Anchoring Ag(I) into Nitro-Functionalized Metal–Organic Frameworks: Effectively Catalyzing Cycloaddition of CO2 with Propargylic Alcohols under Mild Conditions
A facile one-pot precipitation was employed to prepare a petal-shaped hybrid in mild conditions. The hybrid is composed of urate oxidase (UOx) encapsulated into zeolite-like metal-organic frameworks (MOF) with doping...
Highly ultrafine defective Pt nanoparticles (NPs) encapsulated in the mesopores of MIL-101 (Pt(Co)@MIL-101) were achieved for the first time through a chemical dealloying approach. The obtained material could provide more active sites to contact reactants and showed superior catalytic activity towards the hydrogenation of nitroarenes under mild conditions.
The amount of Fe2+ in the iron-containing MOFs can be controlled by using varied ratios of n(FeCl3)/n(FeCl2) in the feed. The morphology of the crystal transforms from a small irregular shape to a large triangular prism.
Results show that the incorporation of Mn can significantly promote the catalytic process, Co exhibits no obviously favorable behavior, and Ni presents an apparently inhibitory impact.