S-Vinyl Sulfide-Derived Pendant-Type Sulfone/Phenoxazine-Based Polymers Exhibiting Thermally Activated Delayed Fluorescence: Synthesis and Photophysical Property Characterization

2020 ◽  
Vol 2 (8) ◽  
pp. 3310-3318
Author(s):  
Jun Kosai ◽  
Yuki Masuda ◽  
Yuki Chikayasu ◽  
Yoshihito Takahashi ◽  
Hisahiro Sasabe ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Photophysical Property ◽  
Vinyl Sulfide ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Property Characterization

Solvent Dependence of Structural Dynamics and Spin-flip Processes in 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (ortho-3CzBN)

2020 ◽  
Author(s):  
Masaki Saigo ◽  
Kiyoshi Miyata ◽  
Hajime Nakanotani ◽  
Chihaya Adachi ◽  
Ken Onda
Keyword(s):  
Dft Calculations ◽  
Excited States ◽  
Structural Changes ◽  
Photophysical Properties ◽  
Delayed Fluorescence ◽  
Time Resolved ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Solvent Dependence ◽  
Acetonitrile Solutions

We have investigated the solvent-dependence of structural changes along with intersystem crossing of a thermally activated delayed fluorescence (TADF) molecule, 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (o-3CzBN), in toluene, tetrahydrofuran, and acetonitrile solutions using time-resolved infrared (TR-IR) spectroscopy and DFT calculations. We found that the geometries of the S1 and T1 states are very similar in all solvents though the photophysical properties mostly depend on the solvent. In addition, the time-dependent DFT calculations based on these geometries suggested that the thermally activated delayed fluorescence process of o-3CzBN is governed more by the higher-lying excited states than by the structural changes in the excited states.<br>

scholarly journals Thermally activated delayed fluorescence and phosphorescence quenching in iminophosphonamide copper and zinc complexes

2021 ◽  
Author(s):  
Peter Werner Roesky ◽  
Bhupendra Goswami ◽  
Thomas J. Feuerstein ◽  
Ravi Yadav ◽  
Sergei Lebedkin ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Zinc Complexes ◽  
Thermally Activated Delayed Fluorescence ◽  
Phosphorescence Quenching ◽  
Thermally Activated ◽  
Copper And Zinc ◽  
Fluorescence And Phosphorescence

New hole transport styrene polymers bearing highly π-extended conjugated side-chain moieties for high-performance solution-processable thermally activated delayed fluorescence OLEDs

2021 ◽  
Vol 12 (11) ◽  
pp. 1692-1699
Author(s):  
Ji Hye Lee ◽  
Jinhyo Hwang ◽  
Chai Won Kim ◽  
Amit Kumar Harit ◽  
Han Young Woo ◽  
...  
Keyword(s):  
High Performance ◽  
High Efficiency ◽  
Delayed Fluorescence ◽  
Hole Transport ◽  
Side Chain ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Turn On ◽  
Solution Processable

New polystyrene-based polymers with high π-extended hole transport pendants were synthesized to obtain a low turn-on voltage and high efficiency in solution-processed green TADF-OLEDs.

Small-molecule based thermally activated delayed fluorescence materials with dual-emission characteristics

2021 ◽  
Author(s):  
Xuping Li ◽  
Shen Shen ◽  
Chenchen Zhang ◽  
Miaoqing Liu ◽  
Jianjun Lu ◽  
...  
Keyword(s):  
Small Molecule ◽  
Delayed Fluorescence ◽  
Emission Characteristics ◽  
Dual Emission ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

scholarly journals Molecular design of efficient yellow- to red-emissive alkynylgold(iii) complexes for the realization of thermally activated delayed fluorescence (TADF) and their applications in solution-processed organic light-emitting devices

2021 ◽  
Author(s):  
Cathay Chai Au-Yeung ◽  
Lok-Kwan Li ◽  
Man-Chung Tang ◽  
Shiu-Lun Lai ◽  
Wai-Lung Cheung ◽  
...  
Keyword(s):  
Molecular Design ◽  
Delayed Fluorescence ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Thermally Activated ◽  
New Class ◽  
Organic Light ◽  
Tunable Emission

We report the design of a new class of fused heterocyclic alkynyl ligand-containing gold(iii) complexes, which shows tunable emission colors spanning yellow to red region and exhibits thermally activated delayed fluorescence (TADF) properties.

Novel thermally activated delayed fluorescence materials by high-throughput virtual screening: going beyond donor–acceptor design

2021 ◽  
Vol 9 (9) ◽  
pp. 3324-3333 ◽  
Author(s):  
Ke Zhao ◽  
Ömer H. Omar ◽  
Tahereh Nematiaram ◽  
Daniele Padula ◽  
Alessandro Troisi
Keyword(s):  
Virtual Screening ◽  
Quantum Chemistry ◽  
High Throughput ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Quantum Chemistry Calculations ◽  
Donor Acceptor ◽  
Molecular Semiconductors ◽  
High Throughput Virtual Screening

125 potential TADF candidates are identified through quantum chemistry calculations of 700 molecules derived from a database of 40 000 molecular semiconductors. Most of them are new and some do not belong to the class of donor–acceptor molecules.

Why Triage the Materials with Low Luminescence Quantum Efficiency: The Use of 35Cbz4BzCN as a Universal Host for Organic Light Emitting Diode through Effective Triplet Energy Transfer

2021 ◽  
Author(s):  
Yi-Mei Huang ◽  
Tse-Ying Chen ◽  
Deng-Gao Chen ◽  
Hsuan-Chi Liang ◽  
Cheng-Ham Wu ◽  
...  
Keyword(s):  
Light Emitting Diode ◽  
Delayed Fluorescence ◽  
Triplet Energy ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Organic Light Emitting Diode ◽  
Thermally Activated ◽  
Triplet Energy Transfer ◽  
Triplet Lifetime ◽  
Triplet Excitons

35Cbz4BzCN, a novel universal host with long triplet lifetime, has been developed. The triplet excitons in 35Cbz4BzCN can be effectively harvested by phosphorescence and thermally activated delayed fluorescence emitters. In...

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