was prepared by the thermal treatment of La-FAU with a mechanical mixture of alkali chlorides under a flow of helium at 500 °C. The eutectic mixture of alkali chlorides formed at this temperature and a molten layer were spread over the support. Synthesized fresh and spent catalysts were characterized to obtain information about changes in crystallinity, textural properties, phase content, chemical composition, and morphology of the catalyst over the reaction time. The initial conversion of ethane was 80% with ethene as the main product (65% yield). The catalyst deactivation has been demonstrated over time on the stream (TOS). The characterization methods confirmed that the chlorine was being removed from the catalyst. The side products detected by mass spectroscopy, including chlorinated hydrocarbons, have been found as a key pathway of chlorine removal from the catalyst. The exchange of chlorine for oxygen in the catalyst led to a significant decrease in the activity and production of higher hydrocarbons and their oxygenates as side products of the ODH reaction.

Meteors with extreme beginning heights from observations with high-sensitivity super-isocon TV systems

ABSTRACT Meteors with extremely high altitudes are considered. Parameters of seven meteors having anomalous beginning heights recorded with highly sensitive super-Isocon TV systems are presented. One 1993 Perseid meteor, one 2001 sporadic meteor and five meteors from the 2002 Leonid storm had beginning heights in the range 135–145 km. The sporadic meteor is used to demonstrate the methods of data processing and observation precision results. The original TV meteor images, photometric calibration curves and meteor light curve are shown. Light curves are shown for the Leonid shower meteors as well. Based on the sporadic meteor and the 2002 Leonid shower meteor data, mass-loss curves were calculated as functions of height and time: the maximum rates of mass loss were 0.14 and 0.20 g s−1, respectively. Using the classic equation for partially isothermal stone particle heating, the detected beginning heights of most meteors considered (136–135 km) are shown to possibly be related to blowing the molten layer off from a meteoroid surface and most segments of the light curves (below 124 km) show intensive evaporation. For some Leonid meteors, appearing higher than 145–140 km, energy exchange of atmosphere molecules and atoms with the ‘cold’ meteoroid surface can also be assumed. Another possible explanation lies in the low melting temperature of 1500–1600 K for Leonid meteors.

A molten carbonate shell modified perovskite redox catalyst for anaerobic oxidative dehydrogenation of ethane

Acceptor-doped, redox-active perovskite oxides such as La0.8Sr0.2FeO3 (LSF) are active for ethane oxidation to COx but show poor selectivity to ethylene. This article reports molten Li2CO3 as an effective “promoter” to modify LSF for chemical looping–oxidative dehydrogenation (CL-ODH) of ethane. Under the working state, the redox catalyst is composed of a molten Li2CO3 layer covering the solid LSF substrate. The molten layer facilitates the transport of active peroxide (O22−) species formed on LSF while blocking the nonselective sites. Spectroscopy measurements and density functional theory calculations indicate that Fe4+→Fe3+ transition is responsible for the peroxide formation, which results in both exothermic ODH and air reoxidation steps. With >90% ethylene selectivity, up to 59% ethylene yield, and favorable heat of reactions, the core-shell redox catalyst has an excellent potential to be effective for intensified ethane conversion. The mechanistic findings also provide a generalized approach for designing CL-ODH redox catalysts.

The initial condition for the long-term evolution of terrestrial planets as determined by Reactive Freezing of the Basal Magma Ocean

<p>Terrestrial planets evolve through various stages of large-scale melting, or magma oceans, due to the energy release during accretion and differentiation. Any magma ocean is thought to become progressively enriched in FeO and incompatible elements upon freezing due to fractional crystallization. The resulting upwards enrichment of the related cumulate (=crystal) packages drives gravitational overturn(s) of the incipient mantle, and ultimately stabilizes a FeO-enriched molten layer at the core-mantle-boundary (CMB)<sup>1</sup>. Such a molten layer, previously termed basal magma ocean (BMO)<sup>2</sup>, is thought to also fractionally crystallize, but downwards instead of upwards, and over much longer timescales than the surficial magma ocean. This BMO fractional crystallization due to slow planetary cooling analogously implies the stabilization of a thick FeO-enriched layer at the CMB. Such a layer would essentially remain stable forever, as being too dense to be entrained by convection of the overlying mantle. However, at least for Earth, geophysical observations rule out the preservation of such a deep dense global layer. Here, we investigate the consequences of an alternative mechanism for BMO freezing, reactive crystallization, on the initial condition of solid-state mantle convection and long-term planetary evolution.</p><p>Based on scaling relationships, we show that any cumulates, which crystallize from the BMO (e.g., due to initial cooling or reaction) are readily entrained by mantle convection. Once the BMO-mantle boundary is exposed, the BMO reacts with the mantle to form reactive cumulates. Reaction is driven by disequilibrium between mantle rocks and the BMO, a situation that is inevitable independent of BMO initial composition. As reactive cumulates are continuously entrained by mantle convection, the BMO continues to freeze by reactive crystallization. Based on lower-mantle mineral-melt phase equilibria<sup>3</sup>, we calculate the compositional evolution of the BMO, and the chemistry of the BMO cumulate package. We demonstrate that for a wide range of BMO initial compositions, the cumulate package consists of two discrete layers: the first is pure bridgmanite close to the MgSiO<sub>3</sub> end-member; the second is mostly bridgmanite+ferropericlase that is moderately enriched in FeO and incompatibles, i.e. similar in composition to FeO-enriched pyrolite. The mass or thickness of the cumulate package depends on reaction kinetics, but is significantly larger than that of the BMO. The bridgmanitic layer is expected to be entrained by mantle convection due to its intrinsic buoyancy, but resist efficient mixing due to its intrinsic strength, thereby potentially providing an explanation for seismic scatterers/reflectors and ancient geochemical reservoirs<sup>4</sup>. The moderately FeO-enriched layer is expected to stabilize thermochemical piles, providing a candidate origin for the seismically-observed large low shear velocity provinces (LLSVPs)<sup>5</sup>.</p><p>These results have implications for the long-term (thermal) evolution of planets in general. Earth-sized terrestrial (exo-)planets and super-Earths should also initially host a MgSiO<sub>3</sub>-rich layer as well as a moderately FeO-enriched layer. In contrast, small terrestrial planets such as Mars may host a more strongly Fe-rich deep dense global layer as long as no BMO is stabilized in their histories.</p><p>[1] Ballmer+, G-cubed 2017; [2] Labrosse+, Nature 2007; [3] Boukaré+, JGR Solid-Earth 2015; [4] Ballmer+, Nat.Geosci. 2017; [5] Ballmer+, G-cubed 2016.</p><p> </p>

Droplet Formation and Dripping Behavior during the Electroslag Remelting Process with Two Series-Connected Electrodes

The formation and dripping behavior of droplets in the process of the electroslag remelting with two series-connected electrodes (TSCE-ESR) has an important influence on the optimization of power supply parameters and the purity of the electroslag ingot. In this article, through numerical simulation based on the VOF (volume of fluid) model, combined with the transparent experimental device for physical simulation, the mechanism of metal droplet formation and the effect of the filling rate on its droplet behavior were studied. The results showed that the proximity effect, instead of the skin effect, is a major factor influencing droplet formation in TSCE-ESR process. The proximity effect makes the region inside the two electrode tip melt first, and the molten steel converges at the electrode tips to form a droplet source. The process of droplet formation and dropping can be divided into three stages: formation of molten layer, droplet stretching and necking, and detachment. In the stage of droplet stretching and necking, the increase in the contact area between the droplet and the slag and the instantaneous increase of the current provide good thermodynamic and dynamic conditions for the removal of non-metallic inclusions. After the droplet drops into the slag pool, it promotes the flow of slag and improves the heat and mass transfer efficiency of the slag/metal interface. The relatively large filling rate can form smaller and dispersed droplets, which improves the refining effect. At the same time, the increase of the filling rate can improve the input power and the electrode remelting rate.

EXPLOSIVE CLADDING OF ALUMINIUM 5052-STAINLESS STEEL 304

This study addresses the effect of process parameters viz., loading ratio (mass of explosive/mass of flyer plate) and preset angle on dynamic bend angle, collision velocity and flyer plate velocity in dissimilar explosive cladding. In addition, the variation in interfacial microstructure and mechanical strength of aluminium 5052-stainless steel 304 explosive clads is reported. The interface exhibits a characteristic undulating interface with a continuous molten layer formation. The interfacial amplitude increases with the loading ratio and preset angle. Maximum hardness is observed at regions closer to the interface