Unusual Behavior of Atactic Poly(methacrylic acid) in Aqueous Solutions Monitored by Wide-Angle Light Scattering

2004 ◽  
Vol 108 (47) ◽  
pp. 18164-18173 ◽  
Author(s):  
Ksenija Kogej ◽  
Hugo Berghmans ◽  
Harry Reynaers ◽  
Sergio Paoletti
2001 ◽  
Vol 1 (4) ◽  
pp. 157-163 ◽  
Author(s):  
Sergey V. Kazakov ◽  
Vladimir I. Muronetz ◽  
Maria B. Dainiak ◽  
Vladimir A. Izumrudov ◽  
Igor Yu. Galaev ◽  
...  

Soft Matter ◽  
2014 ◽  
Vol 10 (39) ◽  
pp. 7712-7722 ◽  
Author(s):  
Simona Sitar ◽  
Vladimir Aseyev ◽  
Ksenija Kogej

We study the structure of aggregates formed by isotactic and atactic poly(methacrylic acid)s in aqueous solutions with added alkali chlorides using light scattering.


1989 ◽  
Vol 54 (11) ◽  
pp. 3011-3024 ◽  
Author(s):  
Vlastimil Fidler ◽  
Stefan Vajda ◽  
Zuzana Limpouchová ◽  
Jiří Dvořák ◽  
Karel Procházka ◽  
...  

The methodology of polarization time-resolved fluorometry and interpretation of its results are outlined at a general level, and the measurement on and use of facilities of the Edinburgh Instruments Model 299T apparatus are discussed in detail. The dynamics of conformational changes in chains of poly(methacrylic acid) containing covalently bonded dansyl labels are studied in aqueous solutions at various pH. It is shown that at pH > 6, the shorter effective rational correlation time τr < 2 ns corresponds to the rotation of the free dansyl label about bonds by which it is attached to the polymeric chain; at pH < 4 the longer effective rational correlation time τr = 20-26 ns corresponds to the rotation of the compact spherical formation constituted by a part of the collapsed polymeric chain in which the label is fixed and whose relative molecular mass is approx. 15 000-20 000.


2010 ◽  
Vol 114 (12) ◽  
pp. 4204-4212 ◽  
Author(s):  
Ekaterina R. Gasilova ◽  
Anna A. Toropova ◽  
Stanislav V. Bushin ◽  
Albert K. Khripunov ◽  
Ludmila A. Grischenko ◽  
...  

2018 ◽  
Vol 60 (S1) ◽  
pp. 172-178 ◽  
Author(s):  
T. N. Nekrasova ◽  
V. D. Pautov ◽  
T. D. Anan’eva ◽  
T. K. Meleshko ◽  
I. V. Ivanov ◽  
...  

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