Fabrication of Hydrazone-Linked Covalent Organic Frameworks Using Alkyl Amine as Building Block for High Adsorption Capacity of Metal Ions

2019 ◽  
Vol 11 (12) ◽  
pp. 11706-11714 ◽  
Author(s):  
Ya Li ◽  
Chang Wang ◽  
Shujuan Ma ◽  
Haiyang Zhang ◽  
Junjie Ou ◽  
...  
2020 ◽  
Vol 8 (6) ◽  
pp. 3438-3449 ◽  
Author(s):  
Facui Yang ◽  
Zhigang Yan ◽  
Jian Zhao ◽  
Shuting Miao ◽  
Dong Wang ◽  
...  

A protein-based bilayer membrane can selectively sequester precious metal ions from leaching solutions of ores and WEEE, and exhibits an adsorption capacity for gold of 1034.4 mg g−1.


Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 156 ◽  
Author(s):  
Xiaoye Zhang ◽  
Yingxi Qin ◽  
Guifang Zhang ◽  
Yiping Zhao ◽  
Chao Lv ◽  
...  

In this work, three kinds of hyperbranched polyamidoamine-palygorskite (PAMAM-Pal) were designed and synthesized by grafting the first generation polyamidoamine (G1.0 PAMAM), G2.0 PAMAM and G3.0 PAMAM onto Pal surfaces, respectively. Then, these PAMAM-Pals were used as additives to prepare polyvinylidene fluoride (PVDF)/hyperbranched polyamidoamine-palygorskite bicomponent composite membranes. The structures of the composite membranes were characterized by Fourier transform infrared spectroscopy (FTIR), thermo gravimetric analysis (TEM), X-ray photoelectron spectroscopy (XPS), field-emission scanning electronmicroscopy (SEM), atomic force microscope (AFM) and Thermogravimetric analysis (TGA). The adsorption properties of composite membranes to heavy metal ions was studied, and the results found that the maximum adsorption capacities for Cu(II), Ni(II) and Cd(II) could reach 155.19 mg/g, 124.28 mg/g and 125.55 mg/g, respectively, for the PVDF/G3.0 PAMAM-Pal membrane, while only 23.70 mg/g, 17.74 mg/g and 14.87 mg/g could be obtained for unmodified membranes in the same conditions. The high adsorption capacity can be ascribed to the large number of amine-terminated groups, amide groups and carbonyl groups of the composite membrane. The above results indicated that the prepared composite membrane has a high adsorption capacity for heavy metal ions removal in water treatment.


2012 ◽  
Vol 487 ◽  
pp. 11-14
Author(s):  
Zong Hua Qin ◽  
Han Ning Cai ◽  
Ren Qiang Li

After Sepharose 4B polymer beads were activated by using epichlorohydrin, glycine was binded with them to prepare an immobilized carboxyl group ion exchange adsorbent. The coupling rate was that 18.3 mg Gly could be fixed by 1 g of wet Sepharose 4B beads. At pH 9, this adsorbent showed power adsorption to metal ions with Ca2+16.49 mg,Mg2+6.92 mg,Fe2+11.06 mg,Fe3+4.98 mg and Mn2+11.84 mg were respectively adsorbed by 20 g of wet Sepharose 4B beads during saturated adsorption. Moreover, this absorbent possessed the properties with good stability, regeneration easily and low cost.


2018 ◽  
Vol 1 (9) ◽  
pp. 4756-4761 ◽  
Author(s):  
Yang Li ◽  
Weiben Chen ◽  
Wenjing Hao ◽  
Yusen Li ◽  
Long Chen

2020 ◽  
Vol 8 (25) ◽  
pp. 12657-12664 ◽  
Author(s):  
Hong-Ju Da ◽  
Cheng-Xiong Yang ◽  
Hai-Long Qian ◽  
Xiu-Ping Yan

A knot-linker planarity control strategy was developed to construct highly crystalline cationic covalent organic frameworks with C3-symmetric guanidine units for fast removal of 2,4-dichlorophenol with high adsorption capacity.


2017 ◽  
Vol 5 (8) ◽  
pp. 4058-4066 ◽  
Author(s):  
Jian Zhang ◽  
Jie Han ◽  
Minggui Wang ◽  
Rong Guo

Multifunctional magnetic adsorbents of Fe3O4/PANI/MnO2 core–shell hybrids have been developed through a facile and economic solution route, which show high adsorption capacity toward heavy metal ions.


1999 ◽  
Vol 40 (7) ◽  
pp. 109-116 ◽  
Author(s):  
M. H. Ansari ◽  
A. M. Deshkar ◽  
P. S. Kelkar ◽  
D. M. Dharmadhikari ◽  
M. Z. Hasan ◽  
...  

Steamed Hoof Powder (SHP), size < 53μ, was observed to have high adsorption capacity for Hg(II) with >95% removal from a solution containing 100 mg/L of Hg(II) with only 0.1% (W/V) concentration of SHP. The SHP has good settling properties and gives clear and odour free effluent. Studies indicate that pH values between 2 and 10 have no effect on the adsorption of Hg(II) on SHP. Light metal ions like Na+, K+, Ca2+ and Mg2+ up to concentrations of 500 mg/L and heavy metals like Cu2+, Zn2+, Cd2+, Co2+, Pb2+, Ni2+, Mn2+, Cr3+, Cr6+, Fe2+ and Fe3+ up to concentrations of 100 mg/L do not interfere with the adsorption process. Anions like sulphate, acetate and phosphate up to concentrations of 200 mg/L do not interfere. Chloride interferes in the adsorption process when Hg(II) concentration is above 9.7 mg/L. The adsorption equilibrium was established within two hours. Studies indicate that adsorption occurs on the surface sites of the adsorbent.


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