Growing Multihydroxyl Hyperbranched Polymers on the Surfaces of Carbon Nanotubes by in Situ Ring-Opening Polymerization

2004 ◽  
Vol 37 (24) ◽  
pp. 8846-8853 ◽  
Author(s):  
Youyong Xu ◽  
Chao Gao ◽  
Hao Kong ◽  
Deyue Yan ◽  
Yi Zheng Jin ◽  
...  

Polymer ◽  
2008 ◽  
Vol 49 (23) ◽  
pp. 4989-4994 ◽  
Author(s):  
Jiangtao Feng ◽  
Wei Cai ◽  
Jiehe Sui ◽  
Zhiguo Li ◽  
Jiaqi Wan ◽  
...  


Polimery ◽  
2017 ◽  
Vol 62 ◽  
pp. 101-108 ◽  
Author(s):  
Iwona Pelech ◽  
Magdalena Kwiatkowska ◽  
Anna Jedrzejewska ◽  
Robert Pelech ◽  
Inez Kowalczyk






2004 ◽  
Vol 856 ◽  
Author(s):  
Alexandru D. Asandei ◽  
Isaac W. Moran ◽  
Gobinda Saha ◽  
Yanhui Chen

ABSTRACTTi(III)Cp2Cl-catalyzed radical ring opening (RRO) of epoxides or single electron transfer (SET) reduction of aldehydes generates Ti alkoxides and carbon centered radicals which add to styrene, initiating a radical polymerization. This polymerization is mediate in a living fashion by the reversible termination of growing chains with the TiCp2Cl metalloradical. In addition, polymers or monomers containing pendant epoxide groups (glycidyl methacrylate) can be used as substrates for radical grafting or branching reactions by self condensing vinyl polymerization. In addition, Ti alkoxides generated in situ by both epoxide RRO and aldehyde SET initiate the living ring opening polymerization of ε-caprolactone. Thus, new initiators and catalysts are introduced for the synthesis of complex polymer architectures.



2011 ◽  
Vol 49 (19) ◽  
pp. 4213-4220 ◽  
Author(s):  
Kubra Dogan Demir ◽  
Mehmet Atilla Tasdelen ◽  
Tamer Uyar ◽  
Asei William Kawaguchi ◽  
Atsushi Sudo ◽  
...  


2021 ◽  
Vol 896 ◽  
pp. 45-50
Author(s):  
Lian Yi Huo ◽  
Xue Tao Shi ◽  
Si Ming Chen ◽  
Meng Yao Zhang

Hyperbranched polymers (HBPs) have been applied in various fields because of its outstanding biodegradability and biocompatibility. At present, there are a variety of methods that are used to fabricate HBPs, such as polycondensation, reactive polymerization and ring-opening polymerization according to reaction mechanism. These methods are all environmental-friendly and high-efficient to generate HBPs, and are valuable for industrialization. In this work, we conclude some common methods of HBPs fabrication and make the comparison between them to analyze their advantages and disadvantages, which contribute in how to improve the synthesis process in the future research.



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