Hydrothermal Activity and the Geochemistry of Metalliferous Sediment

2013 ◽  
pp. 392-407 ◽  
Author(s):  
Rachel A. Mills ◽  
Harry Elderfield
Keyword(s):  
Hydrothermal Activity ◽  
Metalliferous Sediment

Hydrothermal activity in the Upper Permian Ravnefjeld Formation of central East Greenland – a study of sulphide morphotypes

1998 ◽  
pp. 81-87
Author(s):  
Jesper Kresten Nielsen ◽  
Mikael Pedersen
Keyword(s):  
Base Metal ◽  
Early Period ◽  
Sedimentary Basins ◽  
Hydrothermal Activity ◽  
Source Rocks ◽  
Upper Permian ◽  
Thermal Activity ◽  
East Greenland ◽  
The North ◽  
Alum Shale

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Kresten Nielsen, J., & Pedersen, M. (1998). Hydrothermal activity in the Upper Permian Ravnefjeld Formation of central East Greenland – a study of sulphide morphotypes. Geology of Greenland Survey Bulletin, 180, 81-87. https://doi.org/10.34194/ggub.v180.5090 _______________ Bituminous shales of the Ravnefjeld Formation were deposited in the subsiding East Greenland basin during the Upper Permian. The shales are exposed from Jameson Land in the south (71°N; Fig. 1) to Clavering Ø in the north (74°20′N) and have attracted considerable attention due to their high potential as hydrocarbon source rocks (Piasecki & Stemmerik 1991; Scholle et al. 1991; Christiansen et al. 1992, 1993a, b). Furthermore, enrichment of lead, zinc and copper has been known in the Ravnefjeld Formation on Wegener Halvø since 1968 (Lehnert-Thiel 1968; Fig. 1). This mineralisation was assumed to be of primary or early diagenetic origin due to similarities with the central European Kupferschiefer (Harpøth et al. 1986). Later studies, however, suggested base metal mineralisation in the immediately underlying carbonate reefs to be Tertiary in age (Stemmerik 1991). Due to geographical coincidence between the two types of mineralisation, a common history is a likely assumption, but a timing paradox exists. A part of the TUPOLAR project on the ‘Resources of the sedimentary basins of North and East Greenland’ has been dedicated to re-investigation of the mineralisation in the Ravnefjeld Formation in order to determine the genesis of the mineralisation and whether or not primary or early diagenetic base metal enrichment has taken place on Wegener Halvø, possibly in relation to an early period of hydrothermal activity. One approach to this is to study the various sulphides in the Ravnefjeld Formation; this is carried out in close co-operation with a current Ph.D. project at the University of Copenhagen, Denmark. Diagenetically formed pyrite is a common constituent of marine shales and the study of pyrite morphotypes has previously been successful from thermalli immature parts of elucidating depositional environment and thermal effects in the Alum Shale Formation of Scandinavia (Nielsen 1996; Nielsen et al. 1998). The present paper describes the preliminary results of a similar study on pyrite from thermally immature parts of the Ravnefjeld Formation which, combined with the study of textures of base metal sulphides in the Wegener Halvø area (Fig. 1), may provide an important step in the evaluation of the presence or absence of early thermal activity on (or below) the Upper Permian sea floor.

scholarly journals Mineralogical and Geochemical Signatures of Metalliferous Sediments in Wocan-1 and Wocan-2 Hydrothermal Sites on the Carlsberg Ridge, Indian Ocean

Minerals ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 26 ◽  
Author(s):  
Samuel Olatunde Popoola ◽  
Xiqiu Han ◽  
Yejian Wang ◽  
Zhongyan Qiu ◽  
Ying Ye ◽  
...  
Keyword(s):  
Indian Ocean ◽  
Volcanic Glass ◽  
Mineral Chemistry ◽  
Hydrothermal Systems ◽  
Bulk Sediment ◽  
Sediment Samples ◽  
Metalliferous Sediments ◽  
Metalliferous Sediment ◽  
Carlsberg Ridge ◽  
Hydrothermal Environments

In this paper, we conduct a comparative study on the mineralogy and geochemistry of metalliferous sediment collected near the active hydrothermal site (Wocan-1) and inactive hydrothermal site (Wocan-2) from Wocan Hydrothermal Field, on the Carlsberg Ridge (CR), northwest Indian Ocean. We aim to understand the spatial variations in the primary and post-depositional conditions and the intensity of hydrothermal circulations in the Wocan hydrothermal systems. Sediment samples were collected from six stations which includes TVG-07, TVG-08 (Wocan-1), TVG-05, TVG-10 (Wocan-2), TVG-12 and TVG-13 (ridge flanks). The mineralogical investigations show that sediment samples from Wocan-1 and Wocan-2 are composed of chalcopyrite, pyrite, sphalerite, barite, gypsum, amorphous silica, altered volcanic glass, Fe-oxides, and hydroxides. The ridge flank sediments are dominated by biogenic calcite and foraminifera assemblages. The bulk sediment samples of Wocan-1 have an elevated Fe/Mn ratio (up to ~1545), with lower U contents (<7.4 ppm) and U/Fe ratio (<~1.8 × 10−5). The sulfide separates (chalcopyrite, pyrite, and sphalerite) are enriched in Se, Co, As, Sb, and Pb. The calculated sphalerite precipitation temperature (Sph.PT) yields ~278 °C. The sulfur isotope (δ34S) analysis returned a light value of 3.0–3.6‰. The bulk sediment samples of Wocan-2 have a lower Fe/Mn ratio (<~523), with high U contents (up to 19.6 ppm) and U/Fe ratio (up to ~6.2 × 10−5). The sulfide separates are enriched in Zn, Cu, Tl, and Sn. The calculated Sph.PT is ~233 °C. The δ34S returned significant values of 4.1–4.3‰ and 6.4–8.7‰ in stations TVG-10 and TVG-05, respectively. The geochemical signatures (e.g., Fe/Mn and U/Fe ratio, mineral chemistry of sulfides separates, and S-isotopes and Sph.PT) suggest that sediment samples from Wocan-1 are located near intermediate–high temperature hydrothermal discharge environments. Additionally, relatively low δ34S values exhibit a lower proportion (less than 20%) of seawater-derived components. The geochemical signatures suggest that sediment samples from Wocan-2 has undergone moderate–extensive oxidation and secondary alterations by seawater in a low–intermediate temperature hydrothermal environments. Additionally, the significant δ34S values of station TVG-05 exhibit a higher estimated proportion (up to 41%) of seawater-derived components. Our results showed pervasive hydrothermal contributions into station TVG-08 relative to TVG-07, it further showed the increased process of seafloor weathering at TVG-05 relative to TVG-10.

New constraints from zircon, monazite and uraninite dating on the commencement of sedimentation in the Cuddapah basin, India

2017 ◽  
Vol 155 (6) ◽  
pp. 1230-1246 ◽  
Author(s):  
DEBIDARSANI SAHOO ◽  
KAMAL LOCHAN PRUSETH ◽  
DEWASHISH UPADHYAY ◽  
SAMEER RANJAN ◽  
DIPAK C. PAL ◽  
...  
Keyword(s):  
Wide Spectrum ◽  
Hydrothermal Activity ◽  
Time Span ◽  
Detrital Zircons ◽  
Cuddapah Basin ◽  
Relative Timing ◽  
Considerable Time ◽  
Long Span ◽  
Considerable Confusion ◽  
Age Constraints

AbstractThe Cuddapah basin in southern India, consisting of the Palnad, Srisailam, Kurnool and Papaghni sub-basins, contains unmetamorphosed and undeformed sediments deposited during a long span of time in the Proterozoic. In the absence of robust age constraints, there is considerable confusion regarding the relative timing of sedimentation in these sub-basins. In this study, U–Pb isotopic dating of zircon and U–Th–Pbtotaldating of monazite and uraninite from the gritty quartzite that supposedly belongs to the formation Banganapalle Quartzite have been used to constrain the beginning of sedimentation in the Palnad sub-basin. Magmatic and detrital zircons recording an age of 2.53 Ga indicate that the sediments were derived from the granitic basement or similar sources and were deposited after 2.53 Ga. Hydrothermally altered zircons both in the basement and the cover provide concordant ages of 2.32 and 2.12 Ga and date two major hydrothermal events. Thus, the gritty quartzite must have been deposited sometime between 2.53 and 2.12 Ga and represents the earliest sediments in the Cuddapah basin. Monazite and uraninite give a wide spectrum of ages between 2.5 Ga and 150 Ma, which indicates several pulses of hydrothermal activity over a considerable time span, both in the basement granite and the overlying quartzite. The new age constraints suggest that the gritty quartzite may be stratigraphically equivalent to the Gulcheru Quartzite that is the oldest unit in the Cuddapah basin, and that a sedimentary/erosional hiatus exists above it.

scholarly journals Geochemical Fractions of Heavy Metals in Bottom Sediments of the Pobeda Hydrothermal Field, Mid-Atlantic Ridge (17°07′–17°08′ N)

2021 ◽  
Vol 6 (1) ◽  
pp. 14
Author(s):  
Liudmila Demina ◽  
Irina Gablina ◽  
Olga Dara ◽  
Dmitry Budko ◽  
Nina Gorkova ◽  
...  
Keyword(s):  
Total Content ◽  
Element Distribution ◽  
Hydrothermal Field ◽  
Residual Fraction ◽  
Carbonate Sediments ◽  
Metalliferous Sediments ◽  
Geochemical Fractions ◽  
Metalliferous Sediment ◽  
Fe And Mn ◽  
Mid Atlantic Ridge

We examined the distribution of Fe, Mn, Cu, Zn, and Pb in one core of metalliferous, and one core of non-mineralized (background) carbonate sediments (located 69 km northwards), from the Pobeda hydrothermal field. Mechanisms of metal accumulation in sediments (12 samples) were evaluated based on sequential extraction of geochemical fractions, including mobile (exchangeable complex, authigenic Fe-Mn hydroxides, and sulfides), and lithogenic (fixed in crystalline lattices) forms. Maps of element distribution in sediment components were obtained using a scanning electron microscope equipped with an energy-dispersive spectrometry detector. In metalliferous sediments, according to X-ray diffraction data, the main Fe mineral phase was goethite FeOOH (37–44% on a carbonate-free basis). The contents of Fe and Mn reached 31.6 and 0.18%, respectively, whereas concentrations of Cu, Zn and Pb were 0.98, 0.36, and 0.059%. The coefficient of metal enrichment relative to background values varied from 16 to 125 times. The exception was Mn, for which no increased accumulation was recorded. Essential mass of Fe (up to 70% of total content) was represented by the residual fraction composed of crystallized goethite, aluminosilicates, the minerals derived from bedrock destruction processes. Among geochemically mobile fractions, 90–97% of total Fe was found in the form of authigenic oxyhydroxides. The same fraction was the predominant host for Mn in both metalliferous and background sediments (55–85%). A total of 40–96 % of Cd, Cu, Zn, and Pb were associated with these Fe and Mn fractions. The sulfide fraction amounted to roughly 10% of each metal. In metalliferous sediment core, the maximum concentrations of metals and their geochemically mobile fractions were recorded in deeper core intercepts, an observation that might be attributed to influence of hydrothermal diffused fluids. Our data suggested that metals are mostly accumulated in carbonate sediments in their contact zone with the underlying serpentinized basalts.

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