Synthesis of TS-1 from an Inorganic Reactant System and Its Catalytic Properties for Allyl Chloride Epoxidation

2012 ◽  
Vol 51 (39) ◽  
pp. 12730-12738 ◽  
Author(s):  
Meng Wang ◽  
Jicheng Zhou ◽  
Guiyue Mao ◽  
Xianglan Zheng
Keyword(s):  
Catalytic Properties ◽  
Allyl Chloride ◽  
Allyl Chloride Epoxidation

Kinetics of allyl chloride epoxidation with hydrogen peroxide

2011 ◽  
Vol 52 (6) ◽  
pp. 793-797 ◽  
Author(s):  
S. M. Danov ◽  
A. V. Sulimov ◽  
V. A. Kolesnikov ◽  
A. V. Ovcharova
Keyword(s):  
Hydrogen Peroxide ◽  
Allyl Chloride ◽  
Kinetics Of ◽  
Allyl Chloride Epoxidation

Preparation of anatase-free hierarchical titanosilicalite-1 in favor of allyl chloride epoxidation

2021 ◽  
pp. 111388
Author(s):  
Meng Liu ◽  
Jieqiong Li ◽  
Xingchi Chen ◽  
Jie Song ◽  
Wei Wei ◽  
...  
Keyword(s):  
Allyl Chloride ◽  
Allyl Chloride Epoxidation

Kinetics of allyl chloride epoxidation with hydrogen peroxide catalyzed by extruded titanium silicalite

2014 ◽  
Vol 55 (6) ◽  
pp. 712-721 ◽  
Author(s):  
A. V. Sulimov ◽  
S. M. Danov ◽  
A. V. Ovcharova ◽  
A. A. Ovcharov ◽  
V. R. Flid
Keyword(s):  
Hydrogen Peroxide ◽  
Allyl Chloride ◽  
Titanium Silicalite ◽  
Kinetics Of ◽  
Allyl Chloride Epoxidation

Selective synthesis of epichlorohydrin via liquid-phase allyl chloride epoxidation over a modified Ti-MWW zeolite in a continuous slurry bed reactor

2021 ◽  
Vol 45 (1) ◽  
pp. 331-342
Author(s):  
Luoyi Ding ◽  
Jinpeng Yin ◽  
Wen Tong ◽  
Rusi Peng ◽  
Jingang Jiang ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Allyl Chloride ◽  
Reaction System ◽  
Industrial Process ◽  
Slurry Reactor ◽  
Selective Synthesis ◽  
Mww Zeolite ◽  
Allyl Chloride Epoxidation

The epoxidation of allyl chloride (ALC) to epichlorohydrin (ECH) with H2O2 using a piperidine (PI)-modified Ti-MWW catalyst (Ti-MWW-PI) in a continuous slurry reactor was investigated to develop an efficient reaction system for the corresponding industrial process.

Allyl chloride epoxidation with H2O2 on TS-1/SiO2 catalyst in a fixed-bed reactor: experiments and deactivation kinetics

2014 ◽  
Vol 112 (1) ◽  
pp. 267-282 ◽  
Author(s):  
Yi Lin ◽  
Yaquan Wang ◽  
Wenping Feng ◽  
Guoqiang Wu ◽  
Juan Xu ◽  
...  
Keyword(s):  
Fixed Bed ◽  
Allyl Chloride ◽  
Fixed Bed Reactor ◽  
Deactivation Kinetics ◽  
Allyl Chloride Epoxidation

scholarly journals Design of MFI Type Aluminum- and Titanium-Containing Zeolites

Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1451
Author(s):  
Galina M. Kuz’micheva ◽  
Elena N. Domoroshchina ◽  
Galina V. Kravchenko
Keyword(s):  
Escherichia Coli ◽  
Catalytic Activity ◽  
Staphylococcus Epidermidis ◽  
Aquatic Environment ◽  
Catalytic Properties ◽  
Allyl Chloride ◽  
Visible Range ◽  
Vis Spectroscopy ◽  
Complete Extraction

HZSM-5 (MFI type) of composition (Hx)[Al3+xSi12−xO24] × wH2O and nanocomposites NA/HZSM-5, NA:M/HZSM-5 (NA—nanoscale anatase; M = V, Ni, Ag) with Si/Al = 12, 25, 40, 300 (sp.gr. Pnma or P21/n; z = 8), as well as zeolites [(Ti4+xSi12−xO24] × wH2O (TS) with Si/Ti = 47, 53, 73.5 (sp.gr. Pnma) were studied by XRPD, XAS, FTIR-spectroscopy, BET, XPS, SEM, EDX, TPD, UV–VIS-spectroscopy, UV–DRS, and chemiluminescence methods. The results obtained together with photocatalytic, adsorption, antimicrobial, catalytic properties were analyzed using crystallochemical concepts and literature data. It was shown that NA or NA:M introduction into HZSM-5 leads, respectively, to the photodegradation of MeO dye in the UV region or difenoconazole in the visible range, and contributes to the appearance in the dark of adsorption (almost complete extraction of P(V), As(V), and Se(V) from aquatic environment) and bacteriostatic properties in respect to Staphylococcus epidermidis, Bacillus antracoides, and Escherichia coli for NA:Ag/HZSM-5(40, 300). The presence of titanium ions in NA nanoparticles on the HZSM-5 surface improves the catalytic activity in ethanol and propane (the best performance for NA/HZSM-5(25) and NA/HZSM-5(40), respectively) conversion. Determination of the composition (surface and bulk) and structure (statistical and local) of TS zeolites together with the found correlations made it possible to propose new catalysts in the reactions of propane, ethanol, and allyl chloride conversion.

Microstructure and reactivity of small metal particles: The role of Ce additives

1992 ◽  
Vol 50 (1) ◽  
pp. 318-319
Author(s):  
L.D. Schmidt ◽  
K. R. Krause ◽  
J. M. Schwartz ◽  
X. Chu
Keyword(s):  
Atmospheric Pressure ◽  
Noble Metals ◽  
Mixed Oxides ◽  
Catalytic Properties ◽  
Chemical Shifts ◽  
Catalytic Converter ◽  
Structural Evolution ◽  
Single Particles ◽  
Small Metal Particles

The evolution of microstructures of 10- to 100-Å diameter particles of Rh and Pt on SiO2 and Al2O3 following treatment in reducing, oxidizing, and reacting conditions have been characterized by TEM. We are able to transfer particles repeatedly between microscope and a reactor furnace so that the structural evolution of single particles can be examined following treatments in gases at atmospheric pressure. We are especially interested in the role of Ce additives on noble metals such as Pt and Rh. These systems are crucial in the automotive catalytic converter, and rare earths can significantly modify catalytic properties in many reactions. In particular, we are concerned with the oxidation state of Ce and its role in formation of mixed oxides with metals or with the support. For this we employ EELS in TEM, a technique uniquely suited to detect chemical shifts with ∼30Å resolution.

Electron distribution change of small nickel particles encaged in X zeolite in presence of Ce3+ ions, related to their catalytic properties

1986 ◽  
Vol 83 ◽  
pp. 619-621 ◽  
Author(s):  
F. Vergand ◽  
B. Iraqi ◽  
C. Bonnelle ◽  
E. Ramaroson ◽  
M.F. Guilleux ◽  
...  
Keyword(s):  
Electron Distribution ◽  
Catalytic Properties ◽  
Distribution Change ◽  
Nickel Particles ◽  
X Zeolite
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