Bis-N-Heterocyclic Carbene Complexes of Coinage Metals Containing Four Naphthalimide Units: A Structure–Emission Properties Relationship Study

A Me3Si-protected P7 cage reacts with N-heterocyclic-carbene complexes of coinage metals to yield a mononuclear Cu(i) complex featuring a Cu(η4-P7) core and a trinuclear Au(i) complex with linearly coordinated metal ions attached to the P7 cluster.

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Insights into molecular packing effects on the emission properties of fluorenone-based molecules in the aggregate state

Journal of Materials Chemistry C ◽

10.1039/d1tc03459f ◽

2021 ◽

Vol 9 (39) ◽

pp. 13687-13696

Author(s):

Peigen Yao ◽

Yixuan Wang ◽

Weiguo Qiao ◽

Xianglang Sun ◽

Haiyan Peng ◽

...

Keyword(s):

Three Dimensional ◽

Molecular Packing ◽

Molecular Motions ◽

Aggregate State ◽

Structure Packing ◽

Emission Properties ◽

Property Relationship ◽

Relationship Study ◽

Packing Effects ◽

Packing Property

A structure–packing–property relationship study of fluorenone-based molecules indicates that the formation of a three-dimensional molecular packing network is an effective way to suppress molecular motions to achieve AIE properties.

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Emission properties and Cu(i)–Cu(i) interaction in 2-coordinate dicopper(i)-bis(N-heterocyclic)carbene complexes

Dalton Transactions ◽

10.1039/c6dt01239f ◽

2016 ◽

Vol 45 (30) ◽

pp. 12127-12136 ◽

Cited By ~ 23

Author(s):

Michihiro Nishikawa ◽

Taichi Sano ◽

Masaya Washimi ◽

Koichiro Takao ◽

Taro Tsubomura

Keyword(s):

Photophysical Properties ◽

Carbene Ligands ◽

Carbene Complexes ◽

Dinuclear Copper ◽

Emission Properties ◽

Solid States

The 8-shaped dinuclear copper(i) complexes bearing two N-heterocyclic carbene ligands exhibit strong photoluminescence both in solution and the solid states. Copper(i)–copper(i) interactions play a key role in the photophysical properties.

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Groups 1 and 11: The Alkali and Coinage Metals

Organometallic Chemistry ◽

10.1039/9781847558503-00001 ◽

2008 ◽

pp. 1-21 ◽

Cited By ~ 1

Keyword(s):

Coinage Metals

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Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

Inorganic Chemistry Frontiers ◽

10.1039/c9qi01278h ◽

2020 ◽

Vol 7 (3) ◽

pp. 786-794 ◽

Cited By ~ 3

Author(s):

Jingqi Han ◽

Kin-Man Tang ◽

Shun-Cheung Cheng ◽

Chi-On Ng ◽

Yuen-Kiu Chun ◽

...

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Carbene Complexes ◽

New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

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