A New Approach to Hyperbranched Polymers by Ring-Opening Polymerization of an AB Monomer:  4-(2-Hydroxyethyl)-ε-caprolactone

1999 ◽  
Vol 32 (20) ◽  
pp. 6881-6884 ◽  
Author(s):  
Mingjun Liu ◽  
Nikolay Vladimirov ◽  
Jean M. J. Fréchet
Keyword(s):  
Ring Opening ◽  
Hyperbranched Polymers ◽  
Ring Opening Polymerization ◽  
New Approach

Latest Research and Developing Tendency of Hyperbranched Polymers Fabrication

2021 ◽  
Vol 896 ◽  
pp. 45-50
Author(s):  
Lian Yi Huo ◽  
Xue Tao Shi ◽  
Si Ming Chen ◽  
Meng Yao Zhang
Keyword(s):  
Reaction Mechanism ◽  
Ring Opening ◽  
Hyperbranched Polymers ◽  
Ring Opening Polymerization ◽  
Synthesis Process ◽  
Future Research ◽  
Advantages And Disadvantages ◽  
Environmental Friendly ◽  
High Efficient ◽  
The Future

Hyperbranched polymers (HBPs) have been applied in various fields because of its outstanding biodegradability and biocompatibility. At present, there are a variety of methods that are used to fabricate HBPs, such as polycondensation, reactive polymerization and ring-opening polymerization according to reaction mechanism. These methods are all environmental-friendly and high-efficient to generate HBPs, and are valuable for industrialization. In this work, we conclude some common methods of HBPs fabrication and make the comparison between them to analyze their advantages and disadvantages, which contribute in how to improve the synthesis process in the future research.

Growing Multihydroxyl Hyperbranched Polymers on the Surfaces of Carbon Nanotubes by in Situ Ring-Opening Polymerization

2004 ◽  
Vol 37 (24) ◽  
pp. 8846-8853 ◽  
Author(s):  
Youyong Xu ◽  
Chao Gao ◽  
Hao Kong ◽  
Deyue Yan ◽  
Yi Zheng Jin ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Ring Opening ◽  
Hyperbranched Polymers ◽  
Ring Opening Polymerization

Nb and Ta benzotriazole or benzoxazole phenoxide complexes as catalysts for the ring-opening polymerization of glycidol to synthesize hyperbranched polyglycerols

2017 ◽  
Vol 46 (47) ◽  
pp. 16640-16654 ◽  
Author(s):  
Sreenath Pappuru ◽  
Debashis Chakraborty ◽  
Venkatachalam Ramkumar
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
New Approach ◽  
Trimethylol Propane

New approach for synthesizing hyper branched polyethers using organometallic Nb and Ta complexes as catalysts and trimethylol propane as initiator was demonstrated.

scholarly journals Kinetic Model of Hyperbranched Polymers Formed by Self-Condensing Vinyl or Self-Condensing Ring-Opening Polymerization of AB Monomers Activated by Stimuli with Different Reactivities

2010 ◽  
Vol 43 (21) ◽  
pp. 8965-8970 ◽  
Author(s):  
Kuo-Chung Cheng ◽  
Yuan-Yuan Su ◽  
Tsu-Hwang Chuang ◽  
Wenjeng Guo ◽  
Wei-Fang Su
Keyword(s):  
Kinetic Model ◽  
Ring Opening ◽  
Hyperbranched Polymers ◽  
Ring Opening Polymerization

A New Approach for the Synthesis of Miktoarm Star Polymers Through a Combination of Thiol–Epoxy “Click” Chemistry and ATRP/Ring‐Opening Polymerization Techniques

2018 ◽  
Vol 57 (2) ◽  
pp. 146-156 ◽  
Author(s):  
Ikhlas Gadwal ◽  
Prakash P. Wadgaonkar ◽  
Amol B. Ichake ◽  
Shivshankar R. Mane
Keyword(s):  
Click Chemistry ◽  
Ring Opening ◽  
Star Polymers ◽  
Ring Opening Polymerization ◽  
New Approach ◽  
Miktoarm Star

scholarly journals Synthesis of Hyperbranched Polymers by the Anionic Ring-Opening Polymerization of 3,3-Bis(hydroxymethyl)oxetane

2004 ◽  
Vol 36 (5) ◽  
pp. 413-421 ◽  
Author(s):  
Ayako Morita ◽  
Hiroto Kudo ◽  
Tadatomi Nishikubo
Keyword(s):  
Ring Opening ◽  
Hyperbranched Polymers ◽  
Ring Opening Polymerization ◽  
Anionic Ring

A new approach to control crystallinity of resulting polymers: Self-condensing ring opening polymerization

2000 ◽  
Vol 21 (9) ◽  
pp. 557-561 ◽  
Author(s):  
Deyue Yan ◽  
Jian Hou ◽  
Xinyuan Zhu ◽  
Joseph J. Kosman ◽  
Huey-Shen Wu
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
New Approach

A Recommender System for Inverse Design of Polycarbonates and Polyesters

2020 ◽  
Author(s):  
Nathaniel Park ◽  
Dmitry Yu. Zubarev ◽  
James L. Hedrick ◽  
Vivien Kiyek ◽  
Christiaan Corbet ◽  
...  
Keyword(s):  
Ring Opening ◽  
High Performance ◽  
Recommendation System ◽  
Polymeric Materials ◽  
Monomer Conversion ◽  
Design Strategy ◽  
Ring Opening Polymerization ◽  
Inverse Design ◽  
False Negatives ◽  
Accelerate Development

The convergence of artificial intelligence and machine learning with material science holds significant promise to rapidly accelerate development timelines of new high-performance polymeric materials. Within this context, we report an inverse design strategy for polycarbonate and polyester discovery based on a recommendation system that proposes polymerization experiments that are likely to produce materials with targeted properties. Following recommendations of the system driven by the historical ring-opening polymerization results, we carried out experiments targeting specific ranges of monomer conversion and dispersity of the polymers obtained from cyclic lactones and carbonates. The results of the experiments were in close agreement with the recommendation targets with few false negatives or positives obtained for each class.<br>

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