Operando Spectroscopic Monitoring of Active Species in CO2 Hydrogenation at Elevated Pressure and Temperature: Steady-State versus Transient Analysis

Author(s):  
Alina Gau ◽  
Jannis Hack ◽  
Nobutaka Maeda ◽  
Daniel M. Meier
1985 ◽  
Vol 50 ◽  
Author(s):  
J-E. Andersson ◽  
O. Persson

AbstractThe results from a large number of single-hole packer tests in crystalline rock from three test sites in Sweden have been analysed statistically. Average hydraulic conductivity values for 25 m long test intervals along boreholes with a maximal length of about 700 m are used in this study. A comparison between steady state and transient analysis of the same test data has been performed.The mean vaule of the hydraulic conductivity determined from steady state analysis was found to be about two to three times higher compared to transient analysis. However, in some cases the steady state analysis resulted in 10 to 20 times higher values compared to the transient analysis. Such divergence between the two analysis methods may be caused by deviations from the assumed flow pattern, borehole skin effects and influence of hydraulic boundaries.


2021 ◽  
pp. 1-23
Author(s):  
Daniel O'Reilly ◽  
Manouchehr Haghighi ◽  
Mohammad Sayyafzadeh ◽  
Matthew Flett

Summary An approach to the analysis of production data from waterflooded oil fields is proposed in this paper. The method builds on the established techniques of rate-transient analysis (RTA) and extends the analysis period to include the transient- and steady-state effects caused by a water-injection well. This includes the initial rate transient during primary production, the depletion period of boundary-dominated flow (BDF), a transient period after injection starts and diffuses across the reservoir, and the steady-state production that follows. RTA will be applied to immiscible displacement using a graph that can be used to ascertain reservoir properties and evaluate performance aspects of the waterflood. The developed solutions can also be used for accurate and rapid forecasting of all production transience and boundary-dominated behavior at all stages of field life. Rigorous solutions are derived for the transient unit mobility displacement of a reservoir fluid, and for both constant-rate-injection and constant-pressure-injection after a period of reservoir depletion. A simple treatment of two-phase flow is given to extend this to the water/oil-displacement problem. The solutions are analytical and are validated using reservoir simulation and applied to field cases. Individual wells or total fields can be studied with this technique; several examples of both will be given. Practical cases are given for use of the new theory. The equations can be applied to production-data interpretation, production forecasting, injection-water allocation, and for the diagnosis of waterflood-performanceproblems. Correction Note: The y-axis of Fig. 8d was corrected to "Dimensionless Decline Rate Integral, qDdi". No other content was changed.


Author(s):  
Susana Puntarulo

SynopsisBoth respiration and generation by soybean embryonic axes showed a sharp increase upon germination, leading to a significant increase in the steady-state concentration of and H2O2 after 6 h of imbibition. An assay was developed to assess in vivo generation of reactive oxygen species, based upon DCFH-DA oxidation. Fluorescence of the external medium was dependent on reaction time and axes number and was inhibited by catalase.α-Tocopherol content declined significantly after 24 h of incubation, as compared to the content at the onset of germination. Incubation in the presence of redox cycling agent paraquat (4 mM) for 24 h increased α-tocopherol content to 1.9±0.2 nmol per axis from 1.0 ± 0.1 nmol per axis in the absence of paraquat. Supplementation of the incubation medium with 500 μM Fe-EDTA increased α-tocopherol content to 1.8±0.1 nmol/axis and DCFH-DA oxidation by two-fold.The data presented here showed that active metabolism at the onset of germination increased steady-state concentration of oxygen active species and suggest that cellular content of α-tocopherol is physiologically adjusted as a response to conditions of oxidative stress.


1996 ◽  
Vol 40 (01) ◽  
pp. 46-59 ◽  
Author(s):  
K. J. Spyrou

The dynamic stability of ships encountering large regular waves from astern is analyzed, with focus on delineating the specific conditions leading to the uncontrolled turn identified as broaching. The problem's formulation takes into account motions of the actively steered or controls-fixed vessel in surge-sway-yaw-roll with consideration of Froude-Krylov and diffraction wave excitation. Dynamical analysis of surf-riding is carried out for the general case of quartering waves, exploring the route periodic motions—surf riding, loss of stationary stability, turn, capsize. Steady-state and transient analysis is carried out in the system's multidimensional state-space in order to identify all existing limit sets and locate attracting domains. Broaching from periodic motions is also a part of the investigation.


2019 ◽  
Vol 72 (3) ◽  
pp. 305-339 ◽  
Author(s):  
M Garau ◽  
M J Nieves ◽  
I S Jones

Summary We consider both analytical and numerical studies of a steady-state fracture process inside a discrete mass-beam structure, composed of periodically placed masses connected by Euler–Bernoulli beams. A fault inside the structure is assumed to propagate with a constant speed and this occurs as a result of the action of a remote sinusoidal, mechanical load. The established regime of fracture corresponds to the case of an alternating generalised strain regime. The model is reduced to a Wiener–Hopf equation and its solution is presented. We determine the minimum feeding wave energy required for the steady-state fracture process to occur. In addition, we identify the dynamic features of the structure during the steady-state fracture regime. A transient analysis of this problem is also presented, where the existence of steady-state fracture regimes, revealed by the analytical model, are verified and the associated transient features of this process are discussed.


2004 ◽  
Vol 120 ◽  
pp. 239-247
Author(s):  
T. Belmonte ◽  
C. Jaoul ◽  
H. Michel

In this paper, the state of the art in the modelling of nitriding and nitrocarburising using late post-discharge processes is described. In a first part, interstitial diffusion in ternary system is treated. The problem of the diffusion in two-phase domains is evoked. The chemical pathways in N2-H2 and N2-CH4 post-discharges creating active species are next presented to try to identify the precursors responsible for the transport of nitrogen and carbon to the surface of the solid. Finally, attention is paid to the coupling between the gas phase and the solid. Two different approaches are proposed, either by considering a steady state or a transient gas flow. The latter requires to introduce a sequence of surface phenomena (adsorption, surface diffusion, recombination, dissolution…) that provides a rigorous way to couple processes in the gas phase and in the solid.


2012 ◽  
Vol 37 ◽  
pp. 154-164 ◽  
Author(s):  
Aldo Canova ◽  
Fabio Freschi ◽  
Luca Giaccone ◽  
Alessandra Guerrisi

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