Investigation of the Calcium Sulphate-Water System by Infrared Spectroscopy

Nature ◽  
1968 ◽  
Vol 219 (5149) ◽  
pp. 60-61 ◽  
Author(s):  
JOHN BENSTED ◽  
SATYA PRAKASH
2008 ◽  
Vol 62 (21-22) ◽  
pp. 3713-3715 ◽  
Author(s):  
T. Kuryatnyk ◽  
M. Chabannet ◽  
J. Ambroise ◽  
J. Pera

Author(s):  
Núria Ferrer ◽  
M. Carme Sistach

AbstractFourier transform infrared (FTIR) is an efficient tool to analyse deposits on iron gall inscriptions that appear on historic documents. Deposits look like white powder or whitish crystals under a microscope. Crystals show cubic or needle shapes with sizes below 20 μm. Mapping infrared spectroscopy in addition allows the selective identification of mixed deposits. Selective analysis of different inorganic oxalates is possible in four regions of the mid-infrared spectrum, thus avoiding interferences with bands of other compounds present. Calcium, potassium and iron oxalates, further calcium sulphate, calcium carbonate, basic iron sulphates and iron ammonium sulphate were identified on samples taken from selected manuscripts. The results enabled to establish a correlation of ink composition and the observed intensity of ink corrosion.


2021 ◽  
pp. 33-37
Author(s):  
F.M. Ahmadov ◽  

The inhibitors of inorganic mineral sediments based on orthophosphate acid, monoamid of sulphuric acid (MSA) and carboxymethylcelluloze (CMC) have been developed. Created compositional inhibitors of salt deposition are transparent, fluid water solution with 14.5–22.0 % concentration. To specify the efficiency of developed salt deposition inhibitors, the agent capacity to keep cations of calcium in the volume of artificially prepared mineral waters of carbonate and sulphate types modelling produced water within oil fields has been evaluated. It was defined that adding 20–20 mg/l of developed compositions into the solutions of calcium sulphate provides high protection effect. Inhibitors’ protection capacity using the compositions in the charge of 20 mg/l in sulphate water comprises 89.6–96.8 %, and in the carbonate water - 87.8–92.6 %. Using 25 mg/l of these compositions, protection capacity of the inhibitors in sulphate water reaches up to 94.5–98.7 %, and in carbonate water - 92.5–96.8 %. Protection effect of inhibitors in case of using 30 mg/l of the compositions comprises 98.3–100 % in sulphate water, and 96.8–100 % in carbonated one as well.


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