Synthesis and Properties of V-Shaped Xanthene Dyes with Tunable and Predictable Absorption and Emission Wavelengths

Author(s):  
Akari Yamagami ◽  
Kotaro Kiyotaki ◽  
Sae Wakabayashi ◽  
Naoki Egami ◽  
Kenichi Kawano ◽  
...  
1965 ◽  
Vol 5 ◽  
pp. 120-130
Author(s):  
T. S. Galkina

It is necessary to have quantitative estimates of the intensity of lines (both absorption and emission) to obtain the physical parameters of the atmosphere of components.Some years ago at the Crimean observatory we began the spectroscopic investigation of close binary systems of the early spectral type with components WR, Of, O, B to try and obtain more quantitative information from the study of the spectra of the components.


1979 ◽  
Vol 46 ◽  
pp. 386-408 ◽  
Author(s):  
G. V. Coyne ◽  
I. S. McLean

AbstractIn recent years the wavelength, dependence of the polarization in a number of Mira variables, semi-regular variables and red supergiants has been measured with resolutions between 0.3 and 300 A over the range 3300 to 11000 A. Variations are seen across molecular absorption bands, especially TiO bands, and across atomic absorption and emission lines, especially the Balmer lines. In most cases one can ignore or it is possible to eliminate the effects due to interstellar polarization, so that one can study the polarization mechanisms operating in the stellar atmosphere and environment. The stars Omicron Ceti. (Mira), V CVn (semi-regular variable) and Mu Cephei (M2 la), in addition to other stars similar to them, will be discussed in some detail.Models to explain the observed polarization consider that the continuum flux is polarized either by electron, molecular and/or grain scattering or by temperature variations and/or geometrical asymmetries over the stellar photosphere. This polarized radiation is affected by atomic and molecular absorption and emission processes at various geometric depths in the stellar atmosphere and envelope. High resolution spectropolarimetry promises, therefore, to be a power-rul tool for studying stratification effects in these stars.


2020 ◽  
Vol 26 (31) ◽  
pp. 3828-3833 ◽  
Author(s):  
Tuula Peñate-Medina ◽  
Eike Kraas ◽  
Kunliang Luo ◽  
Jana Humbert ◽  
Hanwen Zhu ◽  
...  

Background: Nanoparticle imaging and tracking the release of the loaded material from the nanoparticle system have attracted significant attention in recent years. If the release of the loaded molecules could be monitored reliably in vivo, it would speed up the development of drug delivery systems remarkably. Methods: Here, we test a system that uses indocyanine green (ICG) as a fluorescent agent for studying release kinetics in vitro and in vivo from the lipid iron nanoparticle delivery system. The ICG spectral properties like its concentration dependence, sensitivity and the fluctuation of the absorption and emission wavelengths can be utilized for gathering information about the change of the ICG surrounding. Results: We have found that the absorption, fluorescence, and photoacoustic spectra of ICG in lipid iron nanoparticles differ from the spectra of ICG in pure water and plasma. We followed the ICG containing liposomal nanoparticle uptake into squamous carcinoma cells (SCC) by fluorescence microscopy and the in vivo uptake into SCC tumors in an orthotopic xenograft nude mouse model under a surgical microscope. Conclusion: Absorption and emission properties of ICG in the different solvent environment, like in plasma and human serum albumin, differ from those in aqueous solution. Photoacoustic spectral imaging confirmed a peak shift towards longer wavelengths and an intensity increase of ICG when bound to the lipids. The SCC cells showed that the ICG containing liposomes bind to the cell surface but are not internalized in the SCC-9 cells after 60 minutes of incubation. We also showed here that ICG containing liposomal nanoparticles can be traced under a surgical camera in vivo in orthotopic SCC xenografts in mice.


ACS Photonics ◽  
2021 ◽  
Author(s):  
Hyemin Bae ◽  
Suk Hyun Kim ◽  
Seungmin Lee ◽  
Minji Noh ◽  
Ouri Karni ◽  
...  

Compounds ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 29-40
Author(s):  
Sutapa Sahu ◽  
Yeasin Sikdar ◽  
Riya Bag ◽  
Dilip K. Maiti ◽  
José P. Cerón-Carrasco ◽  
...  

This work presents the development of a quinoxaline and rhodamine conjugate system that acts as a colorimetric chemosensor for hydrogen sulfate (HSO4−) ions in methanol media. This sensor has been characterized both theoretically and experimentally. The detection limits for HSO4− are small as 0.71 µM and 3.8 µM for the absorption and emission experiments, respectively. The effectiveness of the probe in recognizing HSO4− both in gel and solid phase is evaluated as well. Thus, this works presents a simple strategy to detect the environmental HSO4− pollutant event at tiny concentrations.


2021 ◽  
Vol 23 (12) ◽  
pp. 7480-7494
Author(s):  
Sarah Karbalaei Khani ◽  
Bastian Geissler ◽  
Elric Engelage ◽  
Patrick Nuernberger ◽  
Christof Hättig

Spectroscopic signatures of ion-pairing are identified by variation of counterion and substitution and comparison with theory.


2020 ◽  
Vol 3 (1) ◽  
pp. 106
Author(s):  
Vanessa S. D. Gomes ◽  
João C. C. Ferreira ◽  
Renato E. F. Boto ◽  
Paulo Almeida ◽  
Maria João M. F. Sousa ◽  
...  

Two squarylium cyanine dyes were synthesized and characterized by the usual analytical techniques, including Vis-NIR absorption and emission spectroscopy. Their antifungal activity was evaluated, through the obtention of minimum inhibitory concentration (MIC) values, using yeasts of the species Saccharomyces cerevisiae as a biological model.


2019 ◽  
Vol 21 (18) ◽  
pp. 9246-9254 ◽  
Author(s):  
G. V. Baryshnikov ◽  
R. R. Valiev ◽  
V. N. Cherepanov ◽  
N. N. Karaush-Karmazin ◽  
V. A. Minaeva ◽  
...  

The electronic structure, absorption and emission spectra, aromaticity and photophysical behavior of the recently synthesized tetrasilatetrathia[8]circulene and tetragermatetrathia[8]circulene compounds have been studied computationally.


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