Density, electrical conductivity, and vapor pressure of concentrated phosphoric acid

1969 ◽  
Vol 14 (3) ◽  
pp. 380-384 ◽  
Author(s):  
David I. MacDonald ◽  
James R. Boyack

1997 ◽  
Vol 84 (1-3) ◽  
pp. 789-790 ◽  
Author(s):  
Chul Oh Yoon ◽  
Jong Hyun Kim ◽  
Hyun Kyung Sung ◽  
Hosull Lee


1981 ◽  
Vol 26 (3) ◽  
pp. 295-300 ◽  
Author(s):  
Yong K. Kim ◽  
Henry K. Walters ◽  
John D. Hatfield


1909 ◽  
Vol 95 (0) ◽  
pp. 59-66 ◽  
Author(s):  
Harry Edward William Phillips


2007 ◽  
Vol 244 (5) ◽  
pp. 1623-1626 ◽  
Author(s):  
K. Lott ◽  
S. Shinkarenko ◽  
O. Volobujeva ◽  
L. Türn ◽  
T. Nirk ◽  
...  


2015 ◽  
Vol 70 (2) ◽  
pp. 133-134
Author(s):  
Alexander B. Salyulev ◽  
Alexei M. Potapov

AbstractThe electrical conductivity of molten ZnCl2 was measured in a wide temperature range (ΔT=863 K) to a temperature as high as 1421 K that is 417 degrees above the boiling point of the salt. At the temperature maximum of the own vapor pressure of the salt reached several megapascals.



Coatings ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 84 ◽  
Author(s):  
Shengchang Zhang ◽  
Christine Campagne ◽  
Fabien Salaün

Electrosprayed poly(caprolactone) (PCL) microparticles were produced using five solvents (ethyl acetate, acetone, anisole, glacial acetic acid and chloroform) under different PCL concentrations and operating parameters. Not only green and appropriate solvent for PCL electrospraying was pointed out, but also the effects of solution properties (surface tension, electrical conductivity, viscosity and vapor pressure) and operating parameters (flow rate, working distance and applied voltage) on the formation of electrosprayed particles were clarified. The formation and shape of Taylor cone during electrospraying was observed by high-speed images captured with a camera, and the size and morphology of electrosprayed particles were characterized by optical and scanning electron microscopies. It can conclude that the cone–jet range of applied voltage mainly depended on electrical conductivity, and an ideal Taylor cone was easier to form under high viscosity and low surface tension. Although high electrical conductivity was a contributor to fabricate tiny particles, it was easier to fabricate mono-dispersed microparticles under low electrical conductivity. The poly-dispersed distribution obtained with a high electrical conductivity converted into mono-dispersed distribution with the increasing of viscosity. Furthermore, the size of electrosprayed particles also correlated with the surface tension and vapor pressure of the solvent used. Ethyl acetate, due to mild electrical conductivity and surface tension, moderate viscosity and vapor pressure, is a green and suitable solvent for PCL electrospraying. Single pore PCL microparticles with smooth cherry-like morphology can be prepared from ethyl acetate. Finally, long working distance not only stabilizes the break-up of charged jet, but also promotes the evaporation of solvent.



Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 815
Author(s):  
Eri Nagahashi ◽  
Fumihiko Ogata ◽  
Chalermpong Saenjum ◽  
Takehiro Nakamura ◽  
Naohito Kawasaki

The characteristics of acid-activated raw bentonite (RB) activated with binary acid solutions sulfuric acid + nitric acid, nitric acid + phosphoric acid, and phosphoric acid + sulfuric acid, at a concentration of 5 mol/L (denoted as 5-SN, 5-NP, and 5-PS), were evaluated. Moreover, its application for improving the electrical conductivity in tap water was demonstrated. Acid activation induced the partial destruction of RB; subsequently, there was a significant release of sodium ions from the RB. In addition, the specific surface area and pore volume of 5-SN, 5-NP, and 5-PS were higher than those of RB. Next, the electrical conductivity when using RB increased with adsorption treatment because sodium ions were released from the RB. However, the electrical conductivity significantly decreased with adsorption treatment when using acid-activated RB. Specifically, magnesium ions, calcium ions, and potassium ions were removed into 5-SN, 5-NP, and 5-PS, and sodium ions were not released from the RB simultaneously. The removal percentage of the electrical conductivity using 5-SN, 5-NP, and 5-PS was approximately 31% to 36%. The results indicated that employing acid-activated RB with a binary acid solution is a useful method for decreasing the electrical conductivity in tap water.



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