THE EFFECT OF HYDROXYL GROUPS ON THE APPARENT DIENE VALUES OF VEGETABLE OILS AND FATS

1937 ◽  
Vol 59 (12) ◽  
pp. 2744-2745 ◽  
Author(s):  
W. G. Bickford ◽  
F. G. Dollear ◽  
K. S. Markley
Coatings ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 13
Author(s):  
Marlena Musik ◽  
Marcin Bartkowiak ◽  
Eugeniusz Milchert

Vegetable oils and their derivatives have great potential as renewable and sustainable raw materials for the production of polyurethanes and bio-based polyols. For industry an important process is their modification. Chemical reactions that are carried out on vegetable oils and their derivatives are: transesterification, auto-oxidation, hydrogenation, epoxidation, hydroxylation, acrylation, isocyanation and others. One of the modifications are reactions performed on double bonds and/or carbonyl moieties of plants oils and their derivatives. These reactions result in products that are actively used as binders in coating materials due to their unique structural properties. In this manuscript, we describe important technological methods for the introduction of hydroxyl groups: opening of oxirane rings by nucleophilic reagents such as: water, alcohols, glycols, amino alcohols, carboxylic acids; direct hydroxylation of unsaturated bonds with carboxylic peracids in combination with hydrolysis of carboxyl groups and hydration; hydroformylation of unsaturated bonds with subsequent hydrogenation and alkoxylation; and ozonolysis of unsaturated bonds in combination with subsequent hydrogenation and alkoxylation.


Author(s):  
Wardoyo Wardoyo ◽  
Agung S. Widodo ◽  
Widya Wijayanti ◽  
I. N. G. Wardana

The need for vegetable oils as alternative energy reserves increases with the depletion of fossil energy sources. Vegetable oil is the strongest candidate to replace the fossil energy. However, the use of vegetable oil directly as fuel is limited by high viscosity. Viscosity like this results in non-ideal atomization, challenging to evaporate, and cannot burn completely. Among the methods that have been studied by previous researchers and which have proven to be effective, cheaper, and can reduce the viscosity of vegetable oils better is the mixing method. In this study, corn oil was mixed with areca extract as an additive. Areca extract contains polyphenols which are polar types of epicatechin. Epicatechin has three aromatic rings and several hydroxyl groups. Delocalisation of electrons in aromatic rings can produce London forces on vegetable oil molecules, thereby increasing the reactivity of burning vegetable oil droplets. The burning characteristics of corn vegetable oil affected by areca extract have been studied experimentally at room temperature and atmospheric pressure. The results showed that the rate and temperature of combustion increased, as well as the presence of micro explosions. The London force that appears causes the bonds in the triglyceride molecules to weaken so that the combustion becomes reactive, the rate of heat transfer in the droplets gets better, facilitates the appearance of micro explosions and increases the combustion temperature. Vegetable oil from corn has been studied experimentally at atmospheric pressure and room temperature. The results show an increase in the rate of combustion, an increase in combustion temperature, and the presence of micro explosions. London force that appears causes the bonds in the triglyceride molecules to weaken so that combustion becomes more reactive, the rate of heat transfer in the droplet gets better, facilitates the appearance of micro explosions and raises the combustion temperature.


1895 ◽  
Vol 40 (1031supp) ◽  
pp. 16486-16486
Author(s):  
P. L. Simmonds
Keyword(s):  

TAPPI Journal ◽  
2013 ◽  
Vol 12 (11) ◽  
pp. 49-53 ◽  
Author(s):  
CHRISTINE CHIRAT ◽  
LUCIE BOIRON ◽  
DOMINIQUE LACHENAL

Autohydrolysis and acid hydrolysis treatments were applied on mixed softwood chips. The cooking ability was studied by varying the alkali and duration of the cook. Pulps with kappa numbers varying from 30 to 70 were obtained. The bleaching ability of these pulps was studied and compared to control kraft pulps. The prehydrolyzed pulps were shown to be more efficiently delignified by oxygen than the control kraft pulps starting from the same kappa number. Furthermore, the final bleaching was also easier for these pulps. It was also shown that extensive oxygen delignification applied on high-kappa pre-hydrolyzed pulps could be a way to improve the overall yield, which is a prerequisite for the development of such biorefinery concepts. Lignin was isolated from the control kraft and the two pre-hydrolyzed kraft pulps and analyzed by 13C NMR. Lignins from pre-hydrolyzed kraft pulps had similar free phenolic groups content to the control kraft lignin, but their aliphatic hydroxyl groups and β-O-4 content were lower than for the control lignin. The quaternary carbon content was the same for all the samples.


2017 ◽  
Vol 39 (3) ◽  
pp. 188-194
Author(s):  
M.A. Gumenna ◽  
◽  
N.S. Klimenko ◽  
A.V. Stryutsky ◽  
D.M. Hodyna ◽  
...  

2017 ◽  
Author(s):  
Kishor Wagh ◽  
Roshni Halmare ◽  
Meghna Suryawanshi

2015 ◽  
Vol 11 (6) ◽  
pp. 3630-3634
Author(s):  
T.A. Mamedova ◽  
Z.M. Aliyeva ◽  
A.E. Aliyeva ◽  
R.T. Samedov ◽  
V.M. Abbasov ◽  
...  

The process of producing mono-alkyl esters of fatty acids from cottonseed and sunflower oils under the influence of the magnetic field with intensity  15-45 mT  was  investigated . It was revealed that the use of the energy of  magnetic field allows to reduce the reaction time to 10 times, the excess of used alcohol to 2 times while maintaining high yield of the desired product.


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