Stepwise and Concerted Pathways in Thermal and Photoinduced Electron-Transfer/Bond-Breaking Reactions

2000 ◽  
Vol 104 (32) ◽  
pp. 7492-7501 ◽  
Author(s):  
Cyrille Costentin ◽  
Marc Robert ◽  
Jean-Michel Savéant
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
Bond Breaking

Computationally Assisted Design of High Signal-to-Noise Photoinduced Electron Transfer-Based Voltage-Sensitive Dyes

2020 ◽  
Author(s):  
Rishikesh Kulkarni ◽  
Anneliese Gest ◽  
Chun Kei Lam ◽  
Benjamin Raliski ◽  
Feroz James ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Dft Calculations ◽  
Photoinduced Electron Transfer ◽  
Density Functional ◽  
Embryonic Stem ◽  
High Sensitivity ◽  
Md Simulations ◽  
High Signal ◽  
Signal To Noise ◽  
Green Fluorescent

<p>High signal-to-noise optical voltage indicators will enable simultaneous interrogation of membrane potential in large ensembles of neurons. However, design principles for voltage sensors with high sensitivity and brightness remain elusive, limiting the applicability of voltage imaging. In this paper, we use molecular dynamics (MD) simulations and density functional theory (DFT) calculations to guide the design of a bright and sensitive green-fluorescent voltage-sensitive fluorophore, or VoltageFluor (VF dye), that uses photoinduced electron transfer (PeT) as a voltage-sensing mechanism. MD simulations predict an 11% increase in sensitivity due to membrane orientation, while DFT calculations predict an increase in fluorescence quantum yield, but a decrease in sensitivity due to a decrease in rate of PeT. We confirm these predictions by synthesizing a new VF dye and demonstrating that it displays the expected improvements by doubling the brightness and retaining similar sensitivity to prior VF dyes. Combining theoretical predictions and experimental validation has resulted in the synthesis of the highest signal-to-noise green VF dye to date. We use this new voltage indicator to monitor the electrophysiological maturation of human embryonic stem cell-derived medium spiny neurons. </p>

Photoinduced electron transfer in mechanically interlocked suit[3]ane systems

2021 ◽  
Author(s):  
Anton J Stasyuk ◽  
Olga A. Stasyuk ◽  
Miquel Solà ◽  
Alexander Voityuk
Keyword(s):  
Electron Transfer ◽  
Photoinduced Electron Transfer ◽  
New Class ◽  
Transfer Processes ◽  
Two Component ◽  
Electron Transfer Processes

Suitanes, a new class of two-component mechanically interlocked systems, have recently been developed. In this work, we report a detailed study of photoinduced electron transfer processes in the suit[3]anes consisting...

Rare-Earth Eu3+/Gold Nanocluster Ensemble-Based Fluorescent Photoinduced Electron Transfer Sensor for Biomarker Dipicolinic Acid Detection

Langmuir ◽  
2021 ◽  
Author(s):  
Ling-Fang Xiu ◽  
Kai-Yuan Huang ◽  
Chen-Ting Zhu ◽  
Qi Zhang ◽  
Hua-Ping Peng ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Rare Earth ◽  
Photoinduced Electron Transfer ◽  
Dipicolinic Acid ◽  
Gold Nanocluster

scholarly journals A quantum optics approach to photoinduced electron transfer in cavities

2021 ◽  
Vol 154 (5) ◽  
pp. 054104
Author(s):  
D. Wellnitz ◽  
G. Pupillo ◽  
J. Schachenmayer
Keyword(s):  
Electron Transfer ◽  
Quantum Optics ◽  
Photoinduced Electron Transfer

scholarly journals Molecular Engineering for High-Performance Fullerene Broadband Photodetector

2021 ◽  
Author(s):  
Mingming Su ◽  
Yajing Hu ◽  
Ao Yu ◽  
Zhiyao Peng ◽  
Wangtao Long ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Low Temperature ◽  
Electron Acceptor ◽  
Photoinduced Electron Transfer ◽  
High Performance ◽  
Organic Molecules ◽  
Low Cost ◽  
Molecular Engineering ◽  
Temperature Requirement ◽  
High Flexibility

Broadband photodetectors fabricated with organic molecules have the advantages of low cost, high flexibility, easy processing and low-temperature requirement. Fullerene molecules, due to the electron acceptor and photoinduced electron transfer...

Designing a novel photoinduced electron transfer-based small-molecule fluorescent probe specific for CYP3A isozymes

2021 ◽  
pp. 128195
Author(s):  
Keiichi Fujimoto ◽  
Hayato Takeuchi ◽  
Tomoyuki Takaku ◽  
Jun Abe ◽  
Koichiro Harada
Keyword(s):  
Electron Transfer ◽  
Fluorescent Probe ◽  
Small Molecule ◽  
Photoinduced Electron Transfer
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