[6,6]-Phenyl-C61-Butyric Acid Methyl Ester/Cerium Oxide Bilayer Structure as Efficient and Stable Electron Transport Layer for Inverted Perovskite Solar Cells

ACS Nano ◽  
2018 ◽  
Vol 12 (3) ◽  
pp. 2403-2414 ◽  
Author(s):  
Rui Fang ◽  
Shaohang Wu ◽  
Weitao Chen ◽  
Zonghao Liu ◽  
Shasha Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Methyl Ester ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Bilayer Structure ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester

Enhanced efficiency and air-stability of NiOX-based perovskite solar cells via PCBM electron transport layer modification with Triton X-100

Nanoscale ◽  
2017 ◽  
Vol 9 (42) ◽  
pp. 16249-16255 ◽  
Author(s):  
Kisu Lee ◽  
Jaehoon Ryu ◽  
Haejun Yu ◽  
Juyoung Yun ◽  
Jungsup Lee ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Photovoltaic Performance ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester ◽  
Triton X

In this work, a phenyl-C61-butyric acid methyl ester (PCBM) electron transport layer was modified with Triton X-100, and this improved the photovoltaic performance and air-stability of perovskite solar cells.

scholarly journals Phenyl-C61-Butyric Acid Methyl Ester Hybrid Solution for Efficient CH3NH3PbI3 Perovskite Solar Cells

2019 ◽  
Vol 11 (14) ◽  
pp. 3867
Author(s):  
MiJoung Kim ◽  
MoonHoe Kim ◽  
JungSeock Oh ◽  
NamHee Kwon ◽  
Yoonmook Kang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Methyl Ester ◽  
Butyric Acid ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Absorber Layer ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester

Organic–inorganic halide perovskite solar cells (PSCs) have excellent chemical, electronic, and optical properties, making them attractive next-generation thin-film solar cells. Typical PSCs were fabricated with a perovskite absorber layer between the TiO2 electron-transport layer (ETL) and the 2,2′,7,7′-tetrakis-(N,N-di-4-methoxyphenylamino)-9,9′-spirobifluorene (Spiro-OMeTAD) hole-transport layer (HTL). We examined the influence of phenyl-C61-butyric acid methyl ester (PCBM) on the PSC device. PSCs using the PCBM layer as an ETL were investigated, and the absorber layer was coated by dissolving PCBM in a methyl ammonium lead iodide (MAPbI3) precursor solution to examine the changes at the perovskite interface and inside the perovskite absorber layer. The PSCs fabricated by adding a small amount of PCBM to the MAPbI3 solution exhibited a significantly higher maximum efficiency of 16.55% than conventional PSCs (14.34%). Fabricating the PCBM ETL and PCBM-MAPbI3 hybrid solid is expected to be an efficient route for improving the photovoltaic performance.

scholarly journals Improving the Performances of Perovskite Solar Cells via Modification of Electron Transport Layer

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 147 ◽  
Author(s):  
Mao Jiang ◽  
Qiaoli Niu ◽  
Xiao Tang ◽  
Heyi Zhang ◽  
Haowen Xu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Short Circuit ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Short Circuit Current ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Simple Method ◽  
Film Forming

The commonly used electron transport material (6,6)-phenyl-C61 butyric acid methyl ester (PCBM) for perovskite solar cells (PSC) with inverted planar structures suffers from properties such as poor film-forming. In this manuscript, we demonstrate a simple method to improve the film-forming properties of PCBM by doping PCBM with poly(9,9-dioctylfluorene-co-benzothiadiazole) (F8BT) as the electron transport layer (ETL), which effectively enhances the performance of CH3NH3PbI3 based solar cells. With 5 wt % F8BT in PCBM, the short circuit current (JSC) and fill factor (FF) of PSC both significantly increased from 17.21 ± 0.15 mA·cm−2 and 71.1 ± 0.07% to 19.28 ± 0.22 mA·cm−2 and 74.7 ± 0.21%, respectively, which led to a power conversion efficiency (PCE) improvement from 12.6 ± 0.24% to 15 ± 0.26%. The morphology investigation suggested that doping with F8BT facilitated the formation of a smooth and uniform ETL, which was favorable for the separation of electron-hole pairs, and therefore, an improved performance of PSC.

Morphology fixing agent for [6,6]-phenyl C61-butyric acid methyl ester (PC60BM) in planar-type perovskite solar cells for enhanced stability

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 51513-51519 ◽  
Author(s):  
Sunyong Ahn ◽  
Woongsik Jang ◽  
Jong Hyeok Park ◽  
Dong Hwan Wang
Keyword(s):  
Solar Cells ◽  
Methyl Ester ◽  
Titanium Oxide ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester ◽  
Device Operation ◽  
Enhanced Stability

Enhanced stability of planar-type perovskite solar cells (PSCs) has been demonstrated by applying titanium oxide (TiOx) interlayer which acts as a morphological fixing agent for preseving delamication of PC60BM with long-term device operation.

A solution-processed n-doped fullerene cathode interfacial layer for efficient and stable large-area perovskite solar cells

2016 ◽  
Vol 4 (2) ◽  
pp. 640-648 ◽  
Author(s):  
Chih-Yu Chang ◽  
Wen-Kuan Huang ◽  
Yu-Chia Chang ◽  
Kuan-Ting Lee ◽  
Chin-Ti Chen
Keyword(s):  
Solar Cells ◽  
Methyl Ester ◽  
Interfacial Layer ◽  
Cetyltrimethylammonium Bromide ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Large Area ◽  
Solution Processed ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester

A facile and effective approach to enhance the performance and stability of perovskite solar cells is proposed by using a solution-processed cetyltrimethylammonium bromide (CTAB)-doped [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM) film as a cathode interfacial layer.

scholarly journals Investigation of the Effects of Various Organic Solvents on the PCBM Electron Transport Layer of Perovskite Solar Cells

Coatings ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 237
Author(s):  
Chih-Hung Tsai ◽  
Chia-Ming Lin ◽  
Cheng-Hao Kuei
Keyword(s):  
Surface Roughness ◽  
Solar Cells ◽  
Electron Transport ◽  
Organic Solvents ◽  
Electrochemical Impedance ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
X Ray

In this study, four organic solvents including 1,2-dichlorobenzene (DCB), chlorobenzene (CB), methylbenzene (MB), and chloroform (CF) were used as solvents in the [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) electron transport layer (ETL) of perovskite solar cells (PSCs). This study observed the effects of various solvents on the surface morphology of the ETL by using an optical microscope (OM) and scanning electron microscope (SEM). The surface roughness, crystal structure, and surface element bonding of the ETL were observed using an atomic force microscope (AFM), X-ray diffractometer (XRD), and X-ray photoelectron spectroscope (XPS), respectively. The absorption spectrum of the perovskite layer was explored using an ultraviolet-visible (UV-Vis) spectrometer. The characteristics of the PSC device were analyzed in terms of its current density–voltage (J–V) curve, external quantum efficiency (EQE), and electrochemical impedance spectroscopy (EIS) measurements. The results showed that DCB is a solvent with a high boiling point, low vapor pressure, and high dielectric constant, and using DCB as the solvent for ETL, the uniformity, coverage, and surface roughness of the ETL showed better properties. The power conversion efficiency of the PSC in which DCB was used as the solvent achieved a value of 11.07%, which was higher than that of the PSCs in which other solvents were used.

scholarly journals Numerical simulation of perovskite solar cell with different material as electron transport layer using SCAPS-1D Software

2021 ◽  
Vol 24 (3) ◽  
pp. 341-347
Author(s):  
K. Bhavsar ◽  
◽  
P.B. Lapsiwala ◽  
Keyword(s):  
Numerical Simulation ◽  
Solar Cells ◽  
Solar Cell ◽  
Electron Transport ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Perovskite Solar Cell ◽  
Hole Transport ◽  
Transport Layer ◽  
Electron Transport Layer

Perovskite solar cells have become a hot topic in the solar energy device area due to high efficiency and low cost photovoltaic technology. However, their function is limited by expensive hole transport material (HTM) and high temperature process electron transport material (ETM) layer is common device structure. Numerical simulation is a crucial technique in deeply understanding the operational mechanisms of solar cells and structure optimization for different devices. In this paper, device modelling for different perovskite solar cell has been performed for different ETM layer, namely: TiO2, ZnO, SnO2, PCBM (phenyl-C61-butyric acid methyl ester), CdZnS, C60, IGZO (indium gallium zinc oxide), WS2 and CdS and effect of band gap upon the power conversion efficiency of device as well as effect of absorber thickness have been examined. The SCAPS 1D (Solar Cell Capacitance Simulator) has been a tool used for numerical simulation of these devices.

scholarly journals Effect of Absorber Layer Thickness on the Performance of Bismuth-Based Perovskite Solar Cells

2021 ◽  
Vol 55 (4) ◽  
pp. 354
Author(s):  
U.C. Obi ◽  
D.M. Sanni ◽  
A. Bello
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Layer Thickness ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Hole Transport ◽  
Absorber Layer ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Bismuth Perovskite

Theoretical study of methyl-ammonium bismuth halide perovskite solar cells, (CH3NH3)3Bi2I9, was carried out using a one-dimensional Solar Cell Capacitance Simulator (SCAPS-1D) software. The performance of the tested device architectures largely depends on the thickness of the absorbing layer, with the combination of electron transport, and hole transport layers. Thus, the bismuth perovskite absorber layer was optimized by varying the thickness and also, the thicknesses of the different charge-transport materials such as Spiro-OmeTAD, copper (I) oxide (Cu2O), and copper (I) iodide (CuI) as hole transport layer (HTL), and phenyl-C61-butyric acid methyl ester (PCBM), poly(3-hexylthiophene-2,5-diyl) (P3HT), zinc oxide, and titanium dioxide as electron transport layer (ETL). The best performance in terms of the power conversion efficiency (PCE) was recorded for the device with Cu2O as the HTL and ZnO as the ETL with the absorber layer thickness of 200 nm. The working temperature of the device was varied from 295 to 320 K and the effects of temperature on various device architectures were investigated. Results obtained indication that the efficiency of the bismuth perovskite solar cells can be improved by optimizing the thickness of the absorber layer and utilizing an appropriate combination of HTLs and ETLs. Keywords: methyl-ammonium bismuth perovskite, SCAPS, HTL, ETL, PCE.

Elucidating the mechanisms underlying PCBM enhancement of CH3NH3PbI3 perovskite solar cells using GIXRD and XAFS

2020 ◽  
Vol 8 (6) ◽  
pp. 3145-3153 ◽  
Author(s):  
Bing Liu ◽  
Rongli Cui ◽  
Huan Huang ◽  
Xihong Guo ◽  
Jinquan Dong ◽  
...  
Keyword(s):  
Solar Cells ◽  
Methyl Ester ◽  
Active Layer ◽  
Butyric Acid ◽  
Perovskite Solar Cells ◽  
Acid Methyl Ester ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester ◽  
The Stability

In this study, the stability mechanism of the optimized methyl ammonium lead triiodide (CH3NH3PbI3, MAPbI3)/[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) perovskite active layer upon exposure to moisture, light, and heating was investigated.

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